Patent classifications
C10L1/1963
Copolymer and use thereof for reducing crystallization of paraffin crystals in fuels
The present invention relates to a copolymer obtainable by copolymerization of (A) at least one unsaturated dicarboxylic acid or derivatives thereof, (B) at least one -olefin having from at least 6 up to and including 20 carbon atoms, (C) optionally at least one C.sub.3- to C.sub.20-alkyl ester of acrylic acid or methacrylic acid or a mixture of such alkyl esters and (D) optionally one or more further copolymerizable monomers other than monomers (A), (B) and (C), with a molar incorporation ratio of (A):(B):(C):(D) of 1:0.5 to 2.0:0 to less than 0.5:0 to 0.1 followed by the reaction with at least one dialkylamine (E), where the two alkyl radicals in the at least one dialkylamine (E) are independently alkyl radicals having at least 17 up to 30 carbon atoms.
POLYACRYLAMIDE ANTIFOAM COMPONENTS FOR USE IN DIESEL FUELS
There is disclosed an antifoam component which includes at least one acrylamide polymer for use in a diesel fuel. Acrylamide polymers prepared by polymerizing a (meth)acrylamide monomer to yield a homopolymer or, alternatively, the acrylamide polymer may be prepared by polymerizing a (meth)acrylamide monomer and a (meth)acrylate monomer to yield a heteropolymer.
Polymer compositions allowing easier handling
The invention relates to a polymer composition that can be obtained by means of the free radical polymerisation of A) 95-40 wt. % of alkyl (meth)acrylate containing Ai) 20-95 wt. % of at least one alkyl (meth)acrylate with 16 to 40 C-atoms in the alcohol group, and Aii) 5-80 wt. % of at least one (meth)acrylic acid ester of a C.sub.8-C.sub.22 alcohol carrying a C.sub.6-C.sub.20 alkyl group in the 2-position relative to the hydroxyl group, in the presence of B) 5-60 wt. % ethylene copolymer. The invention also relates to a method for producing same and to the use of same as a flow improver for mineral oils and mineral oil distillates.
DRAG REDUCING AGENTS
A drag reducing composition comprises a sealed temporary container; and a drag reducing agent and up to 20 weight percent of a dispersing fluid disposed in the sealed temporary container. The drag reducing agent comprises polyolefin particles having a particle size of about 10 to about 2,000 microns; and the dispersing fluid comprising water, an alcohol, a hydrocarbon, or a combination comprising at least one of the foregoing.
DRAG REDUCING AGENTS
A drag reducing agent has a core comprising a polyolefin; and a temporary container encapsulating the core. The temporary container contains a container material, which includes an ethylene vinyl acetate copolymer, an ethylene vinyl alcohol copolymer, a polyvinylpyrrolidone, an ethylene vinylpyrrolidone copolymer, a vinylpyrrolidone vinyl acetate copolymer, a polyvinyl acetate, a polyvinyl alcohol, a polyethylene oxide, a polyethylene glycol, polyvinylidene chloride, a polysaccharide or its derivative, or a combination comprising at least one of the foregoing. A largest dimension of the drag reducing agent is greater than about 1,000 microns.
Aqueous polymer dispersions, a method for their preparation and the use thereof as pour-point depressants for crude oil, petroleum, and petroleum products
The invention relates to aqueous polymer dispersions comprising at least one polymer obtainable by the reaction of at least one monomer M1 of the general formula H.sub.2CCHC(O)OR (I), wherein R is an unbranched alkyl chain comprising from 18 to 22 carbon atoms, and optionally at least one monomer M2. The invention relates moreover to a method for the preparing of such aqueous polymer dispersion and the use thereof as pour point depressant for crude oil, petroleum, and petroleum products.
Method for the production of fuel oil
A method making fuel oil from refining residuals. Refining residuals are mixed with a diluent and an additive. Preferred diluents include diesel and reformed naphtha and combinations thereof. The additive is believed to be a cross-linked cyclic anhydride copolymer having an intrinsic viscosity (limiting viscosity, ) of between about 0.10 and 3.0 deciliters per gram and an average molecular weight between about 3,000 and 3,000,000. The additive includes excess aromatic hydrocarbons and a surfactant. In the preferred embodiment, the diluent and the residuals are mixed together in a ratio of about 3:1, by weight. The additive is introduced to this mixture in the amount of about 0.10 to 0.25 percent by weight. The components are thoroughly combined to yield a fuel oil having a viscosity that is about 25 to as much as about 70 percent lower than the viscosity of the same residual/diluent mixture lacking the additive.
Copolymers of bicyclic (meth)acrylates and alkyl (meth)acrylates and their use as rheology modifiers in fuels
The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: at least one bicyclic (meth)acrylate ester at least one C8-C24-alkyl (meth)acrylate optionally, and preferably, at least one aromatic vinyl monomer; and optionally other ethylenically unsaturated monomers, whereby the copolymer has a weight averaged molecular weight from 400,000 to 50,000,000 Dalton, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.
COPOLYMER AND USE THEREOF FOR REDUCING CRYSTALLIZATION OF PARAFFIN CRYSTALS IN FUELS
The present invention relates to a copolymer obtainable by copolymerization of
(A) at least one unsaturated dicarboxylic acid or derivatives thereof,
(B) at least one -olefin having from at least 6 up to and including 20 carbon atoms,
(C) optionally at least one C.sub.3- to C.sub.20-alkyl ester of acrylic acid or methacrylic acid or a mixture of such alkyl esters and
(D) optionally one or more further copolymerizable monomers other than monomers (A), (B) and (C),
with a molar incorporation ratio of (A):(B):(C):(D) of 1:0.5 to 2.0:0 to less than 0.5:0 to 0.1
followed by the reaction with at least one dialkylamine (E), where the two alkyl radicals in the at least one dialkylamine (E) are independently alkyl radicals having at least 17 up to 30 carbon atoms.
AQUEOUS EMULSIONS CONTAINING ETHYLENE-VINYL ACETATE COPOLYMERS, PREPARATION PROCESS THEREOF AND THEIR USE AS ANTI-GELLING ADDITIVES OF CRUDE OILS
The present invention relates to an aqueous emulsion comprising: a) from 50% to 60% of an organic phase dispersed in an aqueous phase, said organic phase containing a mixture including from 24% to 30%, calculated with respect to the final emulsion, of ethylene-vinyl acetate copolymers and/or polyalkyl(meth)acrylates, indicated in the present description as polymeric component, and a high-boiling organic solvent, or a mixture of said solvents; b) a primary emulsifier at a concentration higher or equal to 0.1% and lower than or equal to 3% by weight, calculated with respect to the final emulsion; c) from 37% to 47% of an aqueous phase; wherein the ratio between said polymer component and said organic solvent in the final aqueous emulsion is at least 1/1 and where the organic solvent and any polymer of the polymeric component have a Hildebrand solubility parameter such that, the difference (.sub.solvent_.sub.polymer) is lower than 2 in absolute value for any polymer of the polymeric component.