C08F4/6495

Olefin polymer and method for producing olefin polymer

Provided is a novel olefin polymer which is excellent in lightness and moldability, has high rigidity and yields molded products excellent in flexural elasticity. The olefin polymer includes a propylene initial polymerization product formed in the presence of an olefin polymerization catalyst which is a contact reaction product of an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, at least one organoaluminum compound selected from the compounds of the general formula (I), and a first external electron donating compound; and a polypropylene part formed of a propylene polymerization product formed in the presence of the olefin polymerization catalyst and a second external electron donating compound higher in adsorption to the surface of the olefin polymerization solid catalyst component than the first external electron donating compound.

Olefin polymer and method for producing olefin polymer

Provided is a novel olefin polymer which is excellent in lightness and moldability, has high rigidity and yields molded products excellent in flexural elasticity. The olefin polymer includes a propylene initial polymerization product formed in the presence of an olefin polymerization catalyst which is a contact reaction product of an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, at least one organoaluminum compound selected from the compounds of the general formula (I), and a first external electron donating compound; and a polypropylene part formed of a propylene polymerization product formed in the presence of the olefin polymerization catalyst and a second external electron donating compound higher in adsorption to the surface of the olefin polymerization solid catalyst component than the first external electron donating compound.

Scratch resistance polypropylene at high flow

Injection molded article comprising at least 60 wt.-% of a heterophasic propylene copolymer, said polymer comprises a matrix being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate and at least one of the three polypropylene fractions has a melt flow rate in the range of 1.0 to 20.0 g/10 min, and an elastomeric propylene copolymer dispersed in said matrix, wherein said heterophasic propylene copolymer has a melt flow rate of equal or more than 20.0 g/10 min and the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.

Scratch resistance polypropylene at high flow

Injection molded article comprising at least 60 wt.-% of a heterophasic propylene copolymer, said polymer comprises a matrix being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate and at least one of the three polypropylene fractions has a melt flow rate in the range of 1.0 to 20.0 g/10 min, and an elastomeric propylene copolymer dispersed in said matrix, wherein said heterophasic propylene copolymer has a melt flow rate of equal or more than 20.0 g/10 min and the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.

Processes for Producing High Propylene Content PEDM Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for Producing High Propylene Content PEDM Having Low Glass Transition Temperatures Using Tetrahydroindacenyl Catalyst Systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is 28 C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Multiple Non-coordinating Anion Activators For Propylene-ethylene-diene Monomer Polymerization Reactions
20190284319 · 2019-09-19 ·

This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C.sub.3-C.sub.40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230 C., 2.16 kg).

PROCATALYST COMPOSITIONS USEFUL FOR LOW COMONOMER INCORPORATION AND PROCESS FOR PREPARING THE SAME

The present disclosure relates to novel procatalyst compositions including a titanium moiety, a magnesium halide support, a hydrocarbon solution in which the magnesium halide support is formed, and an electron donor modifier described herein. The present disclosure further relates to a one-pot process for preparing the novel procatalyst compositions, as well as use of the novel procatalyst compositions in solution processes for polymerization of ethylene and at least one addition polymerizable monomer to form a polymer composition.

PROCATALYST COMPOSITIONS USEFUL FOR LOW COMONOMER INCORPORATION AND PROCESS FOR PREPARING THE SAME

The present disclosure relates to novel procatalyst compositions including a titanium moiety, a magnesium halide support, a hydrocarbon solution in which the magnesium halide support is formed, and an electron donor modifier described herein. The present disclosure further relates to a one-pot process for preparing the novel procatalyst compositions, as well as use of the novel procatalyst compositions in solution processes for polymerization of ethylene and at least one addition polymerizable monomer to form a polymer composition.

CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST, AND USE THEREOF

Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high activity and a long term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.

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