A fuel additive composition, including: (a) one or more copolymer(s) including: at least one unit of the following formula (I), where u=0 or 1, E=-O or N(Z), or OCO, or COO or NHCO or CONH, where Z represents H or a C1-C6 alkyl group, G represents a group selected between a C1-C34 alkyl group, aromatic ring, aralkyl including at least one aromatic ring and at least one C1-C34 alkyl group, and at least one unit of the following formula (II), where R1 is selected between a hydrogen atom and a methyl group, Q is selected between an oxygen atom and a group NR, where R is selected between a hydrogen atom and C1-C12 hydrocarbon chains, R includes a C1-C34 hydrocarbon chain substituted with at least one quaternary ammonium, (b) one or more amines substituted with a polyalkenyl group, and (c) at least one carrier oil.

The invention relates to a copolymer comprising: at least one motif of the following formula (I), and motifs of the following formula (II), between 5 and 95 mol % of the groups R of the motifs of formula (II) comprising at least one quaternary amino group. The invention also relates to the production of such a copolymer, and to the use thereof as a detergent additive and/or demulsifying additive in a liquid fuel for an internal combustion engine.

##STR00001##

The invention relates to a composition of additives for fuel, comprising: (a) one or more copolymer(s) comprising the following units of formulae (I) and units of formula (IIa): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one quaternary ammonium or iminium function, and (b) one or more copolymer(s) comprising units of formulae (I) and units of formula (IIb): R representing a hydrocarbon-based chain substituted with at least one amino group comprising at least one primary, secondary or tertiary amine function or imine function. The invention also relates to the use of such a composition as a detergent additive and/or demulsifying additive in a liquid fuel for an internal combustion engine.

##STR00001##

A copolymer obtained by copolymerization of at least: an apolar monomer (m.sub.a) with the following formula (I), where u=0 or I, w=0 or I, E=-0- or NH(Z), or OCO, or NHCO or CONH, wherein Z is H or an alkyl group, and G is a group selected among an alkyl, an aromatic ring and an arylalkyl; and a polar monomer (m.sub.b) selected among those of the following formula (II), wherein t=0 or I, Q is selected among the oxygen atom and the NR group, wherein R is selected among a hydrogen atom and hydrocarbon chains, and R is a hydrocarbon chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. The invention also relates to the use of such a copolymer as a detergent additive in a liquid fuel of an internal combustion engine.

Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.

A composition of additives for fuel including: one or more copolymer(s) including:at least one unit of the following formula (I): wherein R1 is selected from hydrogen and methyl group, R2 is selected from C1 to C34 hydrocarbon-based chains, an aromatic ring, an aralkyl containing at least one aromatic ring and at least one C1-C34 alkyl group, andat least one unit of following formula (II): wherein R1 is selected from hydrogen and methyl group, Z is selected from the oxygen atom and NR group with R being selected from a hydrogen atom and C1 to C12 hydrocarbon-based chains, G includes a C1 to C34 hydrocarbon-based chain substituted with at least one quaternary ammonium group and optionally one or more hydroxyl groups, group G also possibly containing one or more nitrogen and/or oxygen atoms and/or carbonyl groups 25 at least one compound selected from succinimides substituted with a hydrocarbon-based chain.

Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions that can be used when the non-polar composition is in a flow, and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone with a longest span having a molecular weight that remains substantially unchanged under the flow conditions and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.

A method for minimizing power loss, reducing a fuel consumption and/or for reducing and/or avoiding deposits in a fuel system in the direct injection diesel engines. The method contains adding a copolymer to a fuel composition, wherein the copolymer contains, in a copolymerized form: (A) an ethylenically unsaturated mono- or dicarboxylic acid or a derivative thereof, (B) an -olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B) and (D) optionally an additional copolymerizable monomers other than monomers (A), (B) and (C), anhydride or carboxylic acid functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present in the copolymer are hydrolysed and/or carboxylic ester functionalities present in the copolymer are partly hydrolyzed.

Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions that can be used when the non-polar composition is in a flow, and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone with a longest span having a molecular weight that remains substantially unchanged under the flow conditions and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.

Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.