Provided is a polymer capable of providing a coating film that has good initial adhesiveness to a base material and good adhesiveness thereto after a pressure cooker test, and has excellent abrasion resistance as determined by a falling sand abrasion test. The polymer includes a perhaloolefin unit, a vinyl ester unit that contains neither a hydroxy group nor an aromatic ring; and a hydroxy group-containing monomer unit. The polymer has a hydroxyl value of 110 mgKOH/g or greater.

The present invention provides a coating film having a structure represented by the following general formula (1) (in the formula, R.sup.11 is a residue formed by removing one isocyanate group from a polyisocyanate, and R.sup.12 is an alkyl group or an alkoxy group having 2 to 12 carbon atoms, R.sup.13 is a residue formed by removing one hydroxyl group from a polyol), wherein a König hardness of the coating film is 20 or more, in an SS curve measurement of a tensile test, the coating film has an elastic deformation region and a plastic deformation region, and in the SS curve measurement, a stress at an inflection point stress between the elastic deformation region and the plastic deformation region is 5 MPa or more.

##STR00001##

A method of applying a material comprising a fusible polymer comprises the step of: applying a filament of the at least partly molten material comprising a fusible polymer from a discharge opening of a discharge element to a first substrate. The fusible polymer has the following properties: a melting point (DSC, differential scanning calorimetry; 2nd heating at heating rate 5° C./min) within a range from ≥35° C. to ≤150° C.; a glass transition temperature (DMA, dynamic-mechanical analysis to DIN EN ISO 6721-1:2011) within a range from ≥−70° C. to ≤110° C.;
wherein the filament, during the application process, has an application temperature of ≥100° C. above the melting point of the fusible polymer for ≤20 minutes. There are furthermore blocked NCO groups present in the material comprising the fusible polymer.

Disclosed herein is a coating composition obtained by mixing a resin and/or hardener; a sagging control agent (SCA) reactive to resin and/or hardener; and a catalyst. Further disclosed herein are methods of preparing 1K and 2K coating compositions and using the coating compositions in an automotive to form a clearcoat.

A curable composition includes a blocked isocyanate in which an NCO group of an isocyanate compound having a H.sub.6XDI skeleton is blocked by a blocking agent having an O═C—CH—C═O skeleton, a curable functional group-containing fluorine polymer, and an alkoxysilane having a functional group including at least one element of a group 15 element to a group 16 element of the periodic table (excluding oxygen). In the curable composition allowing a titanium oxide to be contained, the molar ratio of the curable functional group to the NCO group is 0.5 to 10; the content ratio of the alkoxysilane with respect to 100 pans by mass of the total amount of the blocked isocyanate and the fluorine polymer is 0.2 to 8 parts by mass; and the content ratio of the titanium oxide with respect to 100 parts by mass of the fluorine polymer is 0 to 200 parts by mass.

A precursor formulation of a liner comprising a polymer and at least two curatives is disclosed. One of the at least two curatives comprises a curative formulated to preferentially react with the polymer and the other of the at least two curatives comprises a blocked curative formulated to be substantially unreactive with the polymer. A method of lining a rocket motor is also disclosed, as is a rocket motor including the liner.

The present invention relates to a polyisocyanate composition comprising a formation component having isocyanate groups, the isocyanate groups having been reacted to an extent of ≥98% with at least one CH-acidic compound, characterized in that the formation component consists to an extent of ≥51% by weight of at least one polyisocyanate based on pentamethylene 1,5-diisocyanate having a content of isocyanurate trimer of ≤60 area %, based on the total weight of the polyisocyanates based on pentamethylene 1,5-diisocyanate, and the remaining proportion up to 100% by weight of the total amount of polyisocyanates present in the formation component consists of at least one aliphatic or cycloaliphatic polyisocyanate. The present invention further provides a one-component system comprising the polyisocyanate composition, a process for producing a coating on a substrate, and the coatings obtainable from the one-component system.

A method of applying a material comprising a fusible polymer comprises the step of: applying a filament of the at least partly molten material comprising a fusible polymer from a discharge opening of a discharge element to a first substrate.

The fusible polymer has the following properties: a melting point (DSC, differential scanning calorimetry; 2nd heating at heating rate 5° C./min) within a range from ≥35° C. to ≤150° C.; a glass transition temperature (DMA, dynamic-mechanical analysis to DIN EN ISO 6721-1:2011) within a range from ≥−70° C. to ≤110° C.;
wherein the filament, during the application process, has an application temperature of ≥100° C. above the melting point of the fusible polymer for ≤20 minutes.

There are furthermore blocked NCO groups present in the material comprising the fusible polymer.

The invention relates a polyacrylate-polysilane block copolymer of general structure (I): wherein m and n independent of one another, are integers ranging from 2 to 4000; p is an integer ranging from 0 to 5; q is an integer ranging from 1 to 5; R.sup.1 represents hydrogen, straight-chain or branched alkyl group having 1 to 4 carbon atoms; R.sup.2 represents hydrogen, straight-chain or branched alkyl group having 1 to 18 carbon atoms; R3 represents hydrogen, hydroxyl group, straight-chain or branched alkyl group having 1 to 4 carbon atoms, or an C.sub.6-C.sub.14 aryl group; L is a linking moiety representing amine (—NH—) group, amide (—C(O)NH—) group, urea (—NHC(O)NH—) group, urethane (—OC(O)NH—) group or methylene (—CH.sub.2—) group; R.sup.4, R.sup.5 and R.sup.6 independent of one another, represents hydrogen, straight-chain or branched, alkyl group having 1 to 8 carbon atoms or polydimethylsiloxane group; and R.sup.7 represents hydrogen or methyl group. ##STR00001##

Crosslinkers based on alkoxysilanes and alkoxysilane mixtures containing an isocyanate group can be used as a starting component in the production of coating compositions or as paint binder component, or can be used with adhesive o sealant binders o binder components having g ups reactive toward alkoxysilane groups.