To suppress a phenomenon where an optical axis of the optically anisotropic layer is tilted when the optically anisotropic layer is produced by using a liquid crystalline compound showing smectic phase as a materials showing a higher level of orderliness. An optically anisotropic layer wherein a polymerizable composition, containing one or more polymerizable rod-like liquid crystal compound showing a smectic phase, is fixed in a state of smectic phase, and a direction of maximum refractive index of the optically anisotropic layer is inclined at 10° or smaller to the surface of the optically anisotropic layer, a method for manufacturing the same, a laminate and a method for manufacturing the same, a polarizing plate, a liquid crystal display device, and an organic EL display device.

To suppress a phenomenon where an optical axis of the optically anisotropic layer is tilted when the optically anisotropic layer is produced by using a liquid crystalline compound showing smectic phase as a materials showing a higher level of orderliness. An optically anisotropic layer wherein a polymerizable composition, containing one or more polymerizable rod-like liquid crystal compound showing a smectic phase, is fixed in a state of smectic phase, and a direction of maximum refractive index of the optically anisotropic layer is inclined at 10° or smaller to the surface of the optically anisotropic layer, a method for manufacturing the same, a laminate and a method for manufacturing the same, a polarizing plate, a liquid crystal display device, and an organic EL display device.

The present invention relates to a mixture comprising a not fully aromatic polymerisable compound and a polymerisable photoinitiator, to liquid-crystal (LC) media comprising them, and to the use of the polymerisable compounds and LC media for optical, electro-optical and electronic purposes, in particular in LC displays, especially in LC displays of the polymer sustained alignment type.

A laminate is provided having excellent adhesiveness between a light absorption anisotropic film and a barrier layer, a manufacturing method of the laminate, and an image display device using the laminate. A laminate having: a barrier layer A; and a light absorption anisotropic film B, in which the barrier layer A is adjacently provided on the light absorption anisotropic film B, a relationship between a highest content of a compound A1 contained in the barrier layer A and a highest content of a compound B1 contained in the light absorption anisotropic film B satisfies a relationship in which a value of distance calculated from Hansen solubility parameters and represented by Formula (I) is within a range of 0.0 to 5.0, and the light absorption anisotropic film B contains a component same as the compound A1.
distance={4×(δ.sub.D(B1)−δ.sub.D(A1)).sup.2+(δ.sub.P(B1)−δ.sub.P(A1)).sup.2+(δ.sub.H(B1)−δ.sub.H(A1)).sup.2}.sup.0.5  (I)

An optically anisotropic layer is formed by a liquid crystal compound represented by General Formula 1, in which the long axes of the molecules are oriented. ##STR00001##
wherein L.sub.1 and L.sub.2 independently represent a linking group having a carbonyl group; F.sub.1 and F.sub.2 independently represent an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or a halogen atom; n and m independently represent an integer from 0 to 4; a and b independently represent an integer from 1 to 4; T.sub.1 and T.sub.2 independently represent a spacer portion including a straight chain or branched alkylene or alkylene oxide group having 2 to 20 carbon atoms; and Ar represents a divalent group having at least one aromatic ring selected from a group consisting of aromatic hydrocarbon rings and aromatic heterocycles, the number of Π electrons in the Ar group being 8 or greater.

To suppress a phenomenon where an optical axis of the optically anisotropic layer is tilted when the optically anisotropic layer is produced by using a liquid crystalline compound showing smectic phase as a materials showing a higher level of orderliness. An optically anisotropic layer wherein a polymerizable composition, containing one or more polymerizable rod-like liquid crystal compound showing a smectic phase, is fixed in a state of smectic phase, and a direction of maximum refractive index of the optically anisotropic layer is inclined at 10 or smaller to the surface of the optically anisotropic layer, a method for manufacturing the same, a laminate and a method for manufacturing the same, a polarizing plate, a liquid crystal display device, and an organic EL display device.

A laminate is provided having excellent adhesiveness between a light absorption anisotropic film and a barrier layer, a manufacturing method of the laminate, and an image display device using the laminate. A laminate having: a barrier layer A; and a light absorption anisotropic film B, in which the barrier layer A is adjacently provided on the light absorption anisotropic film B, a relationship between a highest content of a compound A1 contained in the barrier layer A and a highest content of a compound B1 contained in the light absorption anisotropic film B satisfies a relationship in which a value of distance calculated from Hansen solubility parameters and represented by Formula (I) is within a range of 0.0 to 5.0, and the light absorption anisotropic film B contains a component same as the compound A1.

distance={4(.sub.D(B1).sub.D(A1)).sup.2+(.sub.P(B1).sub.P(A1)).sup.2+(.sub.H(B1).sub.H(A1)).sup.2}.sup.0.5(I)

The present invention relates to a mixture comprising a not fully aromatic polymerisabe compound and a polymerisable photoinitiator, to liquid-crystal (LC) media comprising them, and to the use of the polymerisable compounds and LC media for optical, electro-optical and electronic purposes, in particular in LC displays, especially in LC displays of the polymer sustained alignment type.

The present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Also provided are a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer. The present invention provides the compound represented by General Formula (I), a composition including the compound, a polymer produced by polymerizing the composition, and an optically anisotropic body including the polymer.

The present invention relates to heteroaromatic compounds which have two different reactive groups, their use in the synthesis of asymmetrically substituted compounds, and synthesis processes in which the compounds according to the invention are reacted sequentially with two different compounds, whereby an asymmetrically substituted compound is formed.