A method for coating a thin film in a rolling manner and a thin film coating apparatus are provided. The method includes: floating a thin film material on a liquefied material; rolling a cylindrical substrate after contacting the cylindrical substrate with the thin film material; and coating the thin film material on a surface of the cylindrical substrate by using an attraction force between the surface of the cylindrical substrate and the thin film material.

A method for coating a thin film in a rolling manner and a thin film coating apparatus are provided. The method includes: floating a thin film material on a liquefied material; rolling a cylindrical substrate after contacting the cylindrical substrate with the thin film material; and coating the thin film material on a surface of the cylindrical substrate by using an attraction force between the surface of the cylindrical substrate and the thin film material.

Disclosed is a system for treating a surface of a multi-metal article. The system includes first and second compositions for contacting at least a portion of the surface. The first composition includes phosphate ions and zinc ions and is substantially free of fluoride. The second composition includes a lanthanide series metal cation and an oxidizing agent. Methods of treating a multi-metal article using the system also are disclosed. Also disclosed are substrates treated with the system and method.

A treatment agent for chromium-free insulating coating formation suitable for forming an insulating coating on a surface of a grain-oriented electrical steel sheet. The treatment agent includes components (A), (B), (C), and (D). The component (B) is contained in an amount of 50 to 150 parts by mass on a SiO.sub.2 solid basis, and the component (C) is contained in an amount of 5.0 parts by mass or more on an elemental metal basis, the amounts being based on 100 parts by mass, on a solid basis, of the component (A). The component (D) is contained in an amount that a molar ratio of M.sup.2+ and M.sup.3+, each being a metal element in the treatment agent for chromium-free insulating coating formation, to a phosphorus element P satisfies a specified relationship, and the treatment agent for chromium-free insulating coating formation has a pH of less than 4.5.

A coated titanium material includes a titanium material and a coating film formed on a surface of the titanium material. A Ti-based oxide is included in an interface between the titanium material and the coating film. The Ti-based oxide is one or both rutile type TiO.sub.2 and Ti.sub.2O.sub.3. In a case where a cut surface of the coating film is formed by using a SAICAS method under conditions that a horizontal speed is 2 m/s and a vertical speed is 0.1 m/s, on the cut surface, an area percentage of the Ti-based oxide is 30.0% or more in a region having a distance of 15 m from a reference line specified on the basis of a boundary line, which is an intersection line between the cut surface and the interface, to a coating film side.