The thermoplastic polyurethane (TPU) compositions described herein have biodegradable and/or bioabsorbable hard and soft segments. The TPU hard segment can be formed from a polyisocyanate and a 2,5-substituted diketopiperazine.

The curable composition of the present invention contains (A) a cyclic monomer having both a polymerizable functional group and an ionic functional group in the molecule and (B) a polymerizable monomer having a polymerizable functional group capable of being polymerized with the polymerizable functional group of the cyclic monomer (A). The present invention can provide a curable composition that has easy handleability becoming a cured article that has high abrasion resistance and enhanced hydrophilicity without impairing the mechanical characteristics, and particularly can provide a curable composition becoming a cured article that can be favorably used as a polishing pad.

The curable composition of the present invention contains (A) a cyclic monomer having both a polymerizable functional group and an ionic functional group in the molecule and (B) a polymerizable monomer having a polymerizable functional group capable of being polymerized with the polymerizable functional group of the cyclic monomer (A). The present invention can provide a curable composition that has easy handleability becoming a cured article that has high abrasion resistance and enhanced hydrophilicity without impairing the mechanical characteristics, and particularly can provide a curable composition becoming a cured article that can be favorably used as a polishing pad.

An object of the invention is to provide a urethane resin composition containing a biomass raw material and having excellent moisture permeability and excellent film strength. The invention provides a urethane resin composition containing a urethane resin (X), the urethane resin (X) containing, as essential raw materials, a polyol (A) that contains a polyol (a1) having an oxyethylene group, and a polyisocyanate (B), in which the polyol (A) further contains a polyester polyol (a2) containing a biomass-derived glycol (i) and a crystalline polybasic acid (ii) as raw materials, and the polyol (A) has a hydroxyl equivalent in a range of 400 g/eq to 600 g/eq. In addition, the invention provides a moisture-permeable film which is formed of the urethane resin composition.

The present invention relates to a supramolecular biodegradable polymer comprising a quadruple hydrogen bonding unit (abbreviated herein as 4H-unit), a biodegradable backbone and hard blocks and a process for preparing such a supramolecular biodegradable polymer. The supramolecular polymer is specifically suitable for biodegradable articles such as biomedical implants that need high strength and/or elasticity, e.g. medical implants in the cardio-vascular field.

Provided is a polycarbonate polyol used as a raw material of a polyurethane that has an excellent balance of flexibility, mechanical strength and solvent resistance. The polycarbonate polyol includes structural units derived from a polyhydric alcohol and has a hydroxyl value of 20 to 450 mg KOH/g. The polyhydric alcohol includes: a diol (A) containing not less than 70% by weight of a specific oxyalkylene glycol (A1); and a trihydric to hexahydric branched alcohol (B) having 3 to 12 carbon atoms. In the polycarbonate polyol, structural units derived from the branched alcohol (B) is contained in an amount of 0.005 to 5.0% by mole in the structural units derived from the polyhydric alcohol. A ratio of a structural unit (X1) represented by the following Formula (X1) in the structural units derived from the branched alcohol (B) is not higher than 50% by mole.

##STR00001##

The present invention relates to a supramolecular biodegradable polymer comprising a quadruple hydrogen bonding unit (abbreviated herein as 4H-unit), a biodegradable backbone and hard blocks and a process for preparing such a supramolecular biodegradable polymer. The supramolecular polymer is specifically suitable for biodegradable articles such as biomedical implants that need high strength and/or elasticity, e.g. medical implants in the cardio-vascular field.

Provided is a 2-pack adhesive composition comprising I) pack I, which comprises a prepolymer composition (PCB), wherein the prepolymer composition (PCB) comprises one or more isocyanate functional prepolymers (FPA), wherein the isocyanate functional prepolymer (FPA) comprises polymerized units of 4,4 MDI, and wherein the prepolymer composition (PCB) comprises a total amount of all isocyanate monomers of 0 to 0.2% by weight based on the weight of prepolymer composition (PCB). and II) CA pack II, which comprises one or more amine functional polyols. Also provided is a method of making a laminate using such a 2-pack adhesive composition.

The present invention is directed to a curable and electrochemically debondable two-component (2K) adhesive composition comprising: a first component comprising: i) at least one polyol selected from the group consisting of fatty alcohols, polyester polyols, polyether polyols, polyether-polyester polyols and polycarbonate polyols: ii) optionally further active hydrogen compounds: and, iii) non-polymerizable electrolyte: and, a second component comprising at least one polyisocyanate, wherein said composition is characterized in that the molar equivalents ratio of NCO groups to active hydrogen atoms is at least 1:1.

The present invention relates to a flame retardant waterborne coating composition comprising: a) water dispersed hydroxyl-terminated polyurethane particles, and b) isocyanate crosslinker, wherein (i) the hydroxyl-terminated polyurethane contains phosponate oligomer as a building block in an amount of from 3 to 75 parts by weight relative to the hydroxyl-terminated polyurethane, wherein the phosphonate oligomer contains units according to the following structural formula in which n is an integer from 1 to 20, R is a C.sub.1-20 alkyl, C.sub.2-20 alkene, C.sub.2-20 alkyne, C.sub.5-20 cycloalkyl or C.sub.6-20 aryl, and R.sub.2 is an aliphatic or aromatic group, (ii) the hydroxyl number of the hydroxyl-terminated polyurethane is from 5 to 180 mg KOH/g polyurethane, (iii) the molar ratio of hydroxyl groups present in the hydroxyl-terminated polyurethane to isocyanate groups of the crosslinker is from 0.2 to 2.0.

##STR00001##