Patent classifications
C10L1/196
Hydrocarbon marine fuel oil
A liquid hydrocarbon marine fuel oil includes a marine distillate fuel or a heavy oil or a blend thereof containing an additive combination including: (A) a polyalkenyl-substituted carboxylic acid or anhydride, and (B) a metal hydrocarbyl-substituted hydroxybenzoate and/or sulfonate detergent,
where the mass:mass ratio of (A) to (B) is in the range of 20:1 to 1:20 and the treat rate of the additive combination is in the range of 5 to 10000 ppm by mass.
FUEL COMPOSITION
A fuel composition for powering a combustion engine, the composition comprising a liquid base fuel; and a (co)polymer obtainable by (co)polymerizing at least the following monomers: one or more bicyclic (meth)acrylate esters (a); up to 15 wt % of styrene (b); optionally other ethylenically unsaturated monomers that are not monomer (a) or (b); up to a total of 100 wt %, wherein the weight percentages of the monomer are based on the total weight of all of the monomers.
Charged block co-polymers as pour point depressants
Fouling components within a fluid may be prevented from accumulating when an additive contacts the fluid, e.g. by coating the wellbore with the additive prior to the production of the fluid or adding the additive directly to the fluid, etc.. The additive may include, but is not limited to, a block copolymer having at least two components. The first component may be a charged monomer, and the second component may be a long chain fatty alcohol acrylate monomer. In one alternative embodiment, the fluid may be an oil-based fluid produced through a wellbore or an oil-based wellbore fluid, and the fouling components may be or include, but are not limited to, wax, paraffins, asphaltene, resins, and combinations thereof.
POLYMERS AS ADDITIVES FOR FUELS
A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.
Fuel composition
A fuel composition for powering a combustion engine the composition comprising: a liquid base fuel; and a copolymer obtainable by copolymerizing at least the following monomers: —at least one bicyclic (meth)acrylate ester; —at least one fatty-alkyl (meth)acrylate; —optionally, and preferably, at least one aromatic vinyl monomer; and —optionally other ethylenically unsaturated monomers.
USE OF CROSSLINKED POLYMERS FOR LOWERING THE COLD FILTER PLUGGING POINT OF FUELS
The present invention concerns the use, for lowering the cold filter plugging point of a fuel composition, of one or more crosslinked polymers comprising at least one unit of the following formula (I): in which R.sub.1 represents a hydrogen atom or a methyl group; E represents —O—CO—, or —CO—O— or —NH—CO— or —CO—NH—; and G represents a C.sub.1 to C.sub.34 alkyl group; said copolymer having a crosslinking rate of between 0.5 mol % and 30 mol %. The invention also concerns additive compositions containing such a polymer, and fuel compositions with such polymers as additives, in combination with a cold flow improver (CFI) chosen from the copolymers and terpolymers of ethylene and vinyl and/or acrylic ester(s).
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Oil anti-foulant and/or asphaltene agglomeration process
Fouling and/or asphaltene agglomeration (or flocculation) in midstream processes and transportation and in upstream transportation of a hydrocarbon oil is reduced by providing in the oil an additive combination including; (A) a polyalkenyl-substituted carboxylic acid or anhydride, and (B) a metal detergent system comprising a hydrocarbyl-substituted hydroxybenzoate metal salt or a hydrocarbyl-substituted sulfonate metal salt or a mixure of both salts or a complex thereof,
where the mass:mass ratio of (A) to (B) is in the range of 20:1 to 1:20 and the treat rate of the additive is in the range of 5 to 10000 ppm by mass.
Polymers as additives for fuels
A method for minimizing power loss, reducing a fuel consumption and/or for reducing and/or avoiding deposits in a fuel system in the direct injection diesel engines. The method contains adding a copolymer to a fuel composition, wherein the copolymer contains, in a copolymerized form: (A) an ethylenically unsaturated mono- or dicarboxylic acid or a derivative thereof, (B) an -olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B) and (D) optionally an additional copolymerizable monomers other than monomers (A), (B) and (C), anhydride or carboxylic acid functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present in the copolymer are hydrolysed and/or carboxylic ester functionalities present in the copolymer are partly hydrolyzed.
Method for Reducing Piston Deposits in a Marine Diesel Engine
A method of reducing the incidence of deposits on the pistons of a 4-stroke marine diesel engine during operation of the engine when it is fuelled with a marine residual fuel meeting the ISO 8217 2017 fuel standard for marine residual fuels and having a sulphur content of more than 0.1% and less than 0.5% by mass. The method includes the step of lubricating the engine using a lubricating oil composition comprising: a) at least 50% by mass, based on the mass of the composition, of an oil of lubricating viscosity; (b) 5 to 25% by mass, based on the mass of the composition, of an oil-soluble or oil-dispersible alkali metal or alkaline earth metal salicylate detergent, or a mixture of two or more oil-soluble or oil-dispersible alkali metal or alkaline earth metal salicylate detergents; (c) 0.1 to 10% by mass, based on the mass of the composition of one or more oil-soluble or oil-dispersible ashless dispersants; and optionally, (d) 0.1 to 10% by mass, based on the mass of the composition of a polyalkylene-substituted succinic anhydride.
Method for Reducing Piston Deposits in a Marine Diesel Engine
A method of reducing the incidence of deposits on the pistons of a 4-stroke marine diesel engine during operation of the engine when it is fuelled with a marine residual fuel meeting the ISO 8217 2017 fuel standard for marine residual fuels and having a sulphur content of more than 0.1% and less than 0.5% by mass. The method includes the step of lubricating the engine using a lubricating oil composition comprising: a) at least 50% by mass, based on the mass of the composition, of an oil of lubricating viscosity; (b) 5 to 25% by mass, based on the mass of the composition, of an oil-soluble or oil-dispersible alkali metal or alkaline earth metal salicylate detergent, or a mixture of two or more oil-soluble or oil-dispersible alkali metal or alkaline earth metal salicylate detergents; (c) 0.1 to 10% by mass, based on the mass of the composition of one or more oil-soluble or oil-dispersible ashless dispersants; and optionally, (d) 0.1 to 10% by mass, based on the mass of the composition of a polyalkylene-substituted succinic anhydride.