The application relates to a two-component composition comprising: a composition A comprising: at least one polyurethane P having at least two terminal methacrylate functions, the polyurethane content P being at least 6% by weight relative to the total weight of composition A; at least one reducing agent; and at least one methacrylate monomer; a composition B comprising: at least one oxidizing agent; and optionally at least one methacrylate monomer,
said polyurethane P being obtained by a method comprising: E1) a step of preparing an NCO-terminated polyurethane, comprising the polyaddition reaction between: i) at least one polyisocyanate; and ii) at least one polyol; E2) reacting the product formed at the end of step E1) with at least one methacrylate monomer M having at least one hydroxyl function.

The present invention relates to a polymer composition comprising a polymeric matrix and particles of an impact modifier within the polymeric matrix, wherein the impact modifier comprises at least one urethane group and the impact modifier is obtainable by reacting in situ within the polymeric matrix a) a polyol comprising a dimer fatty residue; and b) a polyisocyanate. The invention also relates to a method of making the polymer composition.

Provided is a polyurethane resin-forming composition for a membrane-sealing material, the polyurethane resin-forming composition contributing to formation of (1) a urethane resin that is excellent in moldability, has a suppressed elution amount of a low-molecular-weight reaction product, and has excellent appearance or (2) a urethane resin that has a low viscosity, is excellent in cast moldability, and has a reduced water elution amount of a low-molecular-weight reaction product and a reduced solvent elution amount of a molded product.

The polyurethane resin-forming composition for a membrane-sealing material comprises: a polyisocyanate prepolymer (A) or an allophanate group-containing polyisocyanate prepolymer (A′) comprising a reaction product of a diphenylmethane diisocyanate (a1-1) and/or a modified product of a diphenylmethane diisocyanate (a1-2), and an active hydrogen-containing compound (a2); and a castor oil polymerized polyol (b1) comprising a castor oil polymerization product.

Methods are provided for producing bio-oil polyols, alkoxylating bio-oil polyols to provide polyols, and for employing the alkoxylated bio-oil polyols for making polymers or copolymers of polyesters or polyurethanes.

A polyester urethane polymer containing isocyanate groups and being liquid at ambient temperature, obtained by reacting at least one monomeric diisocyanate and dimer fatty acid-based polyester diol having OH-number ranging between 28 and 120 mg KOH/g in NCO/OH ratio of at least 3/1, and by subsequently removing large part of monomeric diisocyanate by means of suitable separation process, wherein polymer has NCO content ranging between 1.5 and 6% by wt. and maximum monomeric diisocyanate content of 0.5% by wt. The polymer permits the production of moisture-curing polyurethane compositions for application in ambient temperatures, having improved properties in terms of open time, adhesion, application and weather resistance, with unchanged good properties of storage stability, curing rate, strength, ductility, elasticity and hazardous material classification. Compositions of this type are particularly suitable for use as elastic adhesives in replacement glass for vehicles.

A two-component polyurethane composition including a polyol component and a polyisocyanate component, wherein the polyol component comprises at least one polyester polyol A1 based on dimer fatty acids and/or dimer fatty alcohols having an OH number of 65-350 mg KOH/g, at least one polybutadiene polyol A2 and at least one alkoxylated alkylenediamine A3. The polyurethane composition has high strength and only a minor dependence of the mechanical properties, especially strength, on temperature, especially in the range from −40° C. to +100° C.

Described herein is an aqueous basecoat material including at least one aqueous polyurethane-polyurea dispersion (PD) with polyurethane-polyurea particles present in the dispersion and having an average particle size of 40 to 2000 nm and a gel fraction of at least 50%, and also including at least one aqueous dispersion (wD) which includes a polymer prepared by a successive radical emulsion polymerization of three different mixtures (A), (B), and (C), of olefinically unsaturated monomers. Also described herein are multicoat paint systems produced using the basecoat materials.

A two-component polyurethane adhesive including a polyol component K1 and a polyisocyanate component K2; wherein the polyol component K1 includes at least one diol A1 having two primary hydroxyl groups and a molecular weight in the range from 60 to 150 g/mol, at least one triol A2 having an average molecular weight in the range from 1,000 to 10,000 g/mol, at least one polyester polyol A3 based on dimer fatty acids and/or dimer fatty alcohols, especially based on dimer fatty acids; and the polyisocyanate component K2 includes at least one polyisocyanate B1 and/or at least one polyurethane polymer B2 having isocyanate groups.

In an aspect, a curable composition comprises an acid catalyzed urethane (meth)acrylate oligomer comprising an acid catalyst; a cyanoacrylate monomer; a metallocene compound; a free radical polymerization inhibitor; and an acidic anionic polymerization inhibitor. In yet another aspect, a method of making a cured composition comprises forming the curable composition; and curing the curable composition by exposing it to light to form the cured composition.

The present invention relates to a composition for forming an environmentally friendly polyurethane foam, the composition having improved storage stability, air permeability, and anti-oxidation characteristics and to a method for manufacturing a polyurethane foam and, more specifically, to an isocyanate pre-polymer prepared by reaction of a polyisocyanate and a polyol component comprising a bio-polyol, to a composition for forming an environmentally friendly polyurethane foam, the composition having improved storage stability, air permeability, and anti-oxidative characteristics by comprising the pre-polymer as one component, to a method for manufacturing a polyurethane foam using the same, and to an environmentally friendly polyurethane foam manufactured thereby.