C23C22/17

Finishing agent for trivalent chromium chemical conversion coating film, and method for finishing black trivalent chromium chemical conversion coating film

The purpose of the present invention is to provide a water-soluble finishing agent for a trivalent chromium chemical conversion coating film, which has low insulation, no problems with tightening properties, outstanding gloss and high corrosion resistance, and can obtain a trivalent chromium chemical conversion coating film, especially a black trivalent chromium chemical conversion coating film, having few scratches and flaws. The finishing agent for a trivalent chromium chemical conversion coating film is characterized by containing a trivalent chromium source, a phosphate ion source, a zinc ion source, a chelating agent which can form a complex with trivalent chromium, and a non-ionic water-soluble polymer compound selected from a group comprising poly(vinyl alcohol) and derivatives thereof, poly(vinyl pyrrolidone) and derivatives thereof, poly(alkylene glycol)s and derivatives thereof, and cellulose ethers and derivatives thereof.

Passivation composition based on mixtures of phosphoric and phosphonic acids

The present invention provides an aqueous passivation composition for the treatment of zinc or zinc alloy coatings, comprising: i) phosphoric acid; ii) at least one water-soluble polyphosphonic acid or a water-soluble salt thereof, iii) at least one divalent metal cation (M.sup.2+); and, iv) at least one water-soluble or water-dispersible fluoroacid or a salt thereof, wherein said fluoroacid is defined by the following general empirical formula (II):
H.sub.pT.sub.qF.sub.rO.sub.s(II)
wherein: each of q and r represents an integer from 1 to 10; each of p and s represents an integer from 0 to 10; and, T represents an element selected from the group consisting of Ti, Zr, Hf, Si, Sn, Al, Ge, and B.