An electrode for an ozone generator or chlorine generator includes an electrically conductive substrate, a doped-Si layer disposed over the conductive substrate, and a boron-doped diamond (BDD) layer disposed over the doped-silicon layer. The doped-silicon layer defines a discrete architecture that maintains adhesion throughout a high temperature CVD boron-doped diamond process. Another electrode having a PVD nitrogen-doped diamond (ta-C:N) layer disposed over a conductive substrate is also provided.

An illustrative control system for use with a replaceable ozone generator cartridge for use with an aqueous ozone delivery device, for example, for sanitizing objects, including hands, hands and forearms, feet, other tissue, instruments, or other object sanitizing. One embodiment of the control system calculates and transmits usage data to a memory device of the ozone generator cartridge, and also includes various sensors and drivers for controlling an aqueous ozone concentration. The control system also provides other data logging, error detection, and identity verification of the replaceable ozone generator cartridge.

The invention relates to a easily adaptable or DIY installation water cleaning device on any existing spa or pool, said cleaning device including an electrolysis module equipped with a particular boron-doped diamond electrode on silicum substrate. The inventions also relates to a method to clean water on spa or pools using a water cleaning device comprising said particular boron-doped diamond electrode present on the elecrolysis module. The invention also relates to electrolyzed bathing water for use in the treatment of inflammatory diseases of the skin and for use for use in the treatment of wound healing of the skin.

A novel cell for generating ozonated water, the cell comprises a nafion membrane separating a diamond coated anode, and a gold surfaced cathode enclosed within a cell housing with the catalyst side of the nafion membrane facing the cathode. The cell housing has a cathode housing portion and an anode housing portion separated by the membrane, each housing portion having ridges to enhance substantially even flow of fluid over the cathode and anode. The housing portions contain O-rings in grooves to prevent leaks, and alignment features to keep the electrodes aligned. The cathode and anode have an array of holes allowing fluid to penetrate to the surface of the niobium membrane. Input ports allow fluid to flow into the housing and over the anode and cathode and then out of the housing through outlet ports. The housing may also incorporate an integrated spectral photometer including a bubble trap.

An illustrative expendable or reconstructable ozone generator cartridge for an aqueous ozone delivery device, for example, for antimicrobial sanitizing and/or medical treatment, includes a housing for a water treatment manifold providing parallel and operably fixed water pathways through ozone generating cells coupled to the manifold, and optionally a data logging and authentication feature.

An illustrative expendable or reconstructable ozone generator cartridge for an aqueous ozone delivery device, for example, for antimicrobial sanitizing and/or medical treatment, includes a housing for a water ozonating manifold, at least one ozone generating cell coupled to the manifold, and optionally a data logging and authentication feature. Advantageously, a water inlet and aqueous ozone outlet of the ozone generator cartridge is pluggable into and unpluggable from a docking station of the aqueous ozone delivery device, for example, a hand or implement washing and sanitizing device or a medical treatment device.

An electrode assembly for use in an electrochemical cell for the production of ozone from water is provided, the electrode assembly comprising an electrode body formed from a polycrystalline diamond, the electrode body comprising first and second opposing contact surfaces, the first contact surface for contacting a semi-permeable membrane; wherein the electrode assembly further comprises a first layer comprising an electrically conductive material, the first layer extending across at least a portion of the second contact surface of the electrode body. An electrochemical cell comprising the electrode assembly and its use in the production of ozone by the electrolysis of water is also provided.

A novel cell for generating ozonated water including an integrated ozone concentration detector. The cell comprises a nafion membrane separating a diamond coated anode, and a gold surfaced cathode enclosed within a cell housing with the catalyst side of the nafion membrane facing the cathode. The cell housing has a cathode housing portion and an anode housing portion separated by the membrane. The cathode and anode have an array of holes allowing fluid to penetrate to the surface of the niobium membrane. Ozonated water from the anode is channeled to a spectrophotometer integrated within the housing. The spectrophotometer creates a signal representative of the ozone concentration in the ozonated water which is utilized by control circuitry in a closed loop to maintain a stable target concentration. A bubble trap may be integrated within the housing through which the ozonated water passes before entering the spectrophotometer to remove bubbles form the ozonated water. Input ports allow fluid to flow into the housing and over the anode and cathode and then out of the housing through outlet ports.

Provided herein are methods and compositions for reducing the level of a cyanotoxin in cyanotoxin contaminated-water. The electrolytic destruction methods can include contacting the contaminated water with an electrochemical cell in the presence of a magnesium salt and applying an electrical current to the water for a time and in an amount sufficient to oxidize the cyanotoxin. The methods are useful for treatment of lake water, reservoir water, pond water, river water, or irrigation water and any water that serves as a source of drinking water.

A novel system for generating ozonated water, for example, for sterilization of medical equipment. The system comprises an ozone generating cell including a nafion membrane separating an anode, and a cathode enclosed within a cell housing. The cell housing has a cathode housing portion and an anode housing portion separated by the membrane. The housing also incorporates an integrated spectrophotometer including a bubble trap. The system includes a hydrogen water reservoir for receiving water from the cathode and an ozone water reservoir for receiving generated ozonated water from the anode. Control circuitry controls a set of pumps, and controls ozone generation in a closed loop using the spectrophotometer to provide a selected ozone concentration in the ozonated water from the anode. An output port coupled to the ozone water reservoir allows ozonated water to flow out of the system for external use.