Polymer composite materials and methods of preparation are discussed. The composite material may comprise a polyurethane foam and a plurality of inorganic particles dispersed in the polyurethane foam. The composite material may have moisture movement properties, such that (a) a sample of the composite material having a length of 48 inches has a moisture movement of less than 0.15% along the length, and/or (b) a sample having a length of 6 inches has a moisture movement of less than 0.8% along the length, when submerged in 45° C. distilled water for 14 days.

Techniques regarding the polymerization of polyurethanes are provided. For example, one or more embodiments described herein can comprise synthesizing, via a polymerization reaction performed within a flow reactor, a polyurethane. The polymerization reaction can polymerize a diol with a diisocyanate.

Techniques regarding the polymerization of polyurethanes are provided. For example, one or more embodiments described herein can comprise synthesizing, via a polymerization reaction performed within a flow reactor, a polyurethane. The polymerization reaction can polymerize a diol with a diisocyanate.

An embodiment of the present technology is an isocyanate-based adhesive used for a surface-treated crystalline thermoplastic resin base material, the isocyanate-based adhesive having a value represented by (JIS-A hardness)/(strength at break [MPa])×(elongation at break (%))/100 of 2.0 to 70 after being cured by being allowed to stand still under a condition at 23° C. and 50% RH for 3 days, and the crystalline thermoplastic resin base material having a value represented by (δ.sup.d/δ.sup.p+δ.sup.p) of 2.0 to 30.0. δ.sup.p=γ.sup.p−γ.sup.p0 and δ.sup.d=|γ.sup.d−γ.sup.d0|, γ.sup.p0 is a polar term of surface free energy before the surface treatment, γ.sup.p is a polar term of surface free energy after the surface treatment, γ.sup.d0 is a dispersion term of the surface free energy before the surface treatment, and γ.sup.d is a dispersion term of the surface free energy after the surface treatment.

An embodiment of the present technology is an isocyanate-based adhesive used for a surface-treated crystalline thermoplastic resin base material, the isocyanate-based adhesive having a value represented by (JIS-A hardness)/(strength at break [MPa])×(elongation at break (%))/100 of 2.0 to 70 after being cured by being allowed to stand still under a condition at 23° C. and 50% RH for 3 days, and the crystalline thermoplastic resin base material having a value represented by (δ.sup.d/δ.sup.p+δ.sup.p) of 2.0 to 30.0. δ.sup.p=γ.sup.p−γ.sup.p0 and δ.sup.d=|γ.sup.d−γ.sup.d0|, γ.sup.p0 is a polar term of surface free energy before the surface treatment, γ.sup.p is a polar term of surface free energy after the surface treatment, γ.sup.d0 is a dispersion term of the surface free energy before the surface treatment, and γ.sup.d is a dispersion term of the surface free energy after the surface treatment.

The present invention provides a polyol composition that can secure the stability over time even when a large amount of water is blended in the polyol composition; a flexible polyurethane foam that uses the polyol composition, is low in density and is excellent in durability; and a method for producing the same. The above objects are solved by a polyol composition for molding a flexible polyurethane foam, comprising a polyol component; a catalyst; a foam stabilizer; a foaming agent; and a compatibilizing agent, wherein the compatibilizing agent is an anionic surfactant which has a hydrophilic portion having an alkali metal salt, and which has a hydrophobic portion having an aromatic ring or alternatively a hydrophobic portion not having an aromatic ring but containing 8 or more carbon atoms in total.

Polyurethane foams that are hydrophilic but nonetheless have low compression sets are made from a combination of MDI and TDI prepolymers, water, and a polymer polyol. The foams optionally are made incorporating a phase change material in the foam formulation. The phase change material does not require encapsulation.

A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ≥50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m.sup.3.

The present disclosure provides a resin composition for a golf ball cover. The resin composition includes a thermoplastic polyurethane resin including 55 to 70 parts by weight of a polyol, 30 to 40 parts by weight of an isocyanate, and 0.2 to 0.4 parts by weight of a polysiloxane. The polysiloxane includes at least one hydroxyl group or a carboxyl group in the terminal alkyl group. The polyol and the isocyanate constitute a silicone-free thermoplastic polyurethane resin, and the polysiloxane and the isocyanate constitute a thermoplastic polyurethane resin that includes silicone in the main chain, thereby improving the scuff resistance and slip property required for a golf ball cover.

The present disclosure provides a resin composition for a golf ball cover. The resin composition includes a thermoplastic polyurethane resin including 55 to 70 parts by weight of a polyol, 30 to 40 parts by weight of an isocyanate, and 0.2 to 0.4 parts by weight of a polysiloxane. The polysiloxane includes at least one hydroxyl group or a carboxyl group in the terminal alkyl group. The polyol and the isocyanate constitute a silicone-free thermoplastic polyurethane resin, and the polysiloxane and the isocyanate constitute a thermoplastic polyurethane resin that includes silicone in the main chain, thereby improving the scuff resistance and slip property required for a golf ball cover.