The invention relates to a high pressure laminate panel having a surface layer on at least one panel surface, which has as the outermost layer a polymer coating with a polyurethane(meth)acrylate polymer, and which is characterized by excellent scratch resistance and resistance to weathering. Furthermore, a method for the production of polyurethane(meth)acrylate-coated high pressure laminate panels is provided.

Polyurethane foam compositions and processes to make flexible polyurethane foams are disclosed. Polyurethane foam is produced in the presence of additives comprising guanidine derivatives. Improvements in physical properties such as air flow, dimensional stability, tensile, tear, elongation and foam hardness is observed when these additives are present in polyurethane formulations. In addition, these additives can minimize polymer degradation under humid ageing conditions resulting in foam products with better mechanical properties.

Provided is an active energy ray curable resin which has excellent compatibility with organic solvents, general purpose acrylic monomers, and oligomers, and a high curing property with an active energy ray, and also has a high adhesion property for each substrate. A cured film obtained by ultraviolet curing of the active energy ray curable resin has an excellent surface curing property, scratch resistance and bending resistance, while also having high transparency. Provided is a urethane modified (meth)acrylamide compound having a urethane bond and one or more (meth)acrylamide groups in the molecule. The urethane modified (meth)acrylamide compound has excellent compatibility with organic solvents, general purpose acrylic monomers, and oligomers, and exhibits a high curing property with an active energy ray. Also provided is an active energy ray curable resin which is obtained with the urethane modified (meth)acrylamide compound and has an excellent surface curing property, scratch resistance, and bending resistance.

[Problem] An problem of the present invention is to provide to a (meth)acrylamide-based urethane oligomer which has excellent compatibility with organic solvents, general purpose acrylic monomers and oligomers, and a high curing speed to active energy rays, and to provide an active energy ray curable resin composition which contains the urethane oligomer, has excellent adhesion, moisture resistance and surface curability, and has low curing shrinkage, and a formed product thereof [Means for Solution] By using a (meth)acrylamide-based urethane oligomer of the present invention which has a carbonate skeleton, a diene-based skeleton or a hydrogenated diene-based skeleton in the molecule, one or more (meth)acrylamide groups and a component having a molecular weight of less than 1,000 (excluding a (meth)acrylamide compound (A) having a hydroxyl group) at a content of 5% by weight or less, it is possible to obtain a urethane oligomer which has excellent compatibility with organic solvents, general purpose acrylic monomers and oligomers, and a high curability and to obtain an active energy ray curable resin composition which contains the urethane oligomer and has excellent adhesion, tack resistance, moisture resistance and shrinkage resistance.

Processes for preparing a polymer polyol (PMPO) in which a base polyol is continuously produced in a continuous base polyol reactor, the base polyol is continuously discharged from the continuous base polyol reactor; the base polyol is continuously introduced to a continuous PMPO reactor, which is different from the continuous base polyol reactor, and PMPO is continuously removed from the PMPO reactor. Production plant configured to carry out such processes are also described.

A holographic recording medium composition comprising components (a) to (d) below, wherein an amount of allophanate bond units contained in the component (a) relative to a total weight of the components (a) and (b) is 6.510.sup.4 mol/g or more: component (a): an isocyanate group-containing compound; component (b): an isocyanate-reactive functional group-containing compound; component (c): a polymerizable monomer; and component (d): a photopolymerization initiator.

An problem of the present invention is to provide to a (meth)acrylamide-based urethane oligomer which has excellent compatibility with organic solvents, general purpose acrylic monomers and oligomers, and a high curing speed to active energy rays, and to provide an active energy ray curable resin composition which contains the urethane oligomer, has excellent adhesion, moisture resistance and surface curability, and has low curing shrinkage, and a formed product thereof

[Means for Solution]

By using a (meth)acrylamide-based urethane oligomer of the present invention which has a carbonate skeleton, a diene-based skeleton or a hydrogenated diene-based skeleton in the molecule, one or more (meth)acrylamide groups and a component having a molecular weight of less than 1,000 (excluding a (meth)acrylamide compound (A) having a hydroxyl group) at a content of 5% by weight or less, it is possible to obtain a urethane oligomer which has excellent compatibility with organic solvents, general purpose acrylic monomers and oligomers, and a high curability and to obtain an active energy ray curable resin composition which contains the urethane oligomer and has excellent adhesion, tack resistance, moisture resistance and shrinkage resistance.

The present invention relates to an inkjet composition having 1.0-5.0 mol/kg acryloyl groups comprising: i) photo polymerization reactive compound (M) containing exactly one acryloyl group, ii) photo polymerization reactive compound (N) containing at least two acryloyl groups, iii) radical photoinitiator (R), iv) cyanate ester compound (D) containing at least two cyanate groups and v) cyanate ester curing catalyst (C), wherein (M) is different from (D) and (N) is different from (D), 25-50 mol % of the contained acryloyl groups are provided by the reactive compound (N) and the molar ratio of contained acryloyl groups to contained cyanate groups of compound (D) is 0.30 to 0.95.

A polyurethane-resin-forming composition including a polyisocyanate prepolymer (A) and a polyol (B) is disclosed. The polyisocyanate prepolymer (A) contains a reaction product of diphenylmethane diisocyanate (a1-1) and/or modified diphenylmethane diisocyanate (a1-2), and an active hydrogen-containing compound (a2), the polyol (B) includes a transesterification product (b1) of a castor oil-based polyol and a hydroxyl group-containing amine-based compound, a hydroxyl group-containing amine-based compound (b2), and a castor oil-based polyol (b3), a content of the transesterification product (b1) is 0.1 mass % or more and 10 mass % or less with respect to a total mass of the polyisocyanate prepolymer (A) and the polyol (B).

A compound is described having following formula: (I) Also described is a mixture of compounds comprising the reaction product of i) a urethane compound comprising a perfluorooxyalkyl moiety and at least two (meth)acryl groups; and ii) a silane compound comprising hydrolysable groups and a group selected from amine or mercapto group; wherein i) and ii) are reacted at an equivalent ratio of excess compound i) such that (meth)acryl groups remain unreacted. Methods and articles are also described. ##STR00001##