An article includes a substrate, a bond coat layer disposed on the substrate, and a layer of networked ceramic nanofibers disposed on the bond coat layer.

An article includes a substrate, a ceramic barrier coating, and a layer of networked ceramic nanofibers. The ceramic barrier coating is disposed on the substrate and has a porous columnar microstructure. The layer of networked ceramic nanofibers is disposed on the ceramic barrier layer and seals the pores of the porous columnar microstructure.

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

There is disclosed herein processes and systems for forming fiber-reinforced ceramic composite structures which, contrary to conventional methods, directly deposit a ceramic fiber composite on a working surface. The processes and systems enable the printing of ceramic fiber composite structures having complex shapes and allow for multiple fiber-matrix material combinationsso far not possible with conventional approaches. In addition, the systems and process described herein enable the printing of ceramic fiber composites on complex 3D surfaces, such as gas turbine components.

A blade for a gas turbine engine, and methods of manufacture of such a blade having a continuous density gradient so that the portion of the blade nearest the rotator shaft is of a higher density than the portion of the blade furthest from the rotator shaft.

A ceramic bonding material including at least one fibrous material, a flux agent and a thickening agent wherein the ceramic bonding material fired at a set temperature to bond the two adjacent substrate faces.

A method of forming a ceramic component is disclosed. A ceramic matrix material is combined with a binder material. The ceramic matrix material and the binder material are mixed to create an intermediate slurry. After mixing the ceramic matrix material and the binder material, reinforcing fibers are added to the intermediate slurry to create a final slurry. The final slurry is introduced into a mold cavity having a shape corresponding to the ceramic component. The final slurry is at least partially cured within the mold cavity to form an intermediate casting. The intermediate casting is sintered to produce the ceramic component from the intermediate casting.

A ceramic bonding material including at least one fibrous material, a flux agent and a thickening agent wherein the ceramic bonding material fired at a set temperature to bond the two adjacent substrate faces.

The invention relates to a pre-impregnated fibre-reinforced composite material in laminar form, obtained impregnating a fibrous mass with a polymeric binder composition and intended to be subjected to successive forming and pyrolysis operations to produce a fibre-reinforced composite ceramic material. The polymeric binder composition is based on one or more resins chosen from the group consisting of siloxane resins and silsesquioxane resins, and can optionally comprise one or more organic resins. The polymeric binder composition is a liquid with viscosity between 55000 and 10000 mPas at temperatures between 50 C. and 70 C. The polymeric binder composition forms a polymeric binding matrix, not cross-linked or only partially cross-linked that fills the interstices of the fibrous mass. The invention also relates to a method for making said pre-impregnated fibre-reinforced composite material in laminar form. The invention further relates to a fibre-reinforced composite ceramic material, obtained by forming and subsequent pyrolysis of a pre-impregnated fibre-reinforced composite material, as well as a method for making said material.

A preform for making a component of a braking system having a fibre-reinforced ceramic composite material, obtained by forming and subsequent pyrolysis of a pre-preg is described. Also described is a component of a braking system made wholly or in part from the preform, and a method for making a preform in a fibre-reinforced ceramic composite material.