The present invention relates to a composition comprising 10 to less than 50 wt.-% of at least one oligomeric polyisocyanate a-1) based on hexamethylene diisocyanate and more than 50 to 90 wt.-% of at least one polyisocyanate a-2) based on isophorone diisocyanate, comprising monomeric isophorone diisocyanate and at least one oligomeric isophorone diisocyanate, and an isocyanate-reactive component selected from the group consisting of polyester polyol, polyether polyol and mixtures thereof. It has been shown that the above mentioned mixture of the specific isocyanate group containing components improves the thermal and mechanical properties of a cured composition. Thus prepared molded articles are particularly suitable for the preparation of spectacle lenses, inter alia due to these properties.

Adhesive compositions comprise a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

Provided is a developing roller including a shaft body, an elastic layer formed on an external circumference of the shaft body, and a surface layer formed on an external circumference of the elastic layer. The surface layer is formed of polyurethane containing a reaction product of a fluoroethylene vinyl ether copolymer and an isocyanurate form of isocyanate and having a film thickness of from 0.5 μm through 2.0 μm. The developing roller has grooves in a surface of the developing roller. The angle of the grooves from a circumferential direction is from 0 degrees through 30 degrees.

A solvent-based two-component polyurethane-type adhesive composition comprises an —OH component and an —NCO component. The —OH component comprises an amorphous prepolymer including two —OH end groups, with a number-average molar mass M.sub.n of 8000 to 12, 000 g and is chosen from: a) a copolyester (A1) obtained by a polycondensation reaction of at least one aliphatic diol (i) with at least one aromatic diacid (ii) and at least one aliphatic diacid (iii); and b) a polyurethane (A2) obtained by a polyaddition reaction between an aliphatic diisocyanate compound and an amorphous copolyester diol with a number-average molecular weight M.sub.n ranging from 4000 to 11 500 g/mol. The —NCO component comprises a compound (B1) including three —NCO end groups, obtained by the reaction of meta-xylylene diisocyanate (m-XDI) with a triol, said compound (B1) being alone or as a mixture with a compound (B2) derived from an aliphatic diisocyanate.

A process for producing rigid PUR/PIR foams comprising A1 an isocyanate-reactive component, A2 a flame retardant, A3 a blowing agent, A4 a catalyst, A5 optionally auxiliaries and additives, and B an organic polyisocyanate component. Component A1 comprises a triurethane triol A1.1 and a compound A1.2 selected from the group consisting of polyether polyol, polyester polyol, polyether carbonate polyol, and polyether ester polyol. Also disclosed is a rigid PUR/PIR foam, an insulating material, a composite element, and a mixture.

A polyurethane elastomer memory foam composition includes an organic diisocyanate, a chain extender, a crosslinker, a plasticizer, a surfactant, a foaming agent, and a polyester resin, the polyester resin being a random copolymer having randomly distributed subunits of formula 1:

##STR00001##

where: R is ethylene, octylene, or decylene; a is from about 1 to about 99 mole % of the polyester resin; b is from about 1 to about 99 mole % of the polyester resin; c is from 0 to about 10 mole % of the polyester resin; and a+b+c=100 mole % of the polyester resin.

Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of trans1233zd and wherein the polyol comprises a polyol or mixture of polyols such that the trans1233zd(E) has a solubility in said polyol of 20 pphp or less and (b) forming a foam from said foamable composition.

A hot melt moisture cure adhesive composition that includes a polyurethane prepolymer that includes the reaction product of diisocyanate, a polyester triol first polyol, a crystalline polyester second polyol, and a third polyol different from the first and second polyols.

Disclosed herein is a process for producing rigid polyisocyanurate foams, where (a) aromatic polyisocyanate, (b) isocyanate-reactive compounds including at least one polyetherol (b1) and/or polyesterol (b2), wherein where the number-average content of isocyanate-reactive hydrogen atoms of components (b 1) and (b2) is at least 1.7, (c) catalyst, (d) blowing agents, (e) flame retardants, (f) optionally auxiliary and additive substances and (g) optionally compounds having aliphatic hydrophobic groups and not falling under the definition of compounds (a) to (f) are mixed to afford a reaction mixture and allowed to cure to afford a rigid polyisocyanurate foam. Further disclosed herein is a rigid polyisocyanurate foam obtainable by the process.

This invention relates to adhesive compositions comprising a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.