The present invention relates to a two-component coating system comprising a first component and a second component each of which is separate and distinct from each other, wherein the first component comprises a carboxylic acid functional polymer dissolved and/or dispersed in an aqueous medium, and the second component comprises a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): b) whereby m is an integer from 1 to 8; and R and R are both H b) one or more linking chains wherein each one of these linking chains links two of the structural units A; c) one or more connecting groups whereby each one of the connecting groups connects two of the structural units A; and d) a molecular weight in the range from 840 Daltons to 5000 Daltons, wherein the molecular weight is measured using MALDI-TOF mass spectrometry.

The present invention relates to a two-component coating system comprising a first component and a second component each of which is separate and distinct from each other, wherein the first component comprises a carboxylic acid functional polymer dissolved and/or dispersed in an aqueous medium, and the second component comprises a multi-aziridine compound having: a) from 2 to 6 of the following structural units (A): b) whereby m is an integer from 1 to 8; and R and R are both H b) one or more linking chains wherein each one of these linking chains links two of the structural units A; c) one or more connecting groups whereby each one of the connecting groups connects two of the structural units A; and d) a molecular weight in the range from 840 Daltons to 5000 Daltons, wherein the molecular weight is measured using MALDI-TOF mass spectrometry.

Caprolactone polyols and prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes including the same are described herein. The caprolactone polyol is made by a process including admixing caprolactone monomers and pentaspiroglycol (PSG) to form an initiator-caprolactone mixture or reaction mixture, adding one or more catalyst to the initiator-caprolactone mixture to form a reaction mixture, and polymerizing, such as ring opening polymerization, the caprolactone monomers in the reaction mixture, thereby forming the caprolactone polyol. The films or coatings comprising or produced from the prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes described herein have improved mechanical properties and chemical resistance, as compared to standard, commercially available polyols. Methods of making and using the caprolactone polyol and the prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes, as well as films or coating comprising or prepared from the same, are also described herein.

Caprolactone polyols and prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes including the same are described herein. The caprolactone polyol is made by a process including admixing caprolactone monomers and pentaspiroglycol (PSG) to form an initiator-caprolactone mixture or reaction mixture, adding one or more catalyst to the initiator-caprolactone mixture to form a reaction mixture, and polymerizing, such as ring opening polymerization, the caprolactone monomers in the reaction mixture, thereby forming the caprolactone polyol. The films or coatings comprising or produced from the prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes described herein have improved mechanical properties and chemical resistance, as compared to standard, commercially available polyols. Methods of making and using the caprolactone polyol and the prepolymer compositions, polyurethane dispersions, or waterborne polyurethanes, as well as films or coating comprising or prepared from the same, are also described herein.

The present invention relates to a multi-aziridine crosslinker composition, characterized in that the multi-aziridine crosslinker composition is an aqueous dispersion having a pH ranging from 8 to 14 and comprises a multi-aziridine compound in dispersed form, wherein said multi-aziridine compound has: a. from 2 to 6 of the following structural units A: whereby R.sub.1 is H, R.sub.2 and R.sub.4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, R a is an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, m is 1, b. one or more linking chains wherein each one of these linking chains links two of the structural units A; and c. a molecular weight in the range from 500 to 10000 Daltons wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description. ##STR00001##

The present invention relates to a multi-aziridine crosslinker composition, characterized in that the multi-aziridine crosslinker composition is an aqueous dispersion having a pH ranging from 8 to 14 and comprises a multi-aziridine compound in dispersed form, wherein said multi-aziridine compound has: a. from 2 to 6 of the following structural units A: whereby R.sub.1 is H, R.sub.2 and R.sub.4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, R a is an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, m is 1, b. one or more linking chains wherein each one of these linking chains links two of the structural units A; and c. a molecular weight in the range from 500 to 10000 Daltons wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description. ##STR00001##

The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A) whereby R.sub.1 is H; R.sub.2 and R.sub.4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R.sub.3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R.sub.2 and R.sub.3 (in case R.sub.2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R and R are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight of at least 600 Daltons, wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A) whereby R.sub.1 is H; R.sub.2 and R.sub.4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R.sub.3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R.sub.2 and R.sub.3 (in case R.sub.2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R and R are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight of at least 600 Daltons, wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

Disclosed are microcapsule compositions each comprising a microcapsule suspended in an aqueous phase and a viscosity control agent, wherein the viscosity control agent is an acrylate copolymer, a cationic acrylamide copolymer, or a polysaccharide. Also disclosed are consumer products containing such a microcapsule composition.

The present invention relates to a process for producing a coating from an aqueous, radiation-curable coating composition, wherein the process comprises the steps in the sequence (1) to (4): (1) applying an aqueous, radiation-curable coating composition on a surface of a substrate, (2) drying the aqueous, radiation-curable coating composition, affording an at least partially dried coating composition, (3) irradiating the at least partially dried coating composition with UV light having a wavelength s 220 nm under inert atmosphere, followed by (4) irradiating with UV light having a wavelength 300 nm or with E-beam, wherein the aqueous, radiation-curable coating composition is a dispersion comprising: (A) at least one water-dispersible polyurethane (A), wherein the polyurethane (A) has a urea group (NHCONH) concentration of at least 0.1 milli-equivalents per g of polyurethane (A) and of at most 2.6 milli-equivalents per g of polyurethane (A) and the polyurethane (A) is essentially free of radiation-curable, ethylenically unsaturated bonds, (B) at least one radiation-curable diluent (B) with a molar mass less than 750 g/mol and with an acrylate functionality of from 2 to 5, and (C) water and optionally organic solvent, whereby the optional organic solvent is present in an amount of at most 30 wt. %, based on the total amount of water and organic solvent, wherein the amount of (A) is from 30 to 85 wt. % and the amount of (B) is from 15 to 70 wt. %, based on the total amount of (A) and (B).