Patent classifications
C08F4/6465
Production method for stabilized olefin resin composition
Provided is a production method that can produce an olefin resin composition having excellent long-term stability and providing a sufficient stabilization effect to the olefin resin composition. This production method is a method of producing an olefin resin composition that contains a polyolefin resin polymerized with, an addition of a mixture of a phenolic antioxidant represented by the following Formula (1) and a phosphite compound represented by the following Formula (2) or (3), and an organoaluminum compound or a mixed solvent of an organoaluminum compound and an organic solvent, to a catalyst system or a polymerization system before or during the polymerization of the olefin monomer.
Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization
The present disclosure relates to a Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization. The catalyst system of the present disclosure comprises a pro-catalyst, a co-catalyst, and an external donor having a mixture of a selectivity control agent and an activity control agent. The catalyst system of the present disclosure is adapted to prevent the temperature of the polymerization reaction to go beyond the softening temperature of the polymer, thereby exhibiting the self-extinguishing properties.
Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization
The present disclosure relates to a Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization. The catalyst system of the present disclosure comprises a pro-catalyst, a co-catalyst, and an external donor having a mixture of a selectivity control agent and an activity control agent. The catalyst system of the present disclosure is adapted to prevent the temperature of the polymerization reaction to go beyond the softening temperature of the polymer, thereby exhibiting the self-extinguishing properties.
SCRATCH RESISTANT POLYOLEFIN COMPOSITION
An injection molded article made from or containing a propylene-based composition made from or containing: T1) from 90 wt % to 50 wt % of a propylene homopolymer; and T2) from 10 wt % to 50 wt % of a polymer composition made from or containing A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of a copolymer of ethylene and a C.sub.3-C.sub.8 alpha-olefin containing from 0.1% to 20% by weight of alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units.
SCRATCH RESISTANT POLYOLEFIN COMPOSITION
An injection molded article made from or containing a propylene-based composition made from or containing: T1) from 90 wt % to 50 wt % of a propylene homopolymer; and T2) from 10 wt % to 50 wt % of a polymer composition made from or containing A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 20-50% by weight of a copolymer of ethylene and a C.sub.3-C.sub.8 alpha-olefin containing from 0.1% to 20% by weight of alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene containing from 25% to 75% by weight of ethylene units.
CYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS IN ZEIGLER ?NATTA CATALYST SYSTEMS FOR PRODUCING PROPYLENE POLYMER HAVING HIGH MELT-FLOWABILITY
Cyclic organosilicon compounds having a structure represented by the general formula
##STR00001##
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
CYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS IN ZEIGLER ?NATTA CATALYST SYSTEMS FOR PRODUCING PROPYLENE POLYMER HAVING HIGH MELT-FLOWABILITY
Cyclic organosilicon compounds having a structure represented by the general formula
##STR00001##
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.
PROPYLENE-BASED TERPOLYMER COMPOSITION FOR PIPES
The invention relates to a pipe comprising a polypropylene composition (P) comprising a terpolymer composition (A), a nucleating agent (B) and optionally a composition comprising pigment (C), wherein the terpolymer composition (A) comprises at least one terpolymer prepared from propylene, ethylene and 1-hexene, wherein the nucleating agent (B) is a nucleating agent comprising a metal salt of hexahydrophthalic acid represented by formula (I) (I) wherein M1 and M2 are the same or different, and may be combined into one cation, and are selected from at least one metal cation of calcium, strontium, lithium, and monobasic aluminum; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are either the same or different and are individually selected from the group consisting of hydrogen, C.sub.1-C.sub.9 alkyl, hydroxy, C1-C9alkoxy, C.sub.1-C.sub.9 alkyleneoxy, amine, and C.sub.1-C.sub.9 alkylamine, halogens, and phenyl wherein the polypropylene composition (P) has a melt flow rate in the range from 0.10 to 0.70 dg/min as determined by ISO1133-1:2011 at 230° C. and 2.16 kg.
##STR00001##
PROPYLENE-BASED TERPOLYMER COMPOSITION FOR PIPES
The invention relates to a pipe comprising a polypropylene composition (P) comprising a terpolymer composition (A), a nucleating agent (B) and optionally a composition comprising pigment (C), wherein the terpolymer composition (A) comprises at least one terpolymer prepared from propylene, ethylene and 1-hexene, wherein the nucleating agent (B) is a nucleating agent comprising a metal salt of hexahydrophthalic acid represented by formula (I) (I) wherein M1 and M2 are the same or different, and may be combined into one cation, and are selected from at least one metal cation of calcium, strontium, lithium, and monobasic aluminum; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are either the same or different and are individually selected from the group consisting of hydrogen, C.sub.1-C.sub.9 alkyl, hydroxy, C1-C9alkoxy, C.sub.1-C.sub.9 alkyleneoxy, amine, and C.sub.1-C.sub.9 alkylamine, halogens, and phenyl wherein the polypropylene composition (P) has a melt flow rate in the range from 0.10 to 0.70 dg/min as determined by ISO1133-1:2011 at 230° C. and 2.16 kg.
##STR00001##
MULTILAYER POLYPROPYLENE FILM FOR CAPACITOR
An object of the present invention is to provide a film for a capacitor such that the film excels in high-temperature dielectric breakdown voltage (high-temperature BDV) and has blocking resistance, and bleeding-out of, for instance, a nucleating agent is suppressed even after long-term storage. The present invention pertains to a multilayer polypropylene film for a capacitor, the film including a base layer composed of a propylene polymer composition containing a propylene homopolymer (X) and 0.0001 to 0.05 mass % of a polymer-based α-crystal nucleating agent (C), and a front layer or a back layer composed of a propylene-based polymer (Y) on at least one surface of the base layer, wherein the base layer and the front layer or back layer are stretched.