Aspects of the present disclosure provide coatings and methods for depositing coatings onto surfaces. In one aspect, a method for forming a coating includes applying a composition to a surface of a component, the composition including a first polymer, a second polymer that is a fluoropolymer, an isocyanate, and a curative. The method includes curing the mixture at a first temperature of about 50° C. or greater and increasing the first temperature to a second temperature of about 80° C. or greater. The method includes obtaining a coating disposed on the surface of the component, the coating having a thickness of from about 10 mils to about 50 mils and a void density of less than 5 voids of size 0.5 mm or greater per cm.sup.2.

The present invention relates to a method for preparing a wood modifier and a method for wood modification, and in particular, to a method for preparing a room temperature cured multifunctional wood modifier and a method for wood modification to solve the problems of high construction temperature, high toxicity, poor leaching-resistance and single function of existing wood modifiers. The method includes: step 1: weighing a hydrophobic polymer resin, an additive, a curing agent and a solvent, mixing and then stirring at room temperature to obtain a functional reagent A; step 2: weighing nanoparticles, a surface modifier and toluene, mixing and then stirring, cleaning with acetone, centrifuging, and drying to obtain a functional reagent B; step 3: adding a functional reagent C into the functional reagent A, evenly stirring, adding the functional reagent B, and performing ultrasonic processing to obtain the multifunctional wood modifier.

Low-friction fluorinated coatings are disclosed herein. A preferred low-friction material contains a low-surface-energy fluoropolymer having a surface energy between about 5 mJ/m.sup.2 to about 50 mJ/m.sup.2, and a hygroscopic material that is covalently connected to the fluoropolymer in a triblock copolymer, such as PEG-PFPE-PEG. The material forms a lubricating surface layer in the presence of humidity. An exemplary copolymer comprises fluoropolymers with average molecular weight from 500 g/mol to 20,000 g/mol, wherein the fluoropolymers are (α,ω)-hydroxyl-terminated and/or (α,ω)-amine-terminated, and wherein the fluoropolymers are present in the triblock structure T-(CH.sub.2—CH.sub.2—O)—CH.sub.2—CF.sub.2—O—(CF.sub.2—CF.sub.2—O).sub.m(CF.sub.2—O).sub.n—CF.sub.2—CH.sub.2—(O—CH.sub.2—CH.sub.2).sub.p-T where T is a hydroxyl or amine terminal group, p=1 to 50, m=1 to 100, and n=1 to 100. The copolymer also contains isocyanate species and polyol or polyamine chain extenders or crosslinkers possessing a functionality of preferably 3 or greater. These durable, solvent-resistant, and transparent coatings reduce insect debris following impact.

An anti-fouling coating is provided, containing a continuous matrix comprising a first component; a plurality of inclusions comprising a second component, wherein the first component is a low-surface-energy polymer having a surface energy, and the second component is a hygroscopic material containing one or more ionic species. The low-surface-energy polymer and the hygroscopic material are chemically connected ionically or covalently, such as in a segmented copolymer composition comprising fluoropolymer soft segments and ionic species contained within the soft segments. The continuous matrix and the inclusions form a lubricating surface layer in the presence of humidity. Coefficient-of-friction experimental data is presented for various sample coatings. The incorporation of ionic species into the polymer chain backbone increases the hygroscopic behavior of the overall structure. Improvement in lubrication enables material to be cleared from a surface using the natural motion of an automotive or aerospace vehicle.

A curable composition includes a blocked isocyanate in which an NCO group of an isocyanate compound having a H.sub.6XDI skeleton is blocked by a blocking agent having an O═C—CH—C═O skeleton, a curable functional group-containing fluorine polymer, and an alkoxysilane having a functional group including at least one element of a group 15 element to a group 16 element of the periodic table (excluding oxygen). In the curable composition allowing a titanium oxide to be contained, the molar ratio of the curable functional group to the NCO group is 0.5 to 10; the content ratio of the alkoxysilane with respect to 100 pans by mass of the total amount of the blocked isocyanate and the fluorine polymer is 0.2 to 8 parts by mass; and the content ratio of the titanium oxide with respect to 100 parts by mass of the fluorine polymer is 0 to 200 parts by mass.

Some variations provide a method of forming a transparent icephobic coating, comprising: obtaining a hardenable precursor comprising a first component and a plurality of inclusions containing a second component, wherein one of the first component or the second component is a low-surface-energy polymer, and the other is a hygroscopic material; applying mechanical shear and/or sonication to the hardenable precursor; disposing the hardenable precursor onto a substrate; and curing the hardenable precursor to form a transparent icephobic coating. The coating contains a hardened continuous matrix containing regions of the first component separated from regions of the second component on an average length scale of phase inhomogeneity from 10 nanometers to 10 microns, such as less than 1 micron, or less than 100 nanometers. The transparent icephobic coating may be characterized by a light transmittance of at least 50% at wavelengths from 400 nm to 800 nm, through a 100-micron coating.

The present technology provides a curable silicone-based composition comprising a hybrid silicone polymer, a catalyst, and a filler. The present technology provides a curable silicone composition comprising a polymer A comprising an organic molecule or a siloxane molecule comprising an alkoxy radical, a hydroxyl radical, an isocyanate radical, a primary amine, or a carboxylic radical; optionally a polymer B comprising an organic molecule, a siloxane molecule, or a hybrid-siloxane molecule; a catalyst; and a filler.

Some variations provide an anti-fouling segmented copolymer composition comprising: (a) one or more first soft segments selected from fluoropolymers; (b) one or more second soft segments selected from polyesters or polyethers; (c) one or more isocyanate species possessing an isocyanate functionality of 2 or greater, or a reacted form thereof; (d) one or more polyol or polyamine chain extenders or crosslinkers, or a reacted form thereof; and (e) a fluid additive selectively disposed in the first soft segments or in the second soft segments. Other variations provide an anti-fouling segmented copolymer precursor composition comprising a fluid additive precursor selectively disposed in the first soft segments or in the second soft segments, wherein the fluid additive precursor includes a protecting group. The anti-fouling segmented copolymer composition may be present in an anti-ice coating, an anti-bug coating, an anti-friction coating, an energy-transfer material, or an energy-storage material, for example.

A composition including at least one compound having a perfluoropolyether group and a curable site, wherein in a molecular weight distribution curve in gel permeation chromatography measurement, the following formula is satisfied: M2/M1≤3.5, wherein M1 is a molecular weight at a main peak, and M2 is a molecular weight at 25% intensity of an intensity of the main peak on a higher molecular weight side than M1. Also disclosed is a curable composition containing the composition and a method for producing the curable composition.

This disclosure describes incorporation of a liquid additive within one or more phases of a multiphase polymer coating. The structure of the microphase-separated network provides reservoirs for liquid in discrete and/or continuous phases. Some variations provide an anti-fouling segmented copolymer composition comprising: (a) one or more first soft segments selected from fluoropolymers; (b) one or more second soft segments selected from polyesters or polyethers; (c) one or more isocyanate species; (d) one or more polyol or polyamine chain extenders or crosslinkers; and (e) a liquid additive disposed in the first soft segments and/or the second soft segments. The first soft segments and the second soft segments are microphase-separated on a microphase-separation length scale from 0.1 microns to 500 microns. These solid/liquid hybrid materials improve physical properties associated with the coating in applications such as anti-fouling (e.g., anti-ice or anti-bug) surfaces, ion conduction, and corrosion resistance.