The present invention relates to thermoplastic polyurethanes obtainable or obtained by reacting at least a polyisocyanate composition comprising at least one polyisocyanate, at least one chain extender, and at least one polyol composition, wherein the polyol composition comprises at least one polyester polyol (P1) which is obtainable by reacting an aliphatic dicarboxylic acid having 2 to 12 carbon atoms and a mixture (M1) comprising propane-1,3-diol and a further diol (D1) having 2 to 12 carbon atoms, preferably butane-1,4-diol. The present invention also relates to a preparation process for such thermoplastic polyurethanes and also to the use of a thermoplastic polyurethane according to the invention or of a thermoplastic polyurethane obtainable or obtained by a process according to the invention for the production of extrusion products, films and shaped bodies or for the production of polymer compositions.

The present disclosure provides copolymers useful in medical devices. For example, the disclosure provides copolymers comprising the polymerization product ester block, ether blocks and diisocyanates. In certain embodiments, the disclosure provides a medical copolymer for implantation comprising ester blocks and ether blocks, wherein: the ester blocks comprise a negative free energy transfer and the ether blocks comprise a positive free energy transfer, the ether and ester blocks are less than 1/10 the length of said copolymer, and, the blocks are distributed such that no domain of contiguous blocks possessing the same polarity of free energy transfer are less than ⅓ of the molecular weight of the copolymer. The disclosure further provides methods of making the aforementioned polymers, and medical devices comprising the polymers.

Techniques regarding the polymerization of polyurethanes are provided. For example, one or more embodiments described herein can comprise synthesizing, via a polymerization reaction performed within a flow reactor, a polyurethane. The polymerization reaction can polymerize a diol with a diisocyanate.

Techniques regarding the polymerization of polyurethanes are provided. For example, one or more embodiments described herein can comprise synthesizing, via a polymerization reaction performed within a flow reactor, a polyurethane. The polymerization reaction can polymerize a diol with a diisocyanate.

Articles are provided including at least one polyurethane prepared from: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; (c) about 0.01 to about 1.0 equivalent of at least one polyol selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, octadecanediol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, bis(2-hydroxyethyl) terephthalate, 1,4-bis(hydroxyethyl)piperazine, N,N′,bis(2-hydroxyethyl)oxamide and mixtures thereof; and (d) about 0.01 to about 0.5 equivalent of at least one polyol selected from the group consisting of glycerol, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof, each based upon the about 1 equivalent of the at least one polyisocyanate, wherein the article has a Gardner Impact strength of at least about 400 in-lb according to ASTM D-5420-04.

A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ≥50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m.sup.3.

The present invention relates to a novel polyurethane-based UV-curable composition, comprising a low-crystallinity polyurethane polymer, a multifunctional thiol compound, a multifunctional epoxy resin compound, a photobase generator, and an optional photosensitizer. Adhesive films, adhesive tapes, and bonded members with excellent initial bonding performance, die cutting performance, overlap strength and drop-resistance performance may be obtained by using the polyurethane-based UV-curable composition provided by the present invention.

The present disclosure relates to spray polyether and polyester polyurethane elastomeric articles and associated methods of producing such elastomer articles. More specifically, the invention provides spray polyester polyurethane elastomer articles that exhibit excellent tensile and tear strength, superior elongation performance and improved abrasion resistance performance with tunable tensile modulus.

The present disclosure relates to spray polyether and polyester polyurethane elastomeric articles and associated methods of producing such elastomer articles. More specifically, the invention provides spray polyester polyurethane elastomer articles that exhibit excellent tensile and tear strength, superior elongation performance and improved abrasion resistance performance with tunable tensile modulus.

This invention provides a polymer thick film electrically conductive paste composition, comprising conductive metal powder, a resin blend of polyol and phenoxy resin, blocked aliphatic polyisocyanate and one or more polar, aprotic solvents. In one embodiment the paste composition is used to form electrically conductive adhesive. In another embodiment the paste composition is used to form an electrically conductive polymer thick film.