The present invention relates to a polyester consisting of (A) repeat units derived from an acid component, which consists of (a1) 2,5-furandicarboxylic acid, (a2) an aliphatic C.sub.4-C.sub.36 dicarboxylic acid or a mixture of a plurality of aliphatic C.sub.4-C.sub.36 dicarboxylic acids, and (a3) a sulfonate group-containing dicarboxylic acid, and of (B) repeat units derived from a di-ol/amine component, and optionally of further repeat units (C) and/or branching components (E), and of (D) repeat units derived from at least one di- or oligofunctional compound selected from the group consisting of a di- or oligoisocyanate and a di- or oligoisocyanurate. In addition, the present invention relates to the production of these polyesters and their use.

The present invention relates to an antimicrobial polymer coating composition comprising: a urethane acrylate-based oligomer or polymer having a molar ratio of a urethane functional group to a (meth)acrylate-based functional group of 1 to 10; a photosensitizer; and a photoinitiator; an antimicrobial polymer film comprising a cured product of the antimicrobial polymer coating composition; and an antimicrobial polymer film comprising a predetermined urethane acrylate-based polymer resin; and a photosensitizer dispersed in the polymer resin, wherein the polymer film has oxygen permeability of 5 to 100 cc/m.sup.2 day.

A polyetherester polyol is synthesized from reactants including a) aromatic acid or aromatic anhydride or a mixture thereof, and b) OH-functional starter molecules which contain alcoholamine or amine-initiated polyether polyol. Corresponding rigid polyurethane foams produced with the polyetherester polyol are useful for insulation used in appliance applications.

Embodiments of the present disclosure are directed towards solventless compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound.

A flexible tube for an endoscope, containing: a tubular flexible tube substrate material having a flexibility; and a resin layer covering the flexible tube substrate material, in which the resin layer is adhered to the flexible tube substrate material with an adhesive hardened, the adhesive hardened contains an ester-based polyurethane resin, which is a hardened resin of an adhesive for an endoscope, and the adhesive for an endoscope contains an ester-based urethane polymer having a structure represented by a specific formula.

A method for forming a multilayer coated film includes step (1) of applying an aqueous intermediate coating composition (A), step (2) of applying an aqueous base coating composition (B), step (3) of applying a clear coating composition (C), and step (4) of heat-curing the coated films. The coating composition (A) contains a specific hydroxyl group-containing acrylic resin (a1), a specific polyurethane resin (a2), a specific hydroxyl group-containing polyester resin (a3), a melamine resin (a4), and an active methylene-blocked polyisocyanate compound (a5). A ratio of the resin (a1) to the resin (a2) falls within a specific range. The heat-cured coated film of the coating composition (A) has a specific elongation at break, Young's modulus and Tukon hardness. The coating composition (C) contains a hydroxyl group-containing acrylic resin (c1) and an allophanate group-containing polyisocyanate compound (c2).

A coating composition includes at least one, low Tg, polyol resin having hydroxyl groups available for crosslinking, a polyurethane crosslinker that crosslinks the hydroxyl groups when cured, and water in an amount from about 4 to 20 wt. % of the total weight of the coating composition. Characteristically, solvents other than water are present in an amount less than half the amount of water. The coating composition is advantageously used to finish leather.

The present disclosure provides a process comprising providing an isocyanate component A comprising a blend of (i) an aromatic isocyanate prepolymer and (ii) an aliphatic isocyanate prepolymer; providing a polyol component B comprising a blend of; (i) a phosphate-functional polyol, (ii) a polyether polyol, and (iii) an element selected from the group consisting of a polyurethane polyol, a polyester polyol and a combination thereof; mixing component A and component B to form a solventless adhesive (SLA) composition, wherein a weight ratio of component A to component B is from 2:1 to 1:1, the SLA composition having a pot life from 30 min to 60 min at 40 C; applying the SLA composition between a first film and a second film to form a raw laminate; and curing the raw laminate to form a laminate product.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250 F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

The present invention relates to a process for producing a thermoplastic polyurethane reacting at least one thermoplastic polyurethane (TPU-1) or a polyurethane mixture comprising a thermoplastic polyurethane (TPU-1) with at least one compound (V1) comprising two hydroxyl groups to obtain a mixture (G-a) comprising a thermoplastic polyurethane (TPU-2) and the reaction of the mixture (G-a) with a mixture (G-b) comprising an isocyanate composition (ZI) comprising at least one diisocyanate and optionally and a polyol composition (ZP) comprising at least one polyol (P2) to obtain a thermoplastic polyurethane (TPU target), wherein the proportion of the employed components (ZI) and (ZP) is matched to the hard segment content of the employed thermoplastic polyurethane (TPU-1), (V1) and the hard segment content of the thermoplastic polyurethane (TPU target). The invention further relates to a thermoplastic polyurethane obtained or obtainable by such a process and to the use thereof for producing extruded, injection molded and pressed articles as well as foams, cable sheathings, hoses, profiles, drive belts, fibers, nonwovens, films, moldings, soles, sporting goods, shoes, plugs, housings, damping elements for the electricals industry, automotive industry, mechanical engineering, 3D printing, medicine and consumer goods.