This blocked polyisocyanate composition contains a block polyisocyanate derived from one or more diisocyanates, an active hydrogen compound, and a blocking agent containing a malonic acid ester. The active hydrogen compound has a number-average molecular weight of 60 to 5,000 and an average of 1.6 to 2.4 functional groups.

This blocked polyisocyanate composition contains a block polyisocyanate derived from one or more diisocyanates, an active hydrogen compound, and a blocking agent containing a malonic acid ester. The active hydrogen compound has a number-average molecular weight of 60 to 5,000 and an average of 1.6 to 2.4 functional groups.

The present invention provides a blocked isocyanate composition comprising a blocked isocyanate compound in which an isocyanate group of an isocyanate compound is blocked with a fluoroalcohol compound, and at least one amidate compound represented by the following Formula (2):

##STR00001##

wherein B, G, J, R.sup.7. and R.sup.8 are as defined in the specification.

To provide an antifogging agent composition having excellent sustainability of antifogging performance.

An anti fogging agent composition includes a copolymer (A), a polyfunctional blocked isocyanate compound (B), and a surfactant (C). The copolymer (A) is formed of 35 to 90 parts by weight of the monomer (A-1), 5 to 60 parts by weight of the monomer (A-2), and 5 to 30 parts by weight of the monomer (A-3) per 100 parts by weight of the copolymer (A). An NCO/OH ratio obtained by dividing an isocyanate group content (NCO) of the polyfunctional blocked isocyanate compound (B) by a hydroxyl group content (OH) of the copolymer (A) is within a range from 0.1 to 1.5. The surfactant (C) includes 1.00 to 10.0 parts by weight of the anionic surfactant (C-1) and 0.01 to 3.00 parts by weight of the cationic surfactant (C-2) per 100 parts by weight of the copolymer (A).

A water-based coating composition and method for forming a multi-layer coating film by which it is possible to form a coating film 5 having excellent smoothness, image clarity, and chipping resistance in a 3C1B format. The composition is characterized by containing 7 to 60 mass % of an acrylic resin emulsion (a), 10 to 60 mass % of a film-forming resin (b), and 10 10 to 50 mass % of a curing agent (c), on the basis of the total mass of the solid resin content in the composition; the acrylic resin emulsion (a) having a core/shell structure where the core section contains, as a copolymer component, 0.1 to 10 mass % of a polymerizable unsaturated 15 monomer having two or more polymerizable unsaturated groups in one molecule, on the basis of the total mass of monomer of the core section, and the hydroxyl value of the core section is 50 to 200 mgKOH/g, and the hydroxyl value of the shell section is 50 to 200 mgKOH/g.

The present invention relates to a photochromic article that includes a substrate and a photochromic layer formed from a curable photochromic composition. The photochromic composition includes a polyol component that includes a polycarbonate diol, an isocyanate component that includes an unblocked polyfunctional isocyanate and/or a blocked polyfunctional isocyanate, and at least one photochromic compound. The equivalents ratio of blocked/unblocked isocyanate equivalents of the isocyanate component to hydroxyl equivalents of the polyol component is at least 5:1. The photochromic article exhibits a T.sub.1/2 (Fade Half Life) at 23° C. of less than or equal to 70 seconds.

The present invention relates to a process for bonding substrates, wherein the bond is a bond that can be released by heat treatment at a temperature of 50° C. to less than 200° C. and a composition is used to produce the bond, said composition containing a polymer of formula (I): Q-(O—C(O)—CR′R″—C(O)—R).sub.x, where: Q=a polymer group, selected from a polyester group and/or a polyolefin group, wherein the polymer group does not contain any components that result from the use of molecules having (meth)acrylic acid units as monomers; x is greater than or equal to 1; R.sup.1=R.sup.2 or O—R.sup.3; R2=a hydrocarbon group, which can be substituted with halogen atoms, comprising 1 to 10 carbon atoms; R3=a hydrocarbon group, which can be substituted with halogen atoms, comprising 1 to 10 carbon atoms, or a polymer group; R′=—H, or a hydrocarbon group, which can be substituted with halogen atoms, comprising 1 to 10 carbon atoms, or a group of formula (II): —C(O)—NH-Q′, where Q′=an organic group which can also have one or more silicon atoms; and R″=—H or a group of formula (II), with the proviso that if neither of the groups R′ and R″ is a group of formula (II), then at least one of the groups R′ or R″ is —H.

Disclosed is a composition for reactive hot melt resin and a reactive hot melt film prepared from the resin, which resin composition includes a polyurethane resin having a linear structure, an isocyanate blocking agent having a plurality of functional groups, a reaction catalyst, a reaction retardant, etc. Preferably, the resin composition includes a polyurethane resin and an isocyanate blocking agent used as a latent curing agent, which are main components; a catalyst for accelerating the reaction; and a reaction retardant for securing long-term storability. Particularly, the composition for reactive hot melt resin further includes a heat-resistance enhancer, preferably nanosilica, for preventing the resin from melting down during no-sew press treatment to provide a performance to help maintenance of adhesion.

The present invention provides a blocked polyisocyanate composition comprising a blocked polyisocyanate formed through blocking at least a part of isocyanate groups possessed by a polyisocyanate derived from one or two or more diisocyanates selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with an active methylene-based compound comprising a malonic acid diester, wherein a specific molar ratio calculated from contents (mol %) of isocyanurate groups, iminooxadiazinedione groups, uretdione groups, and allophanate groups is 0.05 or more and 0.60 or less.

Provided are adhesives containing a phenoxy resin grafted with methyl methacrylate (MMA) and/or methacrylic acid (MAA), and including a uretdione or a silane. The adhesive compositions are completely or substantially absent free isocyanate. The grafted phenoxy resin forms crosslinking which allows the adhesive to chemisorb to a metal surface, diffuse and entangle in a urethane elastomer and/or provide crossbridging and/or crosslinking across an interface of the adhesive and a cast urethane. Methods of adhering a castable urethane to a substrate, using the provided adhesives, are also provided.