A composition comprising an isocyanate composition comprising a polyisocyanate and a specific thermally conductive filler composition (C) can further be part of a two-component curable composition comprising the isocyanate composition and a polyol composition and having a low viscosity upon admixing and upon cure provides a high thermal conductivity.

There is provided a two-part urethane adhesive composition including: a main agent containing a polyisocyanate component (A); and a curing agent containing water and an active hydrogen-containing compound (B). The (B) contains a compound represented by Formula (4); the (A) contains a urethane prepolymer (A-3); an average active hydrogen concentration of the (B) is 0.50 to 3.50 mol/kg; an average active hydrogen concentration of the (B) and the water is 2.00 to 8.00 mol/kg. The main agent and the curing agent are mixed in such amounts as to satisfy conditions that: a ratio of the number of isocyanate groups of the (A) to the number of active hydrogens of the (B) is 1 to 5; and a ratio of the number of isocyanate groups of the (A) to the total number of active hydrogens of the (B) and the water is 0.5 to 2.5.

A one-pack moisture-curing composition of the present technology contains a preliminary composition, an adhesiveness-imparting agent containing a compound (A) and/or a compound (B), a first catalyst containing a compound (C) and/or dibutyltin bis(pentadione), and a second catalyst containing a dimorpholinodiethylether.

A polyester polyol comprising at least one esterified unit of formula (I) ##STR00001##
wherein L is a difunctional aliphatic group having from two to six carbon atoms and R is a C.sub.1-C.sub.4 alkyl group.

The invention relates to a polyurethane composition comprising one first component and one second component, said first component comprising an alkoxylated aromatic diol, a low molecular aliphatic or cycloaliphatic diol, a specific polybutadiene polyol and a specific polyetherpolyol, in specific ratios. The hardened composition is characterized by having good adhesion characteristics, a resistance which is only slightly dependent on the temperature, in the temperature range of −35 to +85° C. and also very high resistances. It is particularly suitable as a structural adhesive for bonding two substrates.

A thermoset polyisobutylene network polymer includes a polyisobutylene diol residue, a diisocyanate residue, and at least one crosslinking compound residue selected from the group consisting of a residue of a sorbitan ester and a residue of a branched polypropylene oxide polyol.

A novel polyol compound represented by Formula (I) is provided. A polyurethane-based adhesive composition comprising the polyol compound can produce an adhesive layer exhibiting superior bond strength and heat seal strength which will not be substantially deteriorated by the change in the weight ratio between isocyanate component and polyol component. Methods for preparing the polyol compound and for preparing the adhesive composition, as well as a laminate article prepared with said adhesive composition are also provided.

##STR00001##

An adhesive sealant composition of at least one moisture-crosslinkable prepolymer and an anti-sagging agent of 5% to 30% by weight of a thixotropic composition of 10% to 40% by weight of a bisurea a) obtained by reaction of a primary aliphatic amine a1) with a diisocyanate a2) having a molar mass of less than 500 g/mol, and 60% to 90% by weight of an ester b) of formula (I): ##STR00001##
in which R.sup.1, R.sup.2 and R.sup.3 are an oxycarbonylalkyl radical having from 4 to 20 carbon atoms, R.sup.4 is hydrogen, methyl or ethyl or —CH.sub.2—R.sup.5 in which R.sup.5 is oxycarbonylalkyl having from 4 to 20 carbon atoms, in the form of a suspension of solid particles of bisurea a) in a continuous phase formed by ester b).

The invention relates to dioxomolybdenum (VI) complex compounds of the formula MoO.sub.2(L).sub.x(Y).sub.2-x, where the ligand L has the formula (I). Such complex compounds are suitable in particular as catalysts for one- and two-component polyurethane compositions. The invention also relates to two-component polyurethane compositions including at least one polyisocyanate as the first component, at least one polyol as the second component, and at least one such dioxomolybdenum (VI) complex compound as the catalyst. The invention further relates to one-component polyurethane compositions comprising at least one polyurethane prepolymer with isocyanate groups, which are made from at least one polyisocyanate with at least one polyol, and comprising such a dioxomolybdenum (VI) complex compound as the catalyst. The invention additionally relates to different uses of said polyurethane compositions. ##STR00001##

In a polyurethane gel 1 including a gel layer 2 and a coat layer 3 covering the gel layer 2, the gel layer 2 is produced by allowing at least aliphatic polyisocyanate having an average functionality of more than 2.0 to react with polyol having an average functionality of 3.0 or less, and the coat layer 3 is produced by allowing at least aliphatic diisocyanate and/or alicyclic diisocyanate to react with bifunctional active hydrogen compound.