Disclosed herein are antifouling compositions including a combination of one or more dispersant polymers and one or more inhibitors, the one or more dispersant polymers including the polymerized residues of one or more a-olefins and maleic anhydride, further wherein the maleic anhydride residues are reacted with a primary amine; and the one or more inhibitors including a functionalized p-phenylene diamine. Concentrates of the antifouling compositions in solvents are stable and pourable at temperatures of 0° C. to −40° C. The antifouling compositions are added to a petroleum product to form a treated petroleum product, wherein fouling by the treated petroleum product is reduced and a stable dispersion is formed over a wide range of processing conditions.

Novel uses of copolymers for removing and/or reducing the level of deposits in the fuel system and/or injection system of direct injection diesel and/or gasoline engines are provided. What is provided is the use of particular copolymers as fuel additive or lubricant additive; to processes for preparation of such additives, and fuels and lubricants added therewith, such as, more particularly, as a detergent additive; to use of these copolymers for reducing the level of or preventing deposits in the fuel systems and especially the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.

Disclosed are cloud point depressants and methods of making and using them. The disclosed cloud point depressants comprise copolymers of an unsaturated anhydride polymerized with alkyl α-olefins and then contacted with a phenyl alkyl alcohol or alkyl phenol alkoxylate, fatty alcohol and primary or secondary fatty amine to provide a cloud depressant reaction product. When the disclosed reaction products are added to middle distillate fuels or blends of middle distillate fuels with biodiesel, the cloud point depressants inhibit the precipitation of waxes and/or biowaxes in the fuels and the fuels exhibit reduced precipitation, gelling, and/or crystallization when subjected to low or cold temperatures.

A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.

The present invention concerns the use, for lowering the cold filter plugging point of a fuel composition, of one or more crosslinked polymers comprising at least one unit of the following formula (I): in which R.sub.1 represents a hydrogen atom or a methyl group; E represents —O—CO—, or —CO—O— or —NH—CO— or —CO—NH—; and G represents a C.sub.1 to C.sub.34 alkyl group; said copolymer having a crosslinking rate of between 0.5 mol % and 30 mol %. The invention also concerns additive compositions containing such a polymer, and fuel compositions with such polymers as additives, in combination with a cold flow improver (CFI) chosen from the copolymers and terpolymers of ethylene and vinyl and/or acrylic ester(s).

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Ethylene-C.sub.3-C.sub.10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C.sub.3-C.sub.10 alpha-olefin-derived units. The C.sub.3-C.sub.10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C.sub.3-C.sub.10 alpha-olefin-derived units may be propylene-derived units. The dispersants may be made from copolymers having low metal and/or fluorine contents.

A method for minimizing power loss, reducing a fuel consumption and/or for reducing and/or avoiding deposits in a fuel system in the direct injection diesel engines. The method contains adding a copolymer to a fuel composition, wherein the copolymer contains, in a copolymerized form: (A) an ethylenically unsaturated mono- or dicarboxylic acid or a derivative thereof, (B) an -olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B) and (D) optionally an additional copolymerizable monomers other than monomers (A), (B) and (C), anhydride or carboxylic acid functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present in the copolymer are hydrolysed and/or carboxylic ester functionalities present in the copolymer are partly hydrolyzed.

Disclosed are cloud point depressants and methods of making and using them. The disclosed cloud point depressants comprise copolymers of a maleic moiety polymerized with alpha olefins and then contacted with an aliphatic tertiary amine to provide a cloud depressant reaction product. When the disclosed reactions products are added to middle distillate fuels or blends of middle distillate fuels with biodiesel, the cloud point depressants inhibit the precipitation of waxes and/or biowaxes in the fuels and the fuels exhibit reduced precipitation, gelling, and/or crystallization when subjected to low or cold temperatures.

The invention relates to oil-in-water (water continuous) emulsions that can be used as fuels, and which have high static and dynamic stability, to a process for their preparation, and to fuel compositions comprising such emulsions.

The present invention relates to a copolymer obtainable by copolymerization of (A) at least one unsaturated dicarboxylic acid or derivatives thereof, (B) at least one -olefin having from at least 6 up to and including 20 carbon atoms, (C) optionally at least one C.sub.3- to C.sub.20-alkyl ester of acrylic acid or methacrylic acid or a mixture of such alkyl esters and (D) optionally one or more further copolymerizable monomers other than monomers (A), (B) and (C), with a molar incorporation ratio of (A):(B):(C):(D) of 1:0.5 to 2.0:0 to less than 0.5:0 to 0.1 followed by the reaction with at least one dialkylamine (E), where the two alkyl radicals in the at least one dialkylamine (E) are independently alkyl radicals having at least 17 up to 30 carbon atoms.