C08G18/798

COATING COMPOSITION AND IN-MOLD COATING METHOD
20230159788 · 2023-05-25 ·

The present invention provides a coating composition which is capable of forming a coating film that has excellent adhesion to a base material. The coating composition contains: an isocyanate-reactive group-containing resin (A); a polyisocyanate compound (B); and a hydroxyl group-containing aromatic compound (C) having a number average molecular mass of 100-1,000. The isocyanate-reactive group-containing resin (A) in the coating composition contains at least one type of resin selected from a hydroxyl group-containing resin (A1) and an amino group-containing resin (A2).

POLYASPARTIC COATING COMPOSITION, COATING FILM, AND COATING ARTICLE

A polyaspartic coating composition that contains: an aspartic acid ester compound of formula (I):

##STR00001##

where X is an n-valent organic group, R.sub.1 and R.sub.2 are identical or different organic groups inactive against an isocyanate group under reaction conditions, and n is an integer of 2 or more; and a polyisocyanate composition comprising a polyisocyanate obtained from at least one trisocyanate compound of formula (VIII):

##STR00002##

where each Y.sup.1 independently represents a single bond, or a divalent hydrocarbon group which may have at least one selected from the group consisting of an ester structure and an ether structure, the Y.sup.1 groups are identical to or different from each other, and R.sup.3 is a hydrogen atom or a monovalent hydrocarbon group.

PARTICLES OF (AZIRIDINYL HYDROXY)-FUNCTIONAL ORGANIC COMPOUNDS

The invention relates to particles comprising a particular (aziridinyl hydroxy)-functional organic component. The invention further relates to mixtures comprising said particles. The invention further relates to aqueous dispersions comprising said particles. The invention further relates to aqueous compositions comprising said particles. The invention further relates to coating compositions comprising said particles. The invention further relates to aqueous coating compositions comprising said particles. The invention further relates to particles obtained by a process comprising—amongst others—the steps of providing an aqueous dispersion comprising a particular (aziridinyl hydroxy)-functional organic component. The invention further relates to a kit-of-parts comprising in one of its parts an aqueous dispersion comprising a particular (aziridinyl hydroxy)-functional organic component. The invention further relates to cured forms of the various particles, mixtures, aqueous dispersions, aqueous compositions, coating compositions, and aqueous coating compositions. The invention further relates to articles comprising the particles and/or said mixtures, and/or said aqueous dispersions and/or aqueous compositions and/or said cured forms. The invention further relates to various uses of the particles and/or said mixtures, and/or said aqueous dispersions and/or aqueous compositions and/or said cured forms.

METHOD FOR FORMING MULTI-LAYER COATING FILM
20230108182 · 2023-04-06 · ·

A method for forming a multilayer coating film, comprising the steps of applying a color paint (W) to a substrate to form a colored coating film; applying an effect pigment dispersion (X) to the colored coating film, wherein the effect pigment dispersion (X) contains an effect pigment (x2), and the content of the effect pigment (x2) in the effect pigment dispersion (X) is within a range of 15 to 80 parts by mass, based on 100 parts by mass of the total solids content in the effect pigment dispersion (X), to form an effect first base coating film; applying a transparent colored second base paint (Y) containing a color pigment (y2) to form a transparent colored second base coating film; and applying a clear paint (Z) to form a clear coating film, wherein the clear paint (Z) contains a hydroxy-containing acrylic resin (z1) and an aliphatic triisocyanate compound (z2-1) having a molecular weight within a range of 200 to 350.

PROCESS FOR PRODUCING SOLID POLYURETHANE CURING AGENTS

The present invention relates to a process for producing a solid, internally and externally blocked polyurethane curing agent based on a (cyclo)aliphatic polyisocyanate, in which, in the sequence of steps a) to d), a) i) at least one internally blocked (cyclo)aliphatic polyisocyanate and ii) at least one lactam and/or at least one aliphatic alcohol are dissolved in a solvent to produce a reaction mixture, b) the reaction mixture is heated and reacted, c) the reacted reaction mixture is cooled until product precipitates, and d) liquid solvent and any unreacted dissolved reactants and precipitated product are mechanically separated from one another.

STORAGE-STABLE POLYISOCYANATE COMPOSITION AND PREPARATION METHOD

The present application provides a storage-stable polyisocyanate composition and a preparation method. The polyisocyanate composition is obtained by selecting one or more diisocyanate from aliphatic diisocyanates and alicyclic diisocyanates, and reacting same with an alcohol compound; the polyisocyanate composition contains an isocyanurate group, a uretdione group, a carbamate group, and an allophanate group; within the polyisocyanate composition, the molar ratio of the carbamate group/(uretdione group+isocyanurate group) is 0.01-0.2, and preferably 0.01-0.1. Compared to existing techniques, the present application has the advantage of a noticeable increase in system viscosity of uretdione polyisocyanate during storage. With the present application, by means of controlling the ratio of the carbamate group/(uretdione group+isocyanurate group) within the system, the increase in viscosity of a product during storage is inhibited, thereby improving the storage stability of the product.

AZIRIDINE FUNCTIONAL COMPOUND

The present application relates to aziridine functional compounds with reduced genotoxicity and good crosslinking efficiency, for use in the preparation of, for example, coatings.

##STR00001##

COMPOSITIONS CONTAINING URETDIONE GROUPS CROSSLINKING AT LOW TEMPERATURES

The invention relates to compositions containing A) at least one component having at least one uretdione group, B) at least one component having at least one hydroxyl group, C1) of at least one catalyst, containing a structural element of the general formula (I) and/or (II), wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of each other represent the same or different radicals meaning saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic, araliphatic or aromatic organic radicals with 1 to 18 carbon atoms that are substituted or unsubstituted and/or have heteroatoms in the chain, the radicals being capable of forming, even when combined with each other and optionally together with an additional heteroatom, rings with 3 to 8 carbon atoms that can optionally be further substituted, wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of each other can also represent hydrogen, and R.sup.7 represents hydrogen or a carboxylate anion (COO−), and C2) at least one catalyst containing at least one N,N,N′-trisubstituted amidine structure and having an amidine group content (calculated as CN2; molecular weight=40) of 12.0 to 47.0 wt.-%.

WATERBORNE CROSSLINKER COMPOSITION

The present invention relates to a multi-aziridine crosslinker composition, characterized in that the multi-aziridine crosslinker composition is an aqueous dispersion having a pH ranging from 8 to 14 and comprises a multi-aziridine compound in dispersed form, wherein said multi-aziridine compound has: a. from 2 to 6 of the following structural units A: whereby R.sub.1 is H, R.sub.2 and R.sub.4 are independently chosen from H or an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, R a is an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, m is 1, b. one or more linking chains wherein each one of these linking chains links two of the structural units A; and c. a molecular weight in the range from 500 to 10000 Daltons wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

##STR00001##

POLYETHER-MODIFIED POLYISOCYANATE COMPOSITION

The present invention relates to a polyether-modified polyisocyanate composition, which is obtainable by reacting a system containing the following components: a) a polyisocyanate having an isocyanate group functionality of 2-4.5; b) a polyoxyalkylene monoether alcohol; and c) optionally a catalyst; the polyoxyalkylene monoether alcohol has a number-average molecular weight of 900 g/mol-2000 g/mol and an oxypropylene group content of 45 wt. %-100 wt. %, relative to the total weight of the oxyalkylene group of the polyoxyalkylene monoether alcohol; the system has an equivalent ratio of isocyanate group to hydroxyl group of 5:1-110:1; the polyisocyanate composition has the following characteristics: i) the average isocyanate functionality is 1.8-4.1; ii) the isocyanate group content is 8-20 wt. %; and iii) the amount of the polyoxyalkylene monoether structure is greater than 10 wt. % and less than 50 wt. %, for characteristics ii) and iii), relative to the total weight of the polyisocyanate composition.