Patent classifications
C09K8/905
Decreasing proppant embedment with amine-functionalized polysaccharides
Proppant embedment can sometimes be problematic during fracturing operations. A partially oxidized, amine-functionalized polysaccharide comprising a plurality of oxidatively opened monosaccharide units and bearing an amine moiety at one or more sites of oxidative opening may lessen the amount of proppant embedment that occurs. Fracturing methods may comprise providing a fracturing fluid comprising such a partially oxidized, amine-functionalized polysaccharide and a plurality of proppant particulates, introducing the fracturing fluid into a subterranean formation at a hydraulic pressure sufficient to create or extend one or more fractures therein, such that at least a portion of the plurality of proppant particulates become localized in the one or more fractures, and releasing the hydraulic pressure. Upon releasing the hydraulic pressure, embedment of the proppant particulates in a face of the one or more fractures is about 10% to about 40% of a grain size of the proppant particulates.
Hydrocarbon formation treatment micellar solutions
A hydrocarbon formation treatment micellar solution fluid and its use in treating underperforming hydrocarbon formations is described and claimed. A hydrocarbon formation treatment micellar solution fluid wherein the micellar solution fluid comprises water, a non-terpene oil-based moiety, a brine resistant aqueous colloidal silica sol; and optionally a terpene or a terpenoid, wherein the brine resistant aqueous colloidal silica sol has silica particles with a surface that is functionalized with at least one moiety selected from the group consisting of a hydrophilic organosilane, a mixture of hydrophilic and hydrophobic organosilanes, or a polysiloxane oligomer, wherein the brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter, and wherein, when a terpene or terpenoid is present, the ratio of total water to terpene or terpenoid is at least about 15 to 1.
DECREASING PROPPANT EMBEDMENT WITH AMINE-FUNCTIONALIZED POLYSACCHARIDES
Proppant embedment can sometimes be problematic during fracturing operations. A partially oxidized, amine-functionalized polysaccharide comprising a plurality of oxidatively opened monosaccharide units and bearing an amine moiety at one or more sites of oxidative opening may lessen the amount of proppant embedment that occurs. Fracturing methods may comprise providing a fracturing fluid comprising such a partially oxidized, amine-functionalized polysaccharide and a plurality of proppant particulates, introducing the fracturing fluid into a subterranean formation at a hydraulic pressure sufficient to create or extend one or more fractures therein, such that at least a portion of the plurality of proppant particulates become localized in the one or more fractures, and releasing the hydraulic pressure. Upon releasing the hydraulic pressure, embedment of the proppant particulates in a face of the one or more fractures is about 10% to about 40% of a grain size of the proppant particulates.
SALT TOLERANT FRICTION REDUCER
Provided are water-soluble polymers that may include a water-soluble bipolymer, a water-soluble anionic terpolymer, and a water-soluble cationic terpolymer. The water-soluble polymers may include a reaction product of a first monomer that has a vinyl-containing group linked to a pendant carbohydrate moiety; a second monomer that has a vinyl group, a carbonyl group and a nitrogen; an anionic monomer in a water-soluble anionic terpolymer; and a cationic monomer in a water-soluble cationic terpolymer. Further provided are aqueous solutions that may include a water-soluble bipolymer, a water-soluble anionic terpolymer, and a water-soluble cationic terpolymer. Further provided are methods of use that may include introducing an aqueous solution into a formation such that the formation fractures, where the aqueous solution may include a water-soluble bipolymer, a water-soluble anionic terpolymer, and a water-soluble cationic terpolymer.
Modified biopolymers for diversion, conformance, and fluid loss control
Well treatments that use modified biopolymers for diversion, conformance, fluid loss control, and/or other well treatments, including a method of providing conformance, fluid loss control, or diversion in a subterranean formation, may include providing a treatment fluid including a base fluid and hydrogel particles which may include modified biopolymers that are crosslinked, the modified biopolymers may include a biopolymer backbone and side chains derived from synthetic monomers; and introducing the treatment fluid into a subterranean formation penetrated by a wellbore.
Composition and Method for Breaking Synthetic-Polymer-Type Stimulation Fluids
Disclosed herein are breaking additives and methods for use with synthetic polymer-type fracturing fluids. Compared with polysaccharide-type gelling agents, such as guar and guar derivatives, synthetic-polymers such as polyacrylamide-type gelling agents are more difficult to break using common oxidizing breakers because their backbones are composed of strong carbon-carbon bonds.
STORABLE LIQUID SUSPENSION OF HOLLOW PARTICLES
Provided are compositions and methods of using a liquid suspension of hollow particles comprising a plurality of hollow particles, water, a suspending aid, and a stabilizer selected from the group consisting of a non-ionic surfactant, a latex, an oleaginous fluid, porous silica, and combinations thereof. The liquid suspension is homogenous. An example method includes statically storing the liquid suspension in a container for at least one week; wherein the liquid suspension maintains a difference in density from the top of the container to the bottom of the container of less than one pound per gallon while stored. The method further includes adding the liquid suspension to a treatment fluid; wherein the liquid suspension reduces the density of the treatment fluid; and introducing the treatment fluid into a wellbore penetrating a subterranean formation.
Brine resistant silica sol
A brine resistant silica sol is described and claimed. This brine resistant silica sol comprises an aqueous colloidal silica mixture that has been surface functionalized with at least one moiety selected from the group consisting of a monomeric hydrophilic organosilane, a mixture of monomeric hydrophilic organosilane(s) and monomeric hydrophobic organosilane(s), or a polysiloxane oligomer, wherein the surface functionalized brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter.
HYDROCARBON FORMATION TREATMENT MICELLAR SOLUTIONS
A hydrocarbon formation treatment micellar solution fluid and its use in treating underperforming hydrocarbon formations is described and claimed. A hydrocarbon formation treatment micellar solution fluid wherein the micellar solution fluid comprises water, a non-terpene oil-based moiety, a brine resistant aqueous colloidal silica sol; and optionally a terpene or a terpenoid, wherein the brine resistant aqueous colloidal silica sol has silica particles with a surface that is functionalized with at least one moiety selected from the group consisting of a hydrophilic organosilane, a mixture of hydrophilic and hydrophobic organosilanes, or a polysiloxane oligomer, wherein the brine resistant aqueous colloidal silica sol passes at least two of three of these brine resistant tests: API Brine Visual, 24 Hour Seawater Visual and API Turbidity Meter, and wherein, when a terpene or terpenoid is present, the ratio of total water to terpene or terpenoid is at least about 15 to 1.
Nanocelluloses and biogums for viscosity modification
A variety of systems, methods and compositions are disclosed for a treatment fluid comprising a nano-cellulose and a gum. An example method may comprise providing a treatment fluid wherein the treatment fluid comprises: a base fluid; a nano-cellulose; and a gum; and introducing the treatment fluid into a well bore penetrating a subterranean formation.