C08G18/4252

SYNTHESIS METHOD FOR HIGH WEATHER-RESISTANT RED WATER-BASED POLYURETHANE EMULSION
20200299448 · 2020-09-24 ·

The present invention relates to the field of chemical industries, and discloses a method for synthesizing a highly weather-resistant red waterborne polyurethane emulsion, including using oligomeric diol, aliphatic diisocyanate, iron-rich red attapulgite clay, and a hydrophilic chain extender for stepwise polymerization to synthesize a red attapulgite clay modified hydrophilic polyurethane prepolymer, then self-emulsifying and dispersing in metered water, and then adding a small molecule diamine chain extender for chain extension to obtain a red attapulgite clay modified red waterborne polyurethane emulsion. The preparation method of the present invention is easy to operate, energy-saving and environmentally friendly. The prepared red waterborne polyurethane emulsion has a solid content>30 wt. % and the pH between 6.0 and 7.0, and its coating product has the advantages of good water resistance, high weather resistance, vivid color, etc., and has a broad market prospect.

POLYUREA SYSTEMS, PROCESSES FOR PREPARING THE SAME AND USE THEREOF FOR POSTOPERATIVE ADHESION BARRIERS
20200223973 · 2020-07-16 ·

Polyurea systems comprising: (a) an amino-functional aspartic ester of the general formula (I)

##STR00001##

wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH.sub.2).sub.n, R.sub.1 and R.sub.2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents an integer of at least 2; and (b) an isocyanate functional prepolymer having a residual monomer content of less than 1% by weight, the prepolymer prepared by reacting: (b1) an aliphatic isocyante; and (b2) a polyol component having a number average molecular weight of 400 g/mol and an average OH functionality of 2 to 6, wherein the polyol component comprises one or more constituents selected from the group consisting of polyester polyols, polyester-polyether polyols and mixtures thereof; processes for making the same; postoperative adhesions barriers prepared therewith and dispensing systems for such polyurea systems.

COMPOSITION FOR AUTOMOBILE INTERIOR SKIN, MANUFACTURING METHOD THEREOF, AND AUTOMOBILE INTERIOR SKIN MANUFACTURED USING THE SAME

A composition for an automotive interior skin, a method for manufacturing the same, and an automotive interior skin manufactured using the same. The composition for an automotive interior skin includes: 30 wt % to 70 wt % of a polyol compound; 5 wt % to 40 wt % of dicyclohexylmethane-4,4-diisocyanate; and 5 wt % to 30 wt % of an aromatic glycol-based chain extender.

Polyester adhesive composition and adhesive sheet

Provided are a polyester-based pressure-sensitive adhesive composition having high wetting ability and superior adherability and light peelability, and a pressure-sensitive adhesive sheet produced with such a pressure-sensitive adhesive composition. The polyester-based pressure-sensitive adhesive composition includes a polyester obtained by polycondensation of a difunctional or polyfunctional carboxylic acid and a diol; a fatty acid ester; and a crosslinking agent, wherein the polyester has a weight average molecular weight of 8,500 to 50,000, and the fatty acid ester has no additional functional group and has a molecular weight of 200 to 700. The polyester-based pressure-sensitive adhesive composition contains 10 to 150 parts by weight of the fatty acid ester based on 100 parts by weight of the polyester.

Semi-Crystalline Mixture of Polyester Polyols, and the Use Thereof
20200148814 · 2020-05-14 ·

The present invention relates to a semi-crystalline mixture of polyester polyols which recrystallises upon melting and which can be obtained by polycondensing a reaction mixture comprising one or more dicarboxylic acids selected from saturated aliphatic dicarboxylic acids having an even number of at least 8 methylene groups, and one or more diols selected from aliphatic diols which have at least one ether function. The invention also relates to a polymeric material which is obtained from the chemical modification of the mixture of polyester polyols with organic compounds which contain at least one isocyonate group and/or epoxide group. The mixtures and materials according to the invention are characterised by relatively low melting enthalpies, while the melting temperature can be set in a range of 30 to 60 C., meaning that it is possible to obtain easily fusible formulations containing the mixtures and materials according to the invention. The mixtures and materials according to the invention also provide such formulations with a high elasticity and breaking resistance. The present invention therefore includes the use of the polyester polyols and polymeric materials according to the invention as deforming, fusing, and extrusion means in thermoplastic materials, and the use thereof for producing adhesives and sealants, in particular hot-melt adhesives and reactive adhesives.

Polyurea systems, processes for preparing the same and use thereof for postoperative adhesion barriers

Polyurea systems comprising: (a) an amino-functional aspartic ester of the general formula (I) ##STR00001##
wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH.sub.2).sub.n, R.sub.1 and R.sub.2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents an integer of at least 2; and (b) an isocyanate functional prepolymer having a residual monomer content of less than 1% by weight, the prepolymer prepared by reacting: (b1) an aliphatic isocyante; and (b2) a polyol component having a number average molecular weight of 400 g/mol and an average OH functionality of 2 to 6, wherein the polyol component comprises one or more constituents selected from the group consisting of polyester polyols, polyester-polyether polyols and mixtures thereof; processes for making the same; postoperative adhesions barriers prepared therewith and dispensing systems for such polyurea systems.

PROCESS FOR PREPARING A POLYURETHANE USING A POLYESTER POLYOL COMPRISING POLYCYCLIC AROMATIC MOIETIES
20200095368 · 2020-03-26 · ·

The present invention is directed to a polyisocyanate polyaddition product, obtained or obtainable according to a process containing reacting at least a polyisocyanate composition (C-I) comprising at least one polyisocyanate; and a composition (C-II) comprising at least one compound (C-A) having at least two functional groups which are reactive towards isocyanate groups, wherein the compound (C-A) has a molecular weight of 500 g/mol or more and comprises polycyclic aromatic moieties. The present invention is further directed to a process for preparing said polyisocyanate polyaddition product and the use thereof in a cable, conveyor belt, roller, seal for gasket or railway pad.

POLYETHERESTER POLYOL AND USE THEREOF FOR PRODUCING POLYURETHANE RIGID FOAM MATERIALS

A polyetherester polyol is synthesized from reactants including a) aromatic acid or aromatic anhydride or a mixture thereof, and b) OH-functional starter molecules which contain alcoholamine or amine-initiated polyether polyol. Corresponding rigid polyurethane foams produced with the polyetherester polyol are useful for insulation used in appliance applications.

Thermoplastic polyurethane resin composition having enhanced texture and durability and production method thereof

A thermoplastic polyurethane resin composition having enhanced texture and durability is capable of ensuring excellent appearance quality by applying polyester polyol including, polytetramethylene ether glycol and polydimethylsiloxane diol to an existing thermoplastic polyurethane resin composition, having excellent mechanical properties and long-term durability, such as anti-scratch and abrasion resistance, while largely enhancing texture quality, largely reducing producing costs by replacing a material such as natural leather, reducing generation of a volatile organic compound (VOC), and using the VOC in a surface material for a vehicle interior material.

AROMATIC POLYESTER POLYETHER POLYOLS, POLYURETHANES MADE THEREFROM AND BUILDING MATERIALS COMPRISING SAME

This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure. The disclosure provides aromatic polyester polyether polyols and compositions comprising such polyols. The disclosed aromatic polyester polyether polyols and compositions including same are the products of the transesterification reaction of polyethylene terephthalate (PET) and an ethoxylated triol, namely glycerin or trimethylolpropane, wherein the degree of ethoxylation is from 1 to 9 moles. At least some of the PET used to generate the aromatic polyester polyether polyols is derived from recycled PET. The disclosed aromatic polyester polyether polyols have utility in preparing polyurethane materials, for example.