A thermoset foam comprises from 0.2 to 4.0 wt. % of at least one aliphatic brominated polyether polyol, from 2.0 to 7.0 wt. % of at least one aromatic brominated polyester polyol, and from 2.0 to 7.5 wt. % of at least one flame retardant comprising organo-phosphate, organo-phosphonate, or organo-phosphite, wherein the ratio of the amount of aliphatic bromine expressed as a percentage of total bromine to the amount of aromatic bromine expressed as a percentage of total bromine is from 10:90 to 50:50.

Bellows, for example, a roll bellows and a folding bellows, can be produced that can be used at higher temperatures such as those prevailing in modern articulated constructions, using a mixture comprising at least one thermoplastic elastomer selected from the group of copolysters with a hard segment and a soft segment, wherein in a first step the at least one thermoplastic elastomer is mixed with approximately 0.8 wt. % to approximately 5 wt. % triallyl isocyanurate, based on the total amount of the mixture; in a second step the bellows is produced; and in a third step, the bellows is exposed to an ionizing irradiation in a range from approximately 140 kGy to approximately 350 kGy.

This invention provides a readily adhesive polyester film that has fewer flaws and in which no appearance defects occur due to tight winding during the storage of rolled products, and a method for efficiently producing the readily adhesive polyester film. More specifically, this invention provides a readily adhesive polyester film comprising a polyester film as a base film and a readily adhesive layer on at least one side of the base film, wherein the base film contains particles with an average particle diameter of 0.1-2 μm or more in an amount of 1 mass % or less based on the mass of the base film, and the readily adhesive layer is a cured product of a composition comprising a copolymerized polyester resin (A), a blocked isocyanate group-containing urethane resin (B), and a silicone surfactant (C). This invention also provides a method for producing a readily adhesive polyester film.

This invention provides: a polyurethane for cosmetic preparations, which is obtained by reacting (A) a polyester polyol having two or more hydroxyl groups in each molecule, (B) an aliphatic diol consisting of two hydroxyl groups and an aliphatic hydrocarbon group having 3 to 8 carbon atoms, (C) a carboxyl group-containing diol which has a carboxyl group and two hydroxyl groups in the molecule and has a molecular weight of 100 to 300, (D) a diisocyanate containing at least one compound selected from the group consisting of isophorone diisocyanate, hexamethylene diisocyanate and dicyclohexylmethane-4,4′-diisocyanate, and (E) a chain extender which contains at least one compound selected from the group consisting of water, ethylene diamine and propylene diamine and which has a weight average molecular weight of 50,000 to 300,000; a production method; and a cosmetic preparation which contains this polyurethane for cosmetic preparations.

Disclosed herein is a process for producing rigid polyisocyanurate foams, where (a) aromatic polyisocyanate, (b) isocyanate-reactive compounds including at least one polyetherol (b1) and/or polyesterol (b2), wherein where the number-average content of isocyanate-reactive hydrogen atoms of components (b 1) and (b2) is at least 1.7, (c) catalyst, (d) blowing agents, (e) flame retardants, (f) optionally auxiliary and additive substances and (g) optionally compounds having aliphatic hydrophobic groups and not falling under the definition of compounds (a) to (f) are mixed to afford a reaction mixture and allowed to cure to afford a rigid polyisocyanurate foam. Further disclosed herein is a rigid polyisocyanurate foam obtainable by the process.

Provided are a polyol composition in which hard caking does not occur when stored for a long period of time, and a polyurethane foam using the same.

The polyol composition comprises a polyol compound, a foaming agent, a filler, and a metal oxide fine particle, the foaming agent including a hydrofluoroolefin, and the metal oxide fine particle having a count number ratio of OH ions of a metal constituting the metal oxide fine particle with respect to a total count number of all ions measured using time-of-flight secondary ion mass spectrometry of 0.1 or less.

A rigid polyurethane foam formulation comprising a polyol composition comprising, by weight based on the weight of the polyol composition, more than 70% of at least one polyester polyol having an average hydroxyl number of from 150 to less than 300 mg KOH/g and an average functionality of at least 2; a blowing agent comprising water and an auxiliary blowing agent; a silicone copolymer surfactant; from 1% to 5% by weight based on the weight of the polyol composition, of a cyclic siloxane having a surface tension less than 21 dynes/cm at 25° C., wherein the weight ratio of the cyclic siloxane to the silicone copolymer surfactant is from 0.6 to less than 2.27; a catalyst, and optionally a flame retardant; and a polyisocyanate; such that the isocyanate index is in the range of from 180 to 500; a rigid polyurethane foam formed from the foam formulation; and a method of forming a rigid polyurethane foam.

Thermoplastic polymer compositions having enhanced properties, as well as methods of making and using the same, are provided. Thermoplastic polymers according to some aspects of the present invention may be rigid, but may also be suitable for use in applications requiring a thermoplastic polymer resin. Thermoplastic polymers according to various aspects of the present invention may be useful in preparing shaped articles such as, for example, sheets, films, tubes, preforms, bottles, profiles, and other similar articles.

The present invention provides a resin composition for optical shaping that, with its low viscosity, enables easy stereolithographical fabrication of an object, and that can produce an object having desirable toughness and desirable water resistance, particularly for dental mouthpieces and denture base materials. The present invention relates to a resin composition for optical shaping comprising a urethanized (meth)acrylic compound (A) and a photopolymerization initiator (B), the urethanized (meth)acrylic compound (A) being a (meth)acrylate containing at least one polyol moiety and a urethane bond per molecule, said at least one polyol moiety being selected from the group consisting of a polyester, a polycarbonate, a polyurethane, and a polyether each having a structure derived from a C4 to C18 aliphatic chain diol unit (a) having a branched structure.

Aqueous polyurethane dispersions and coatings and heat-activatable adhesives made from the dispersions are disclosed. The dispersions include a polyurethane reaction product of a polyester polyol and a polyisocyanate. The polyester polyol comprises recurring units of at least one C.sub.2-C.sub.6 aliphatic diol, at least one aliphatic or cycloaliphatic C.sub.4-C.sub.10 dicarboxylic acid, and an aromatic diacid source, which can be recycled PET. The dispersion is formulated using 1 to 3 moles of an acid-functional diol per mole of polyester polyol. Dispersions for the adhesives are produced at NCO/OH molar ratios within the range of 0.90 to 0.98. The adhesives successfully bond a wide range of plastic and metal materials, often demonstrating substrate failure, even with steel. This contrasts with commercial adhesives such as EVA that exhibit only adhesive failure with the same substrates.