Patent classifications
C08G18/6622
Aqueous binder compositions
The invention relates to mixtures of at least one acrylic resin dispersion A and a second dispersion B which is at least one of a polyurethane dispersion B1 which comprises, in its polymer, moieties derived from grafted fatty acids, and a mixture B2 of a polyurethane dispersion B21 and an aqueously dispersed alkyd resin B22, and to a method of use thereof for coating of porous substrates.
Composites formed from an absorptive filler and a polyurethane
Composite materials and methods for their preparation are described herein. The composite materials can comprise a polyurethane and an absorptive filler. The polyurethane can be formed from the reaction of at least one isocyanate selected from the group consisting of diisocyanates, polyisocyanates, and combinations thereof, and one or more isocyanate-reactive monomers. The one or more isocyanate-reactive monomers can comprise at least one polyol and a first isocyanate-reactive monomer which includes one or more isocyanate-reactive functional groups and a moiety configured to associate with the absorptive filler.
SUSTAINABLE POLYESTER POLYOL COMPOSITIONS
Polyester polyol compositions are disclosed. The polyol compositions, which comprise recurring units of a digested thermoplastic polyester, a glycol, and castor oil, ricinoleic acid, or a mixture of castor oil and ricinoleic acid, have hydroxyl numbers within the range of 20 to 150 mg KOH/g and average hydroxyl functionalities within the range of 2.5 to 3.5. The invention includes flexible polyurethane foams that incorporate the polyester polyols. Sustainable polyester polyols made completely or in substantial part from recycled, post-industrial, and/or biorenewable materials such as polyethylene terephthalate, glycols, and castor oil are provided. The polyols have desirable properties for formulating flexible polyurethane foams and other products.
POLYURETHANE FOAM-FORMING COMPOSITIONS, METHODS OF MAKING LOW DENSITY FOAMS USING SUCH COMPOSITIONS, AND FOAMS FORMED THEREFROM
Disclosed are polyurethane foam-forming compositions with a phase stable isocyanate-reactive composition that includes a halogenated olefin blowing agent that has low or no ozone depletion potential and low global warming potential. Such polyurethane foam-forming compositions are suitable for spray application to produce polyurethane foams that are believed to exhibit good fire resistance properties, low smoke generation and low or no scorch due to reduced exotherm, thereby making them particularly suitable for use, for example, as relatively thick wall and/or roof insulation.
Aqueous cationic polyurethane dispersions
An aqueous polyurethane resin dispersion, the polyurethane resin having a cationic group and a polyalkylene oxide in a side chain thereof and is obtainable by reacting a polyisocyanate with a polyether diol and with a polymeric diol such as a polyester diol, polyether diol, polycarbonate diol, polyacrylate diol or polyolefin diol and with a cationic polyol selected from the group consisting of an quaternary ammonium, a quaternary phosphonium, a tertiary sulfonium and a iodonium wherein the cationic polyol comprises at least two hydroxyl groups and has a total number of carbon atoms making up the carbon chains between the cationic charged atom and a hetero atom or end of the carbon chain of the cation over charge ratio of at least 12. The aqueous dispersion can be used in treatment liquids for inkjet printing and in inkjet inks.
Ultra low density biodegradable shape memory polymer foams with tunable physical properties
Compositions and/or structures of degradable shape memory polymers (SMPs) ranging in form from neat/unfoamed to ultra low density materials of down to 0.005 g/cc density. These materials show controllable degradation rate, actuation temperature and breadth of transitions along with high modulus and excellent shape memory behavior. A method of m ly low density foams (up to 0.005 g/cc) via use of combined chemical and physical aking extreme blowing agents, where the physical blowing agents may be a single compound or mixtures of two or more compounds, and other related methods, including of using multiple co-blowing agents of successively higher boiling points in order to achieve a large range of densities for a fixed net chemical composition. Methods of optimization of the physical properties of the foams such as porosity, cell size and distribution, cell openness etc. of these materials, to further expand their uses and improve their performance.
COMPOSITE MATERIAL COMPOSED OF OUTER LAYER AND POLYURETHANE FOAM LAYER
In a process for producing a composite element having at least a covering layer and polyurethane foam, the covering layer is inserted into a mold and a polyurethane reaction mixture is introduced onto the covering layer. The polyurethane reaction mixture is reacted to form a polyurethane foam, wherein the polyurethane reaction mixture is obtained by mixing a) polyisocyanate with b) compounds having isocyanate-reactive OH groups, c) blowing agents including water, d) thickeners and e) catalysts. Bis(N,N-dimethylaminoethoxyethyl) carbamate, N,N,N-trimethyl-N-hydroxyethylbis(aminopropyl ether), N,N,N-trimethyl-N-hydroxyethyl(aminoethyl ether) or mixtures thereof and/or tetramethyldiaminoethyl ether are employed as catalysts and the polyurethane foam has a density of not more than 200 g/dm.sup.3.
COMPOSITE MATERIAL COMPOSED OF OUTER LAYER AND POLYURETHANE FOAM LAYER
In a process for producing a composite element having at least a covering layer and polyurethane foam, the covering layer is inserted into a mold and a polyurethane reaction mixture is introduced onto the covering layer. The polyurethane reaction mixture is reacted to form a polyurethane foam, wherein the polyurethane reaction mixture is obtained by mixing a) polyisocyanate with b) compounds having isocyanate-reactive OH groups, c) blowing agents including water, d) thickeners and e) catalysts. Bis(N,N-dimethylaminoethoxyethyl) carbamate, N,N,N-trimethyl-N-hydroxyethylbis(aminopropyl ether), N,N,N-trimethyl-N-hydroxyethyl(aminoethyl ether) or mixtures thereof and/or tetramethyldiaminoethyl ether are employed as catalysts and the polyurethane foam has a density of not more than 200 g/dm.sup.3.
Rigid polyurethane foam
A rigid polyurethane foam includes the reaction product of an isocyanate and an isocyanate reactive component in the presence of a blowing agent. The isocyanate reactive component includes an aromatic polyester polyol, a rigid polyol, and an aliphatic polyester polyol. The rigid polyurethane foam has a tensile adhesion of greater than 35 kPa (5 psi) when disposed on a metal substrate or a polyester, polyurethane, or epoxy coated metal substrate, each having a substrate temperature of greater than 41 C. (105 F.), and tested in accordance with ASTM D1623-09. A method of forming a composite article comprising a substrate and the rigid polyurethane foam includes the steps of combining the isocyanate reactive component and the isocyanate in the presence of the blowing agent to form a reaction mixture and applying the reaction mixture to the substrate having a substrate temperature of greater than 41 C. (105 F.) to form the composite article.
Device and method for treatment of openings in vascular and septal walls
A device, system and method for treatment of an opening in vascular and/or septal walls including patent foramen ovale. The device has wings/stops on either end, an axis core covered in a shape memory foam and is deliverable via a catheter to the affected opening, finally expanding into a vascular or septal opening where it is held in place by the expandable shape memory stops or wings.