Patent classifications
C08G18/5033
POLYOL COMPONENTS AND USE THEREOF FOR THE PRODUCTION OF RIGID POLYURETHANE FOAMS
This invention relates to a polyol component P), to a process for preparing rigid polyurethane foams by using said polyol component P) and also to the rigid polyurethane foams themselves.
Hydrocarbon Blown Polyurethane Foam Formulation Giving Desirable Thermal Insulation Properties
Polyurethane/polyisocyanurate foam insulation described herein is derived from a composition that contains an organic polyisocyanate, an isocyanate reactive material containing at least about 20% by weight, based on the total weight of the composition, of an aromatic polyester polyol, a hydrocarbon blowing agent, a first catalyst selected from the group consisting of a carboxylate salt of an alkali metal, a carboxylate salt of an alkaline earth metal, a carboxylate salt of a quaternary ammonium, and combinations thereof, and a second catalyst comprising a non-reactive tertiary amine, wherein a molar ratio of the first catalyst to the second catalyst is less than about 1.25, the composition gels quickly, and the composition has an isocyanate index greater than about 175. Such an insulating foam has a ratio of thermal conductivity at 75 F. to thermal conductivity at 25 F. between about 0.98 and about 1.10.
Composition for polyurethane foaming, polyurethane foam and use thereof
A composition for polyurethane foaming, a polyurethane foam and a use thereof. The composition contains two different polyols with a polyethylene oxide ether structure and a polypropylene oxide ether structure, and a specific type of catalyst, flame retardant and water are added thereto; at the same time, the composition contains a small amount of a surfactant and other small molecular alcohols. The traits of the product are that it is pale yellow and transparent, and the product is not layered during long-term storage. The above-mentioned composition and polyphenylpolymethylene polyisocyanate (PAPI) produce a low-density polyurethane foam by means of a foaming machine. The foam has a good thermal insulation effect and a high rate of yield, and the foam has a flame retardant property, that is to say, same can be used for construction insulation, and can also be used for packaging a buffer material, has a good thermal insulation, adhesion and dimensional stability, and has a low odor during the process of construction, the foaming agents all use water, and do not contain chlorofluorocarbon substances that destroy the ozone layer and climate.
2-PART REACTIVE URETHANE RESIN COMPOSITION AND METHOD FOR PRODUCING THEREOF
Provided is a material having an excellent sound-absorbing performance which can be easily applied to the desired area at the operation site and which can effectively prevent sound leakage
The material includes a 2-part reactive urethane resin composition prepared from a polyisocyanate component and a polyol-containing component, wherein the polyol-containing component comprises a polyol component (a), catalysts (b), a foam stabilizer (c), an amine compound having primary or secondary amino groups (d), and carbon dioxide (e).
The 2-part reactive urethane resin composition, when cured, is an open-cell soft polyurethane foam, wherein the average sound absorption coefficient of said polyurethane foam is 30% or more, measured in accordance with JIS A 1405-2:2007 for 63 hertz to 5000 hertz.
Hydrocarbon blown polyurethane foam formulation giving desirable thermal insulation properties
Polyurethane/polyisocyanurate foam insulation described herein is derived from a composition that contains an organic polyisocyanate, an isocyanate reactive material containing at least about 20% by weight, based on the total weight of the composition, of an aromatic polyester polyol, a hydrocarbon blowing agent, a first catalyst selected from the group consisting of a carboxylate salt of an alkali metal, a carboxylate salt of an alkaline earth metal, a carboxylate salt of a quaternary ammonium, and combinations thereof, and a second catalyst comprising a non-reactive tertiary amine, wherein a molar ratio of the first catalyst to the second catalyst is less than about 1.25, the composition gels quickly, and the composition has an isocyanate index greater than about 175. Such an insulating foam has a ratio of thermal conductivity at 75 F. to thermal conductivity at 25 F. between about 0.98 and about 1.10.
Insulated pipe containing polyurethane foam which is foamed by an environmentally friendly foaming agent and has a low degree of brittleness
Described herein is a process for producing a pipe insulated with polyurethane foam, where (a) isocyanates are mixed with (b) polyols, (c) blowing agent including at least one aliphatic, halogenated hydrocarbon compound (c1), made up of from 2 to 5 carbon atoms, at least one hydrogen atom and at least one fluorine and/or chlorine atom, where the compound (c1) includes at least one carbon-carbon double bond, (d) catalyst including N,N-dialkylbenzylamine, optionally (e) chain extenders and/or crosslinkers and optionally (f) auxiliaries and additives to give a reaction mixture, the reaction mixture is applied to a pipe for media and is allowed to cure to give the polyurethane foam. Also described herein is an insulated pipe obtained by such a process and a method of using such an insulated pipe as insulated composite wall pipe for district heating or district cooling networks laid in the ground.
STABILITY OF POLYURETHANE POLYOL BLENDS CONTAINING HALOGENATED OLEFIN BLOWING AGENTS
A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba)
Rigid polyurethane foam
A rigid polyurethane foam which has ultrafine cells, has a low thermal conductivity of 0.0190 W/(m.Math.K) or lower, exhibits excellent heat insulating properties and flame retardancy, and has very little impact on global warming, without using a special apparatus such as a gas loading device. Provided is a rigid polyurethane foam which is obtained by mixing and reacting raw materials including a polyol, a polyisocyanate, a blowing agent, and a catalyst. The rigid polyurethane foam contains the polyol containing a polyester polyol having an aromatic component concentration of 17-35 wt. %, and a non-amine-based polyether polyol and/or an aromatic amine-based polyether polyol; the polyisocyanate in which MDI/TDI are mixed at a ratio of 4/6 to 9/1; and the blowing agent containing a halogenated olefin.
POLYURETHANE FOAM PREMIXES CONTAINING HALOGENATED OLEFIN BLOWING AGENTS AND FOAMS MADE FROM SAME
The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.
Polyol component and use thereof for the production of rigid polyurethane foams
A polyol component P) contains at least two different polyether polyols A) and C), and at least one polyether ester polyol D). A process can be used for producing rigid polyurethane foams using the polyol component P), and the rigid polyurethane foams produced therefrom are useful.