C08G18/7657

TRANSLUCENT POLYURETHANE OR POLYISOCYANURATE FOAMS
20220049044 · 2022-02-17 ·

The present invention relates to a process for producing translucent polyurethane and polyisocyanurate foams by reaction of a component A comprising A1 at least one polyol reactive with the component B; A2 optionally at least one amine; A3 water and optionally formic acid; A4 at least one foam stabilizer; A5 optionally auxiliary and/or additive substances; A6 optionally at least one flame retardant; A7 at least one catalyst; and a component B comprising B1 at least one aliphatic or cycloaliphatic polyisocyanate component or a combination thereof; and B2 optionally at least one hydrophilized isocyanate; and B3 less than 20 parts by weight of an aromatic polyisocyanate component, wherein the parts by weight of B3 are based on the sum of the parts by weight of B1 to B3 normalized to 100 parts by weight, characterized in that the reaction of the component A with the component B is carried out at an isocyanate index of at least 150, wherein the obtained translucent polyurethane and polyisocyanurate foams have a light transmission according to EN ISO 13468-2:2006 of at least 10% and a haze of at least 70%, determined according to ASTM D1003-13, in each case measured at a layer thickness of 20 mm. The present invention further relates to polyurethane and polyisocyanurate foams obtained by the process and to the use thereof as a construction element, as a wall element, as a floor element, in buildings, in vehicles or lamps.

TWO-COMPONENT BINDER SYSTEM FOR THE POLYURETHANE COLD-BOX PROCESS

A description is given of a two-component binder system particularly for use in the polyurethane cold box process, a mixture for curing by contacting with a tertiary amine, a method for producing a feeder, a foundry mold or a foundry core, and also feeders, foundry molds and foundry cores producible by this method, and the use of a two-component binder system of the invention or of a mixture of the invention for binding a mold raw material or a mixture of mold raw materials, in particular in the polyurethane cold box process.

STORAGE-STABLE, MOISTURE-CURING POLYURETHANE ADHESIVE WITH RAPID ADHESIVE FORMATION ON GLASS
20170275509 · 2017-09-28 · ·

A moisture-curing adhesive composition has a) at least one polyurethane polymer having isocyanate groups, b) at least a silane adhesion promoter, c) at least one amine catalyst, and d) at least one chelate complexing agent. Compositions are suitable especially as adhesive or sealant, in particular for glass panes, for example in vehicle construction or vehicle repair, wherein the use of a primer or activator can be dispensed with.

LOW EMISSIONS POLYURETHANE FOAM MADE WITH ISOCYANATE REACTIVE AMINE CRYSTALS
20170247495 · 2017-08-31 ·

Tertiary amine catalysts having isocyanate reactive groups capable of forming thermally stable covalent bonds able to withstand temperatures from 120° C. and higher and up to 250° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60); b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

Polyurethane foam compositions and process for making same
09745440 · 2017-08-29 ·

The present invention generally relates to polyurethane foam composition. In one embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more liquid and/or solid fire-retardants. In another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more intumescent materials (e.g., expandable graphite (EG)). In still another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of expandable graphite.

ADHESIVE COMPOSITIONS WITH POLYESTERS COMPRISING 2,2,4,4-TETRAALKYL-1,3-CYCLOBUTANEDIOL AND METHODS OF MAKING THE SAME

Adhesive compositions comprise a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

Continuous Process For Forming A Unitary Mat
20170225355 · 2017-08-10 ·

A continuous process forms a unitary mat on a line having at least two conveyors spaced from each other. The process includes combining the isocyanate, an isocyanate catalyst, and a plurality of lignocellulosic particles to form a mixture and a self-polymerization product of the isocyanate in-situ in the mixture. The process also includes forming the unitary mat from the mixture on a first conveyer and transferring the unitary mat from the first conveyor to a second conveyor across a predetermined distance while maintaining structural integrity of the unitary mat. The lignocellulosic particles have a moisture content of 0.5 to 30 weight percent of water. Moreover, the continuous process is free of a step of adding water to the isocyanate, the isocyanate catalyst, the lignocellulosic particles, and/or the unitary mat.

Moisture Vapor Transmission Thermoplastic Polyurethane with High Heat Resistance
20170226265 · 2017-08-10 ·

The present invention relates to novel thermoplastic polyurethanes (TPU) that contain alkylene substituted spirocyclic compounds. The present invention provides for TPU which exhibit high temperature resistance.

FLAME-RETARDANT POLYURETHANE MATERIALS

In an example, a process of forming a flame-retardant polyurethane material includes chemically reacting a polyisocyanate (that includes at least three isocyanate groups) with a phosphonate that includes at least one hydroxyl group to form a polyisocyanate-phosphonate compound. The process also includes forming a mixture that includes the polyisocyanate-phosphonate compound and a polyol. The process further includes polymerizing the mixture to form a flame-retardant polyurethane material.

Catalyst composition for producing polyurethane resin, and method for producing polyurethane resin using said catalyst composition
09725553 · 2017-08-08 · ·

To provide a catalyst composition excellent in cell openness properties and initial curing properties, and a method for producing a polyurethane resin using the same. A catalyst composition comprising an amine compound (A) of the formula (1), a hydroxy acid (B) of the formula (2) and a tertiary amine compound (C) is used for the production of a polyurethane resin. [Each of R.sub.1 and R.sub.2 which are independent of each other, is a methyl group or an ethyl group, R.sub.3 is a C.sub.2-4 linear or branched alkyl group, R.sub.4 is a C.sub.1-18 bivalent hydrocarbon residue, m is an integer of from 1 to 3, and n is an integer of from 1 to 6.] ##STR00001##