Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyisocyanate; a polyol blend, and a physical blowing agent composition. The polyol blend includes an aromatic amine-initiated polyether polyol having an OH number of at least 200 mg KOH/g and a functionality of at least 3, wherein (i) the aromatic amine-initiated polyether polyol having an OH number of at least 200 mg KOH/g is present in amount of at least 20% by weight, based on the total weight of polyol, and (ii) the polyol blend has a content of —C.sub.2H.sub.4O— units of 2 to 7% by weight, based on total weight of the polyurethane foam-forming composition. The physical blowing agent composition includes cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,1,1,4,4,4-hexafluoro-2-butene.

An aqueous polyurethane resin dispersion includes a cationic group and a polyalkylene oxide in a side chain thereof. The polyurethane resin is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing a quaternary N-atom or tertiary amino group, and a polyisocyanate. The polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin is suitable as a resin in treatment liquids of substrates and images made by inkjet printing.

Polyurethane or polyisocyanurate foam stock and methods of manufacturing are described herein. The foam stock can include (a) a polyurethane or polyisocyanurate formed by the reaction of (i) one or more isocyanates selected from the group consisting of diisocyanates, polyisocyanates, and mixtures thereof, and (ii) one or more polyols; and (b) a filler present in an amount from greater than 50% to 90% by weight, based on the total weight of the foam stock. The density of the foam stock can be from 10 lb/ft.sup.3 to 35 lb/ft.sup.3. The flexural strength of the foam stock can be at least 100 psi. The resulting foam stock can be used to produce polyurethane or polyisocyanurate foam to be used in composite panels.

A process for producing rigid PUR/PIR foams via the reaction of a reaction mixture comprising A1 an isocyanate-reactive component, A2 a flame retardant, A3 a blowing agent, A4 a catalyst, and A5 optionally auxiliaries and additives with B an organic polyisocyanate component. Component A1 comprises a diurethane diol A1.1 and a compound A1.2 selected from the group consisting of polyether polyol, polyester polyol, polyether carbonate polyol, and polyether ester polyol. Also disclosed is a rigid PUR/PIR foam, an insulating material, a composite element, and a mixture.

Polyisocyanurate (PIR) and/or polyurethane (PUR) comprising insulation foams having significantly improved long term insulation values are disclosed as well as a processing method to fabricate said improved insulation foams and use of the improved insulation foams for thermal insulation.

A structural adhesive composition having high elongation and impact resistance contains an epoxy resin, a urethane resin formed by using a polyol comprising a long chain as a functional group, and an epoxy curing agent.

The present disclosure provides for a metal chelated polyol liquid and/or a metal chelated polyether polyol liquid that can be used in an isocyanate-reactive composition and a reaction mixture for forming a polyurethane polymer. The metal chelated polyester polyol liquid is a reaction product of a chelating polyester polyol having a chelating moiety and a metal compound having a metal ion. The metal chelated polyether polyol liquid is a reaction product of a chelating polyether polyol having a chelating moiety and a metal compound having a metal ion. The chelating moiety of the chelating polyester polyol or the chelating polyether polyol chelates the metal ion to form the metal chelated polyester polyol liquid or the metal chelated polyether polyol liquid, respectively, having a mole ratio of the metal ion to the chelating moiety of 0.05:1 to 2:1.

A process for producing an amine-based polyol by reacting a tertiary amine with various epoxides in two or more steps. The present disclosure also relates to the amine-based polyol obtained by this process and the use of the amine-based polyol in the production of polyurethanes, wherein the polyurethanes are preferably synthesized based on toluene diisocyanate (TDI) and are preferably molded foams.

Described herein are a reactive composition, a semi-rigid polyurethane foam obtained therefrom, a filled cavity, and a method of use thereof in automobile parts.

A two-component adhesive composition is provided. The two-component adhesive composition comprises an isocyanate component, an isocyanate-reactive component and an polyether amine-epoxy silane adduct, and can achieve superior adhesion strength between the adhesive and a substrate like metal alloy substrate. A laminated article prepared with said composition, a method for preparing the article and the use of the polyether amine-epoxy silane adduct as adhesion promoter in a two-component polyurethane adhesive composition are also provided.