The present invention pertains to polyurethane-urea based optical adhesives for formation of optical film laminates, optically functional film laminates, and ophthalmic or eyeglass lenses employing the same and methods for producing the same.

Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and, optionally, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and optionally, a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

This disclosure provides a fluorine-containing mixture and a fluorine-containing super-oleophobic microporous membrane using the fluorine-containing mixture as a raw material, as well as preparation methods and applications for the fluorine-containing mixture and the fluorine-containing super-oleophobic microporous membrane. The fluorine-containing mixture of the present disclosure comprises, by weight percentage, the following components: Component A: 50%˜90%; Component B: 3%˜25%; Component C: 0%˜35%; Component D: 0%˜3%; wherein Component A comprises high molecular weight polytetrafluoroethylene homopolymer or copolymer dispersion resin; Component B comprises one or more fluorine-containing alkyl acrylate monomers; Component C comprises one or more fluorine-free acrylates; Component D comprises high temperature free radical initiator. There's no need to add inflammable or explosive lubricating oil, making the process highly safe; and the obtained fluorine-containing super-oleophobic microporous membrane has high waterproof, air-permeable, oil-resistant and washable performance, in line with the needs of a new generation of waterproof and air-permeable protective clothing.

A biomedical device is disclosed which is a polymerization product of a mixture comprising (a) one or more difunctional isocyanates; (b) one or more polyalcohols; (c) one or more hydroxy-terminated polysiloxane prepolymers; and (d) one or more polyoxazoline polyols having a weight average molecular weight of equal to or greater than about 1000 Daltons.

The present invention provides a surface protective film which includes an adhesive layer on one surface of a substrate film, wherein the adhesive layer is a cured product of a composition containing: a urethane-based resin having a photoreactive group at the end or side chain thereof; a monofunctional (meth)acrylate monomer; a crosslinking agent having two or more photoreactive groups at the end thereof; a peel strength adjusting agent; and a photoinitiator, the composition being solvent-free; and the adhesive layer has peel strength of 0.5 gf/in to 10 gf/in, as measured on glass at a peel angle of 180° and a peel rate of 1.8 m/min.

The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, obtainable by (I) preparing a composition (Z) comprising based each case on the total amount of the composition (Z), (Z.1) 15 to 65 wt % of at least one intermediate containing isocyanate groups and having blocked primary amino groups, its preparation comprising the reaction (Z.1.1) of at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, with (Z.1.2) at least one polyamine comprising at least two blocked primary amino groups and at least one free secondary amino group, by addition reaction of isocyanate groups from (Z.1.1) with tree secondary amino groups from (Z.1.2), (Z.2) 35 to 85 wt % of at least one organic solvent which possesses a solubility in water, of not more than 38 wt % at a temperature of 20° C., (II) dispersing the composition (Z) in aqueous phase, and (III) at least partly removing the at least one organic solvent (Z.2) from the dispersion obtained in (II), The present invention also relates to basecoat materials comprising the dispersion (PD), and to multicoat paint systems produced using the basecoat materials.

An article is prepared by injection molding, wherein the article is formed from a hydrophilic thermoplastic polyurethane composition, wherein the thermoplastic polyurethane composition comprises the reaction product of a hydroxyl terminated polyol intermediate component, an aliphatic isocyanate component, and, optionally, a chain extender component. For injection molding, the hydrophilic thermoplastic polyurethane has a crystallization temperature measured by dynamic scanning calorimetry of at least 75° C.

An isocyanate composition according to the present invention contains: a difunctional or more-functional isocyanate compound; and 1.0 ppm by mass to 1.0×10.sup.4 ppm by mass, based on the isocyanate compound, of a compound having at least one unsaturated bond excluding unsaturated bonds constituting an aromatic ring, the compound being different from the isocyanate.

Provided is a method for producing a resin lens, comprising: A) mixing a polyisocyanate, a modified isocyanate, a catalyst and a release agent, and performing vacuum defoaming at 0˜30° C. for 10˜90 min to obtain a material a; B) mixing the material a with a sulfur-containing compound, and performing vacuum defoaming at 15˜20° C. for 20˜120 min to obtain mixed monomers; and C) completing casting of the mixed monomers, and curing to obtain a resin lens. The present disclosure uses polyisocyanate and a modified isocyanate at the same time to prepare a resin lens with higher glass transition temperature and higher surface hardness without producing bank mark and edge fogging. The present disclosure further provides a method for producing modified isocyanate. The obtained modified isocyanate used with polyisocyanate further improves the glass transition temperature and surface hardness of the resin lens without producing bank mark and edge fogging.

In the composition according to the embodiment, the content of an unreacted diisocyanate monomer in a urethane-based prepolymer may be controlled to control the physical properties thereof such as gelation time. Thus, since the micropore characteristics, polishing rate, and pad cut rate of a polishing pad obtained by curing the composition according to the embodiment may be controlled, it is possible to efficiently manufacture high-quality semiconductor devices using the polishing pad.