C08F4/7031

Encapsulated catalyst and methods of olefin polymerization

A method for encapsulating a catalyst in a dispersed polymer particle comprising dissolving a Group 8 to Group 11 transition metal containing catalyst and a self-dispersing polymer in a solvent; adding water and optionally a base under particle forming conditions to form a dispersed polymer encapsulated catalyst comprising particles having a population number average diameter between 10 and 300 nanometers is provided.

METHOD FOR PRODUCING COPOLYMER OF ALLYL MONOMER HAVING POLAR GROUP

The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.

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METHOD FOR PRODUCING COPOLYMER OF ALLYL MONOMER HAVING POLAR GROUP

The present invention pertains to a method for producing a copolymer of ethylene and an allyl monomer having a polar group represented by general formula (1), or a copolymer of ethylene, an allyl monomer having a polar group represented by general formula (1), and other monomers, wherein the copolymer is produced in the presence of a boron compound having a boron-hydrogen bond or a boron-carbon bond (for example, a compound represented by general formula (2)) by using a metal complex represented by general formula (C1) as a polymerization catalyst (the symbols in the formulas are as described in the description). According to the present invention, a copolymer of ethylene and an allyl monomer can be efficiently produced with high catalytic activity, wherein the copolymer has a polar group and can be used in various applications.

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METHOD FOR PRODUCING COPOLYMER OF POLAR GROUP-CONTAINING ALLYL MONOMER

The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications.

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METHOD FOR PRODUCING COPOLYMER OF POLAR GROUP-CONTAINING ALLYL MONOMER

The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications.

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MULTI-COMPONENT POLAR OLEFIN COPOLYMER AND METHOD FOR PRODUCING THE SAME

An object of the present invention is to provide a multi-component polar olefin copolymer which has sufficiently improved solvent solubility without impairing mechanical properties and the like. The present invention relates to a multi-component polar olefin copolymer containing: one kind of unit of nonpolar monomer (X1) that is ethylene or an -olefin having 3 to 10 carbon atoms; one or two or more kinds of units of polar monomers (formula (1), Z1); and structural unit(s) of one or two or more kinds of units of nonpolar monomers (X2) that are different from the above X1 and/or one or two or more kinds of units of polar monomers (formula (2), Z2):


H.sub.2CCHCOOQT1(1)


H.sub.2CCHT2(2)

MULTI-COMPONENT POLAR OLEFIN COPOLYMER AND METHOD FOR PRODUCING THE SAME

An object of the present invention is to provide a multi-component polar olefin copolymer which has sufficiently improved solvent solubility without impairing mechanical properties and the like. The present invention relates to a multi-component polar olefin copolymer containing: one kind of unit of nonpolar monomer (X1) that is ethylene or an -olefin having 3 to 10 carbon atoms; one or two or more kinds of units of polar monomers (formula (1), Z1); and structural unit(s) of one or two or more kinds of units of nonpolar monomers (X2) that are different from the above X1 and/or one or two or more kinds of units of polar monomers (formula (2), Z2):


H.sub.2CCHCOOQT1(1)


H.sub.2CCHT2(2)

CATALYST FOR OLEFIN POLYMERIZATION AND PRODUCTION METHOD FOR POLAR GROUP-CONTAINING OLEFIN-BASED POLYMERS

A catalyst for olefin polymerization that contains a metal complex represented by general formula (C1) and a method for producing polyethylene, a copolymer of ethylene and an olefin having a polar group represented by general formula (1), or a copolymer of ethylene, an olefin having a polar group represented by general formula (1) and another monomer, using the aforementioned metal complex as a polymerization catalyst, wherein the symbols in formula (C1) and formula (1) are as defined in the specification.

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ENCAPSULATED CATALYST AND METHODS OF OLEFIN POLYMERIZATION

A method for encapsulating a catalyst in a dispersed polymer particle comprising dissolving a Group 8 to Group 11 transition metal containing catalyst and a self-dispersing polymer in a solvent; adding water and optionally a base under particle forming conditions to form a dispersed polymer encapsulated catalyst comprising particles having a population number average diameter between 10 and 300 nanometers is provided.

ENCAPSULATED CATALYST AND METHODS OF OLEFIN POLYMERIZATION

A method for encapsulating a catalyst in a dispersed polymer particle comprising dissolving a Group 8 to Group 11 transition metal containing catalyst and a self-dispersing polymer in a solvent; adding water and optionally a base under particle forming conditions to form a dispersed polymer encapsulated catalyst comprising particles having a population number average diameter between 10 and 300 nanometers is provided.