Methods of producing an elastomer are disclosed that include (I) applying an actinic radiation curable composition preferably selected from a urethane (meth)acrylate, an allophanate urethane (meth)acrylate or a lactone-containing (meth)acrylate to a substrate at a thickness of at least 0.25 mm (10 mils); (II) exposing the composition ultraviolet radiation to produce a cured film; and (III) removing the film from the substrate. Related compositions are also disclosed.

The invention pertains to the technical field of urethane based materials, in particular to radiation curable urethane precursors that are cross-linkable in solid form and materials obtainable therefrom. In addition the invention pertains to methods for manufacturing these precursors and materials, and their uses. The invention is advantageous to the fields of i.e. coatings and biomedical applications.

The present invention provides an active energy ray-curable composition exhibiting high curability and having excellent offset printability when used for a printing ink, an active energy ray-curable printing ink having both excellent curability and offset printability, and a printed matter using the same. An active energy ray-curable composition includes a urethane (meth)acrylate resin (A) and a polymerization initiator (B), wherein the urethane (meth)acrylate resin (A) is produced by using an aromatic polyisocyanate (a), a hydroxyl group-containing mono(meth)acrylate (b), and a polyol (c) as essential reaction raw materials so that the ratio [(b)/(a)] of the number of moles (b) of hydroxyl groups contained in the hydroxyl group-containing mono(meth)acrylate (b) to the number of moles (a) of isocyanate groups contained in the aromatic polyisocyanate (a) is within a range of 0.99 to 0.40, and the urethane (meth)acrylate resin (A) has a (meth)acryloyl group concentration within a range of 1.5 to 4.0 mmol/g.

Fiber coatings with low Young's modulus, high tear strength, and/or high critical stress are realized with coating compositions that include an oligomeric material formed from an isocyanate, a hydroxy acrylate compound and a polyol. The oligomeric material includes a polyether urethane acrylate and a di-adduct compound. The reaction mixture used to form the oligomeric material includes a molar ratio of isocyanate:hydroxy acrylate:polyol of n:m:p, where when p is 2, n is in the range from 3.0 to 5.0 and m is in the range from 1.50n-3 to 2.50n-5. Control of the n:m:p ratio leads to compositions that, when cured, provide coatings and cured products having high critical stress, high tear strength, and a high ratio of tear strength to Young's modulus.

A thermoplastic resin composition and a molding product made therefrom are provided. The thermoplastic resin composition includes a branched copolymer obtained from a copolymerization of a urethane compound and a copolymerizable monomer, wherein the urethane compound is obtained from reaction of a (meth)acrylate compound containing hydroxyl group and a triisocyanate compound.

A hard coating film is provided. The hard coating film includes: a substrate; a first hard coating layer formed on one surface of the substrate; and a second hard coating layer formed on the other surface of the substrate, wherein the first hard coating layer has a corrected breaking strength of 50 to 500 MPa. and an image display device having the hard coating film. The hard coating film has excellent impact resistance as well as excellent bending resistance.

A thermoplastic resin composition and a molding product made therefrom are provided. The thermoplastic resin composition includes a branched copolymer obtained from a copolymerization of a urethane compound and a copolymerizable monomer, wherein the urethane compound is obtained from reaction of a (meth)acrylate compound containing hydroxyl group and a triisocyanate compound.

A structure having dry-wiping off characteristic relative to dirt attached to a concave-convex shaped surface of the structure, and a method for producing the structure. A structure having a concave-convex shaped surface, fabricated from a composition containing at least one compound having in a molecule, one to ten polymerizable group(s) and a photopolymerization initiator, wherein the structure has a Martens hardness of 3 N/mm.sup.2 or more and 130 N/mm.sup.2 or less when the Martens hardness of the structure is measured under a condition under which a Martens hardness of a molten quartz is 4,100 N/mm.sup.2. The structure is produced by applying the composition onto a substrate; pressing a coating film on the substrate into a concave-convex shaped face of a mold; photocuring the coating film while it is pressed into the concave-convex shaped face of the mold; and peeling the cured film on the substrate from the mold.

Nonaqueous coating material compositions comprising at least one polyhydroxyl and (per)fluoroalkyl group-containing poly(meth)acrylate component (A), at least one polyisocyanate group-containing compounds (B), and one or more catalysts (D). Also provided are multistage coating methods using the coating material compositions, and also the use of the coating material compositions as a clearcoat material and for coating of wind energy systems or aircraft, or parts thereof, more particularly as an anti-icing coating.