The present invention relates to a liquid crystal display device including a pair of a substrate arranged opposite to each other, an electrode group disposed on one side or both sides of the pair of substrates facing each other, a plurality of active devices connected to the electrode group, a liquid crystal alignment film disposed on each facing side of the pair of substrates, and a liquid crystal layer interposed between the pair of substrates, wherein the liquid crystal alignment film is manufactured by irradiating linearly polarized light to a film obtained from polyamic acid or a derivative thereof having a photoisomerization structure in the main chain or a film being subject to heat-baking so as to provide alignment-controlling capability, and the liquid crystal layer is a liquid crystal composition having negative (−) dielectric anisotropy. By the present invention, a liquid crystal display device having improved image sticking characteristics and good alignment stability is provided.

An object of the present invention is to provide a liquid crystal composition in which various characteristics of a liquid crystal display element such as a dielectric anisotropy, a viscosity, a nematic phase upper limit temperature, and γ.sub.1, and a burn-in characteristic of a display element are not deteriorated, dropping mark is unlikely to be generated during preparation, a compound represented by liquid crystal composition Formula (I) suitable for a liquid crystal display element in which a discharging amount of the liquid crystal material stable in an ODF step is realized is contained, and a compound represented by General Formula (II) is contained by equal to or more than 15%, and a liquid crystal display element using the same.

A liquid crystal display device that prevents a decrease in the voltage holding ratio (VHR) and an increase in the ion density (ID) in a liquid crystal layer and that resolves the problems of display defects, such as white streaks, variations in alignment, and image sticking. The liquid crystal display has features of preventing a decrease in the voltage holding ratio (VHR) and an increase in the ion density (ID) in a liquid crystal layer and suppressing display defects such as image sticking. Therefore, the liquid crystal display device is particularly useful for active matrix driving liquid crystal display devices with an IPS mode or an FFS mode and can be applied to liquid crystal display devices of, for example, liquid crystal televisions, monitors, cellular phones, and smart phones.

The present invention relates to a liquid crystal display device that includes a particular color filter containing a material containing chiral liquid crystals and a particular pigment. The present invention provides a liquid crystal display device that can prevent a decrease in the voltage holding ratio (VHR) of a liquid crystal layer and solve the problem of display defects, such as white spots, variations in alignment, and burn-in. Because liquid crystal display devices according to the present invention characteristically prevent a decrease in the voltage holding ratio (VHR) of a liquid crystal layer and reduces the occurrence of display defects, such as burn-in, the liquid crystal display devices are particularly useful as liquid crystal display devices in IPS mode and FFS mode for active-matrix driving and can be applied to household electrical appliances, automobiles, production facilities, measuring and analytical instruments, and communication devices.

The present invention relates to liquid-crystalline media (LC media) having negative or positive dielectric anisotropy, comprising a low-molecular-weight component and a polymerizable component. The polymerizable component comprises self-aligning, polymerizable mesogens (polymerizable self-alignment additives) which effect homeotropic (vertical) alignment of the LC media at a surface or the cell walls of a liquid-crystal display (LC display). The invention therefore also encompasses LC displays having homeotropic alignment of the LC medium without alignment layers. The invention discloses novel structures for self-alignment additives which have a certain position of the functional groups.

A liquid crystal display device, including: a display substrate including a first base substrate, a switching device disposed on the first base substrate, a color filter layer disposed on the switching device, and a first electrode disposed on the color filter layer; a counter display substrate including a second base substrate and a second electrode disposed on the second base substrate and facing the first electrode, wherein the counter display substrate is disposed separately from and facing the display substrate; a liquid crystal layer disposed between the display substrate and the counter display substrate, wherein the liquid crystal layer includes at least one first liquid crystal compound represented by Formula 1 and at least one second liquid crystal compound represented by Formula 2; and a light-shielding spacer disposed between the display substrate and the counter display substrate and maintaining a thickness of the liquid crystal layer:

##STR00001##

wherein in Formula 1 and Formula 2, each of R.sub.11—*,

##STR00002##

R.sub.12—*, L.sub.11-*, L.sub.12-*, L.sub.13-*, L.sub.14-*, R.sub.21—*, *-L.sub.21-*, m, n, i, j, o is same as defined in the specification.

Provided is a liquid crystal compound satisfying at least one of physical properties such as high stability to heat and light, a high clearing point (or high maximum temperature), low minimum temperature of a liquid crystal phase, small viscosity, suitable optical anisotropy, large dielectric anisotropy, a suitable elastic constant and excellent compatibility with other liquid crystal compounds, a liquid crystal composition containing the compound and a liquid crystal display device including the composition.

A compound, represented by formula (1):

##STR00001##

wherein, in formula (1), R.sup.1 is alkoxy having 1 to 9 carbons or the like; R.sup.2 is alkenyl having 2 to 10 carbons; Z.sup.1 and Z.sup.2 are independently a single bond, —CH.sub.2CH.sub.2—, —CH═CH— or the like; and a and b are independently 0 or 1.

The liquid crystal composition of the present invention can be used in a liquid crystal display element of an IPS type or a TN type in which display defects such as burn-in and dropping marks in high speed response are unlikely to be generated. Since the liquid crystal composition contains a component which is a dielectrically positive component including a dielectrically positive compound and a dielectrically neutral component of which dielectric anisotropy is greater than −2 and less than +2, the liquid crystal composition has excellent characteristics that the liquid crystal composition has a liquid crystal phase in a wide temperature range, low viscosity, excellent solubility at a low temperature, high specific resistance and a high voltage holding ratio, and is stable with respect to heat and light.

A liquid crystal display including a first substrate, a second substrate overlapping with the first substrate, and a liquid crystal layer provided between the first substrate and the second substrate, wherein the liquid crystal layer includes a liquid crystal compound represented by Formula 1 and a liquid crystal stabilizing agent:

##STR00001##

wherein A, B, n1, n2, R, R′, Z.sub.1, and Z.sub.2 are the same as described in the specification.

An object of the present invention is to provide a liquid crystal display element using a liquid crystal composition having negative dielectric anisotropy, which is capable of realizing excellent display properties by being used in an FFS mode liquid crystal display element without deteriorating various properties, as a liquid crystal display element, such as dielectric anisotropy, viscosity, a nematic phase upper limit temperature, nematic phase stability at low temperature, and γ.sub.1, and burn-in characteristics of the display element.

Provided is an FFS mode liquid crystal display element using an n-type liquid crystal composition so as to achieve the above object.