The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

The present invention provides an aircraft window including a polyurethane including a reaction product of components including (a) about 1 equivalent of at least one polyisocyanate; and (b) about 1 equivalent of 1,4-cyclohexane dimethanol based upon the about 1 equivalent of the at least one polyisocyanate, and other aircraft window compositions.

A photosensitive resin composition contains a polymer compound having a linking group represented by Formula A-1 in the main chain; and an infrared absorbing material. In Formula A-1, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or a monovalent organic group, and X.sup.1 is a specific linking group. ##STR00001##

The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

Nanoporous three-dimensional networks of polyurethane particles, e.g., polyurethane aerogels, and methods of preparation are presented herein. Such nanoporous networks may include polyurethane particles made up of linked polyisocyanate and polyol monomers. In some cases, greater than about 95% of the linkages between the polyisocyanate monomers and the polyol monomers are urethane linkages. To prepare such networks, a mixture including polyisocyanate monomers (e.g., diisocyanates, triisocyanates), polyol monomers (diols, triols), and a solvent is provided. The polyisocyanate and polyol monomers may be aliphatic or aromatic. A polyurethane catalyst is added to the mixture causing formation of linkages between the polyisocyanate monomers and the polyol monomers. Phase separation of particles from the reaction medium can be controlled to enable formation of polyurethane networks with desirable nanomorphologies, specific surface area, and mechanical properties. Various properties of such networks of polyurethane particles (e.g., strength, stiffness, flexibility, thermal conductivity) may be tailored depending on which monomers are provided in the reaction.

A hydrophilic foam comprises a polymer formed from a betaine prepolymer that is a reaction product of a betaine of formula (I) with one or more polyether glycols and a polyfunctional isocyanate compound of formula (II), (I) wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are each hydrocarbon groups having from 1 to 4 carbon atoms, A.sup.? is an anionic functional group, and X.sup.+ is a cationic atom, (II) wherein R.sup.5 is a linear or branched aliphatic hydrocarbon group having from 2 to 12 carbon atoms, or a 5- or 6-membered aliphatic or aromatic carbocyclic group having from 5 to 50 carbon atoms, and b is an integer having a value of 1, 2, or 3.

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Provided are an aqueous dispersion, a method for manufacturing the aqueous dispersion, and an image forming method in which the image is formed of the aqueous dispersion, the aqueous dispersion including a microcapsule that has a shell having a three-dimensional cross-linked structure containing a urethane bond and/or urea bond, and has a core, in which the shell and/or core has a polymerizable group; a dispersant in which a urethane bond and/or urea bond and an anionic group are contained, a weight-average molecular weight is 5000 or more, and an anionic group value, which is the number of millimoles of the anionic group contained in 1 g of the dispersant, is from 0.10 to 2.50 mmol/g; and water.

There are provided an ink jet ink composition including water; and particles including a chain polymer including Unit (1), Unit (2), and a hydrophilic group and a polymerizable group, and an image forming method. Cy.sup.1 and Cy.sup.2 each independently represent a divalent organic group having 3 to 30 carbon atoms including a ring, Y.sup.1 and Y.sup.2 each independently represent an oxygen atom, a sulfur atom, or a NR.sup.1 group, R.sup.1 represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, *1 in Unit (1) represents a bonding position to a structural unit other than Unit (1), and *2 in Unit (2) represents a bonding position to a structural unit other than Unit (2).

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Dielectric materials with optimal mechanical properties for use in laser ablation patterning are proposed. These materials include a polymer selected from the group consisting of polyureas, polyurethane, and polyacylhydrazones. New methods to prepare suitable polyacylhydrazones are also provided. Those methods involve mild conditions and result in a soluble polymer that is stable at room temperature and can be incorporated into formulations that can be coated onto microelectronic substrates. The dielectric materials exhibit high elongation, low CTE, low cure temperature, and leave little to no debris post-ablation.

A fluorochemical composition that includes one or more fluorochemical urethane compounds, a method of treating a substrate (e.g., a method for imparting water and oil repellency and antisoiling characteristics to a substrate), and an article having a fluorochemical composition coating thereon