Provided is a solventless two-component adhesive having excellent processed appearance and processability while exhibiting excellent adhesive strength even with aging at room temperature (around 25° C.) and in a short period of 12 hours. Provided are a two-component curable adhesive containing a polyisocyanate composition (X) containing a polyisocyanate (A) and a resin composition (Y) containing a polyol (B) as essential components, the two-component curable adhesive satisfying (1) to (3), as well as a laminated film and a packaging body produced using the two-component curable adhesive: (1) a tensile shear adhesive strength (N1) when provided between two bases and after a lapse of 30 minutes after pressure bonding is 0.5 N/cm.sup.2 or more; (2) the tensile shear adhesive strength (N1) when provided between two bases and after a lapse of 30 minutes after pressure bonding is three times or less a tensile shear adhesive strength (N2) after a lapse of 10 minutes after pressure bonding; and (3) a tensile shear adhesive strength (N3) when provided between two bases and after a lapse of 5 hours after pressure bonding is 20 N/cm.sup.2 or more.

The present technology provides a polyurethane composition including: a main agent; and a curing agent, wherein the main agent includes a urethane prepolymer having an isocyanate group, a morpholine compound having one morpholine ring, and an ether compound having two dimethylamino groups, and the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule.

The present technology provides a polyurethane composition including: a main agent; and a curing agent, wherein the main agent includes a urethane prepolymer having an isocyanate group, a morpholine compound having one morpholine ring, and an ether compound having two dimethylamino groups, and the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength.

Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and a polyol component comprising at least one highly-reactive amine-initiated polyol are disclosed. The at least one amine-initiated polyol comprises primary hydroxyl groups and a backbone incorporating one or more tertiary amines. The amine-initiated polyol further comprises a functionality of from 2 to 12, a hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s. The polyol component can further comprise a non-amine-initiated polyol. The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Still further, a laminate comprising the adhesive compositions is disclosed.

Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and a polyol component comprising at least one highly-reactive amine-initiated polyol are disclosed. The at least one amine-initiated polyol comprises primary hydroxyl groups and a backbone incorporating one or more tertiary amines. The amine-initiated polyol further comprises a functionality of from 2 to 12, a hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s. The polyol component can further comprise a non-amine-initiated polyol. The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Still further, a laminate comprising the adhesive compositions is disclosed.