Provided are polymers, which may be crosslinked to form a main-chain liquid crystalline (LC) hydrogel with a three-dimensional network. Also provided are methods of using the hydrogel as a substrate for tissue culture. For example, the hydrogel may organize into LC phases and encapsulate a plurality of cells within its polymeric network. In some embodiments, human stem cells are cultured using the present method with good viability and demonstrate faster proliferation in the present LC hydrogel compared to a non-LC gel.

An optical film includes a plurality of helically arranged liquid crystals and organic solid crystal structures at least partially surrounding the plurality of helically arranged liquid crystals. A method of making the optical film includes obtaining a substrate with an alignment layer and a film of a first solution on the alignment layer. The first solution includes liquid crystals and organic crystal molecules. The liquid crystals form a plurality of helically arranged liquid crystals on the alignment layer. The method also includes forming organic solid crystal structures by crystallizing the organic crystal molecules. The organic solid crystal structures at least partially surround the plurality of helically arranged liquid crystals.

An optically anisotropic layer is formed by a liquid crystal compound represented by General Formula 1, in which the long axes of the molecules are oriented. ##STR00001##
wherein L.sub.1 and L.sub.2 independently represent a linking group having a carbonyl group; F.sub.1 and F.sub.2 independently represent an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a halogen atom; n and m independently represent an integer from 0 to 4; a and b independently represent an integer from 1 to 4; T.sub.1 and T.sub.2 independently represent a spacer portion including a straight chain or branched alkylene or alkylene oxide group having 2 to 20 carbon atoms; and Ar represents a divalent group having at least one aromatic ring selected from a group consisting of aromatic hydrocarbon rings and aromatic heterocycles, the number of Π electrons in the Ar group being 8 or greater.

Provided is a polymer that includes a predetermined structural unit derived from an azomethine derivative having a polymerizable group and is reversibly fluidized and non-fluidized by being irradiated with light.

Compounds that have ultraviolet light absorbing properties, and which can also have mesogenic properties. Compositions that include one or more such compounds. Articles of manufacture that include one or more such compounds, such as optical elements that include an optical substrate and a layer that includes at least one such compound.

New classes of thiadiazole and oxadiazole compounds for use in LC mixtures are disclosed. In an embodiment, the new classes of thiadiazoles and oxadiazoles comprise at least one phenyl ring attached to the heterocyclic ring, where no alkyl, alkenyl or alkynyl tails are attached to the phenyl ring, but one alkyl, alkenyl or alkynyl tail is attached to the other end of the molecule, and a fluoro or cyano group appears in the para position of the phenyl ring. These compounds are disclosed as being effective at inducing smectic A phases in liquid crystal mixtures, particularly in liquid crystal mixtures also possessing a smectic C phase, more particularly in materials possessing a chiral smectic C (ferroelectric) phase.

The present invention provides a liquid crystal display device that can exhibit a long-lasting favorable voltage holding ratio and prevent deterioration of reliability. The liquid crystal display device of the present invention includes: paired substrates disposed to face each other; a liquid crystal layer disposed between the substrates; and an alignment film disposed between at least one of the substrates and the liquid crystal layer, the at least one of the substrates including an electrode and/or a conductive line that contain(s) copper or aluminum, the liquid crystal layer containing a liquid crystal component and an additive component with a chemical structure including a benzotriazole group represented by a given chemical formula.

New classes of thiadiazole and oxadiazole compounds for use in LC mixtures are disclosed. In an embodiment, the new classes of thiadiazoles and oxadiazoles comprise at least one phenyl ring attached to the heterocyclic ring, where no alkyl, alkenyl or alkynyl tails are attached to the phenyl ring, but one alkyl, alkenyl or alkynyl tail is attached to the other end of the molecule, and a fluoro or cyano group appears in the para position of the phenyl ring. These compounds are disclosed as being effective at inducing smectic A phases in liquid crystal mixtures, particularly in liquid crystal mixtures also possessing a smectic C phase, more particularly in materials possessing a chiral smectic C (ferroelectric) phase.

Provided is a polymer that includes a predetermined structural unit derived from an azomethine derivative having a polymerizable group and is reversibly fluidized and non-fluidized by being irradiated with light.

An optically anisotropic layer is formed by a liquid crystal compound represented by General Formula 1, in which the long axes of the molecules are oriented.

##STR00001##

wherein L.sub.1 and L.sub.2 independently represent a linking group having a carbonyl group; F.sub.1 and F.sub.2 independently represent an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a halogen atom; n and m independently represent an integer from 0 to 4; a and b independently represent an integer from 1 to 4; T.sub.1 and T.sub.2 independently represent a spacer portion including a straight chain or branched alkylene or alkylene oxide group having 2 to 20 carbon atoms; and Ar represents a divalent group having at least one aromatic ring selected from a group consisting of aromatic hydrocarbon rings and aromatic heterocycles, the number of electrons in the Ar group being 8 or greater.