The present disclosure provides a two-component solventless adhesive composition comprising a polyol component and an isocyanate component. The polyol component comprises a phosphate functional compound, and at least one polyol selected from polyester, polyether, and the combination thereof; and the isocyanate component comprises isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether, and the combination thereof.

This invention relates to moisture curable polyurethane adhesive compositions and more particularly to moisture curable polyurethane adhesive compositions having improved initial tack and moisture permeability when cured. In one embodiment the disclosed moisture curable polyurethane adhesive compositions are suited for use as hot melt adhesives for use in manufacturing textile, clothing and/or footwear articles.

A system for applying a coating composition to a substrate utilizing a high transfer efficiency applicator is provided herein. The system includes a storage device for storing instructions for performing a matching protocol, and one or more data processors configured to execute the instructions to, receive, by one or more data processors, target image data of a target coating, the target image data generated by an electronic imaging device, and apply the target image data to a matching protocol to generate application instructions. The system further includes a high transfer efficiency applicator defining a nozzle orifice. The high transfer efficiency applicator is configured to expel the coating composition through the nozzle orifice to the substrate to form a coating layer. The high transfer efficiency applicator is configured expel the coating composition based on the application instructions.

Provided is an adhesive which, in a metal foil-containing laminated composite film used in a high temperature sterilization treatment, is resistant to the effects of moisture in the air during curing, has good workability when used as a solvent-free adhesive, and exhibits excellent adhesive strength and acid resistance. Provided is a method for producing an adhesive composition, the method including: a step of obtaining an alcohol-added isocyanate (E) by reacting a trifunctional or higher isocyanate compound (C2) and a monofunctional alcohol (D) at an equivalence ratio of isocyanate groups in the trifunctional or higher isocyanate compound (C2):monofunctional alcohol (D)=100 mol %:25 to 65 mol %, and a step of mixing a polyisocyanate (A) containing a trifunctional or higher isocyanate compound (C1) and the alcohol-added isocyanate (E), and an alcohol (B) having an acid value of 0.5 to 30 mgKOH/g, so that the equivalence ratio between isocyanate groups in the polyisocyanate (A) and hydroxyl groups in the alcohol (B) (isocyanate groups/hydroxyl groups) is within a range from 0.7 to 2.5.

An aqueous dispersion of polyurethane resin is obtained by a chain elongation reaction in water wherein (C) at least one chain extender selected from a group consisting of water-soluble polyamines, hydrazine and derivatives thereof is added to a dispersion liquid obtained by emulsifying and dispersing a mixture in water. The mixture comprises: (B) at least one compound selected from the phosphorous compounds represented by the following formula (1) and (A) an urethane prepolymer and/or a neutralized urethane prepolymer material which has an isocyanate group at the terminal. The urethane prepolymer of component (A) is an urethane prepolymer obtained from (a1) an organic polyisocyanate and (a2) a polymeric polyol. The neutralized urethane prepolymer material of component (A) is a neutralized material obtained by neutralizing an urethane prepolymer which is obtained by further using (a3) a compound having an anionic hydrophilic group and at least two active hydrogens in a molecule together with the components (a1) and (a2).

Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.

A system for applying a coating composition is provided herein. The system includes a first high transfer efficiency applicator defining a first nozzle orifice and a second high transfer efficiency applicator defining a second nozzle orifice. The system further includes a reservoir. The system further includes a substrate defining a first target area and a second target area. The first high transfer efficiency applicator and the second high transfer efficiency applicator are configured to receive the coating composition from the reservoir and configured to expel the coating composition through the first nozzle orifice to the first target area of the substrate and to expel the coating composition through the second nozzle orifice to the second target area of the substrate.

What is described is a polymer which is a polyurethane polymer having blocked isocyanate groups or a reaction product of said polyurethane polymer with at least one epoxy resin, where the polyurethane polymer having blocked isocyanate groups is an addition product formed from at least one polyisocyanate and at least one polyester polyol, wherein the isocyanate groups of the addition product have been blocked by reaction with at least one aromatic compound having at least one hydroxyl group. Such a polymer is suitable as an impact modifier in epoxy resin compositions, especially when they are used as adhesives or structural foams. The polymer improves the corrosion resistance and vertical expansion of the epoxy resin composition.

The present invention relates to a dimensionally stable adhesive compound which is formulated so as to be largely water- and solvent-free and can be brought into contact with the substrate to be bonded by being wiped on in the form of a thin adhesive film that is suitable in particular for bonding materials obtained from plant fibers. The organic constituent of the adhesive compound according to the invention consists predominantly of polyester polyurethanes, at least some of which are based on semi-crystalline polyester polyols. The invention also relates to a method for applying a tacky film to a planar substrate, preferably to paper, by wiping the adhesive compound onto the point of contact with the substrate.

A two-pack polyurethane adhesive for semi-structural and structural adhesive bonds which are applied in melt form and have a high handling strength wherein the two-pack polyurethane adhesive includes a first pack A containing at least one polyester A1 which is solid at room temperature and at least one polyol A2 having a hydroxyl group functionality greater than 2.0, and a second pack B containing polyurethane prepolymers having isocyanate groups.