Patent classifications
C08G18/0876
Syntactic polyurethane elastomers for use in subsea pipeline insulation
Syntactic polyurethane elastomers are made using a non-mercury catalyst. The elastomer is made from a reaction mixture containing a polymer polyol which has a liquid polyether polyol as a continuous phase and polymer particles dispersed in the liquid polyether polyol, a chain extender, a polyisocyanate and microspheres. The elastomer adheres well to itself, which makes it very useful as thermal insulation for pipelines and other structures that have a complex geometry.
Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion
Polymer polyols (PMPOs), processes for their production, and the use of such PMPOs, particularly in the production of flexible polyurethane foams. The PMPOs are produced using an ethylenically unsaturated composition that includes a crosslinker that results in crosslinks in the PMPO polymer particles that may decompose when exposed to flame temperatures. The PMPOs is capable of providing a flexible polyurethane foam that may exhibit combustibility resistance properties.
STABILISER FOR POLYOLEFIN-IN-POLYETHER POLYOL DISPERSIONS
Stabiliser, comprising the reaction product of at least one macromer with at least one C.sub.4-30-alkyl(meth)acrylate in at least one polyether polyol 1 in the presence of at least one free radical polymerisation catalyst and optionally at least one chain transfer agent, the at least one macromer being at least one molecule which comprises in its structure one or more polymerisable double bonds, able to copolymerise with C.sub.4-30-alkyl(meth)acrylates and which furthermore comprises in its structure one or more hydroxyl-terminated polyether chains.
Polymer dispersions having nanosized polyurea particles dispersed in a polyether
Dispersions of polyurea particles are made by reacting polyisocyanate compounds and coreactants that include at least one polyamine while dispersed in a base polyether. The polyisocyanate or the polyamine, or both, has a functionality of at least 2. A highly preferred coreactant is an alkylthio-substituted aromatic diamine such as 3,5-di(methylthio)-2,4-toluene diamine. The dispersions have extremely small particles, which promotes storage stability.
Electrically-conductive compositions and methods of using them with pipelines
Minimum Federal Safety Standards for corrosion control on buried oil and natural gas pipelines stipulate that metallic pipes should be properly coated and have impressed-current cathodic protection (ICCP) systems in place to control the electrical potential field around susceptible pipes. In certain examples described herein, electrically-conductive nanocomposites can be used and provide intrinsically-safe foam materials without the dielectric shielding issues of existing materials used to physically protect and stabilize buried pipelines. As cured or formed by customary spray applications, the nanocomposite foams described herein are directly compatible with ICCP functionality wherever foam contacts the metallic pipe. Various foam compositions and their use with underground pipelines are described.
Heat conservation-insulating material coated with UV curing-type film and having maximized heat efficiency, and method for manufacturing same
The present invention relates to a heat conservation-insulating material which is coated with a UV film and has maximized heat efficiency, wherein: the material uses a thermosetting water-soluble acrylic adhesive to ensure the minimum uniform coating film thickness required for corrosion prevention of a pipe and strength reinforcement during curing and allow easy installation with flexibility and sufficient working time before the installation; and a surface of the insulating material is UV-coated and thermosetting-coated by dual-cure curing method so that even a part where light or ultraviolet rays cannot penetrate can be cured, a heat conservation-insulating material having vivid colors can be obtained even when dye and pigment are added to realize various colors, and the cutting processability is excellent to enable a uniform coating on various surfaces, such as metal, plastic, glass, ceramics, stone, wood, and various building materials, or even on sharply bent shapes.
Use of a Coating Agent Composition for Lining Containers
The invention relates to the use of a coating agent composition for lining containers as well as a method for cleaning a container that has a corresponding lining and in which at least one product has been stored and/or transported.
Foamed isocyanate-based polymer
There is described a foamed isocyanate-based polymer derived from a reaction mixture comprising: an isocyanate; a polyol composition comprising a first prescribed amount of polymer particles dispersed in a base polyol; a second prescribed amount of biomass-based carbonaceous particulate material; and a blowing agent. In one embodiment, the foamed isocyanate-based polymer having an Indentation Force Deflection when measured pursuant to ASTM D3574-11 which is within about 15% as that of a reference foam produced by omitting the biomass-based carbonaceous particulate material from the reaction mixture and increasing the amount of polymer particles in the polymer polyol composition to equal the sum of the first prescribed amount and the second prescribed amount. In another embodiment, the foamed polymer has a cellular matrix comprising a plurality of interconnected struts, the biomass-based carbonaceous particulate material conferring to the cellular matrix a load efficiency of at least about 5 Newtons/weight % of biomass-based carbonaceous particulate material. A process to produce the foamed isocyanate-based polymer is also described. A polyol-based dispersion to produce the foamed isocyanate-based polymer is also described. It has been discovered that a relatively expensive petroleum-based copolymer polyol can be fully substituted by a relative inexpensive bio-based (amorphous carbon) dispersion with no significant compromise in important physical properties in the resulting polyurethane foam.
Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
This invention relates to polyurethane foams which exhibit decreased aldehyde emission, to a process of preparing these polyurethane foams, and to a method of decreasing aldehyde emissions in foams. The polyurethane foams herein additionally comprise a small quantity of a polyhydrazodicarbonamide dispersion polyol to the isocyanate-reactive component, or a trimerized hexamethylene diisocyanate to the polyisocyanate component.
POLYMER-MODIFIED POLYOL DISPERSION
The invention relates to a method of making a polymer-modified polyol having a solid content from 13 to 55 wt. % wherein an olamine is reacted with an organic polyisocyanate in the presence of a base polyol and at least one catalyst, wherein said at least one catalyst is a zinc carboxylate, and wherein the base polyol has hydroxyl functions wherein more than 20% of said hydroxyl functions are primary hydroxyl functions. The invention further relates to a polymer-modified polyol obtainable with the method of the invention, the use of the polymer-modified polyol for the preparation of optionally foamed plastics, and to a method for the preparation of optionally foamed plastics using the polymer-modified polyol of the invention.