A laminate having: an electrode for electrolysis, and a membrane laminated on the electrode for electrolysis, wherein when the laminate is wetted with a 3 mol/L NaCl aqueous solution, and under a storage condition at ordinary temperature, an amount of a transition metal component (with the proviso that zirconium is excluded), detected from the membrane after storage for 96 hours, is 100 cps or less; and A protective laminate having: a first electrode for electrolysis, a second electrode for electrolysis, a membrane disposed between the first electrode for electrolysis and the second electrode for electrolysis, and an insulation sheet that protects at least one of the surface of the first electrode for electrolysis and the surface of the second electrode for electrolysis.

A laminate having: an electrode for electrolysis, and a membrane laminated on the electrode for electrolysis, wherein when the laminate is wetted with a 3 mol/L NaCl aqueous solution, and under a storage condition at ordinary temperature, an amount of a transition metal component (with the proviso that zirconium is excluded), detected from the membrane after storage for 96 hours, is 100 cps or less; and A protective laminate having: a first electrode for electrolysis, a second electrode for electrolysis, a membrane disposed between the first electrode for electrolysis and the second electrode for electrolysis, and an insulation sheet that protects at least one of the surface of the first electrode for electrolysis and the surface of the second electrode for electrolysis.

A chlorination electrolyser having a housing provided with an inlet and an outlet suitable for the circulation of brine; at least one pair of bipolar electrodes facing each other and positioned within said housing. Each bipolar electrode of the at least one pair has a valve metal substrate; an active coating comprising at least one layer of a catalytic composition comprising ruthenium and titanium disposed over the substrate; a top coating having at least one layer composed of oxides of tantalum, niobium, tin, or combinations thereof disposed over the active coating. A self-cleaning electrochlorination system having the an electrolyser, a method for its production, its use in normal and low salinity pools for hypochlorite mediated water disinfection and a method for hypochlorite-mediated water disinfection.

A chlorination electrolyser having a housing provided with an inlet and an outlet suitable for the circulation of brine; at least one pair of bipolar electrodes facing each other and positioned within said housing. Each bipolar electrode of the at least one pair has a valve metal substrate; an active coating comprising at least one layer of a catalytic composition comprising ruthenium and titanium disposed over the substrate; a top coating having at least one layer composed of oxides of tantalum, niobium, tin, or combinations thereof disposed over the active coating. A self-cleaning electrochlorination system having the an electrolyser, a method for its production, its use in normal and low salinity pools for hypochlorite mediated water disinfection and a method for hypochlorite-mediated water disinfection.

An electrically conductive substrate contains at least titanium. An intermediate layer is provided on a primary surface of the electrically conductive substrate. A composite layer is provided on the intermediate layer. The composite layer includes tantalum layers and catalyst layers. Each of the catalyst layers contains platinum and iridium. Each of the tantalum layers is made from tantalum oxide, tantalum, or a mixture of tantalum oxide and tantalum. The tantalum layers and the catalyst layers are alternately stacked one layer by one layer in a thickness direction of the electrically conductive substrate. A bottom layer of the composite layer closest to the primary surface of the electrically conductive substrate is constituted by one tantalum layer of the tantalum layers. A top layer of the composite layer furthest from the electrically conductive substrate is constituted by one catalyst layer of the catalyst layers.

An electrically conductive substrate contains at least titanium. An intermediate layer is provided on a primary surface of the electrically conductive substrate. A composite layer is provided on the intermediate layer. The composite layer includes tantalum layers and catalyst layers. Each of the catalyst layers contains platinum and iridium. Each of the tantalum layers is made from tantalum oxide, tantalum, or a mixture of tantalum oxide and tantalum. The tantalum layers and the catalyst layers are alternately stacked one layer by one layer in a thickness direction of the electrically conductive substrate. A bottom layer of the composite layer closest to the primary surface of the electrically conductive substrate is constituted by one tantalum layer of the tantalum layers. A top layer of the composite layer furthest from the electrically conductive substrate is constituted by one catalyst layer of the catalyst layers.

A radiation-assisted (typically solar-assisted) electrolyzer cell and panel for high-efficiency hydrogen production comprises a photoelectrode and electrode pair, with said photoelectrode comprising either a photoanode electrically coupled to a cathode shared with an anode, or a photocathode electrically coupled to an anode shared with a cathode; electrolyte; gas separators; all within a container divided into two chambers by said shared cathode or shared anode, and at least a portion of which is transparent to the electromagnetic radiation required by said photoanode (or photocathode) to apply photovoltage to a shared cathode (or anode) that increases the electrolysis current and hydrogen production.

A radiation-assisted (typically solar-assisted) electrolyzer cell and panel for high-efficiency hydrogen production comprises a photoelectrode and electrode pair, with said photoelectrode comprising either a photoanode electrically coupled to a cathode shared with an anode, or a photocathode electrically coupled to an anode shared with a cathode; electrolyte; gas separators; all within a container divided into two chambers by said shared cathode or shared anode, and at least a portion of which is transparent to the electromagnetic radiation required by said photoanode (or photocathode) to apply photovoltage to a shared cathode (or anode) that increases the electrolysis current and hydrogen production.

This disclosure provides systems, methods, and apparatus related to nanoparticle/ordered-ligand interlayers. In one aspect, a structure comprises an assembly and a layer of ligands disposed on a surface of the assembly. The assembly comprises a plurality of metal nanoparticles. The metal nanoparticles of the plurality of metal nanoparticles in the assembly are proximate one another. The layer of ligands is operable to detach from the surface of the assembly but to remain proximate the surface of the assembly when the assembly is disposed in an electrolyte and a negative bias is applied to the assembly. An interlayer forms between the assembly and the layer of ligands, with the interlayer comprising desolvated cations from the electrolyte.

The present invention provides an electrode for electrolysis in which a planarized metal substrate having a mesh structure such that the aspect ratio of an individual cross-section of a wire constituting the mesh structure is 120% or greater is used to increase the surface area of a coating layer, thereby increasing adhesion to a membrane and gas trap is reduced to reduce overvoltage.