This invention relates to adhesive compositions comprising a polyester polyol that includes residues of at least one 2, 2, 4, 4-tetraalkylcyclobutane-1, 3-diol, including, for example, 2, 2, 4, 4-tetramethylcyclobutane-1, 3-diol (TMCD). Adhesive compositions as described herein exhibit enhanced properties as compared to conventional adhesive compositions, and may be suitable for a wide variety of end use applications, including, flexible packaging, woodworking, automotive uses, and electronics.

A coating composition for application to a substrate utilizing a high transfer efficiency applicator. The coating composition includes a carrier, a binder, a corrosion inhibiting pigment. The coating composition has an Ohnesorge number (Oh) of from about 0.01 to about 12.6. The coating composition has a Reynolds number (Re) of from about 0.02 to about 6,200. The coating composition has a Deborah number (De) of from greater than 0 to about 1730.

Thermoplastic polymer compositions having enhanced properties, as well as methods of making and using the same, are provided. Thermoplastic polymers according to some aspects of the present invention may be rigid, but may also be suitable for use in applications requiring a thermoplastic polymer resin. Thermoplastic polymers according to various aspects of the present invention may be useful in preparing shaped articles such as, for example, sheets, films, tubes, preforms, bottles, profiles, and other similar articles.

[Purpose] To provide a thermosetting composition with which it is possible to obtain paint films which not only display stain resistance for a short period after application, but with which excellent stain resistance can also be expected for longer periods, and which comply with the paint film properties required for painted steel sheet such as water resistance and bending workability, and have high environmental protection and safety qualities. [Solution] The present invention relates to a thermosetting composition, wherein it contains, as essential components, (A) a polyester resin of number average molecular weight 1,000-10,000 and hydroxyl value 5-200 mg KOH/g and, (B) 0.5 to 2.0 equivalents, relative to the hydroxyl groups of the aforesaid component (A), of a compound (B) which is a blocked aliphatic polyisocyanate compound having reactivity to the hydroxyl groups of component (A), wherein the blocks are methyl ethyl ketone oxime and/or ε-caprolactam, (C) 0.05 to 5 mass %, relative to the total resin solids mass of component (A) and component (B), of an organotin compound represented by the following general formula (I) [Chem.1] R.sup.1—Sn-(O)C═(O)—R.sup.2).sub.3 (I) (R.sup.1 in the formula represents an organic group wherein it has 1-24 carbons, and is directly bound to the Sn atom via a C atom. R.sup.2 represents an organic group wherein it has 1-24 carbons, and is directly bound to the C atom of the (C═O) via a C atom), and (D) 0.5 to 50 mass %, relative to the total resin solids mass of component (A) and component (B), of an organosilicate represented by the following general formula (II) and/or a condensation product thereof [Chem.2] (R.sup.3, R.sup.4, R.sup.5 and R.sup.6 in the formula are each a hydrogen atom or 1-10 carbon organic group, and may be the same or different, n is 1). ##STR00001##

The present invention refers to a process for the production of hot melt adhesives having a low emission of monomeric isocyanates upon heating wherein in a first step a polyurethane prepolymer is generated which is subsequently reacted with a chain extender. Further, the present invention refers to hot melt adhesives obtained by the inventive process.

Aqueous polyurethane dispersions and coatings and heat-activatable adhesives made from the dispersions are disclosed. The dispersions include a polyurethane reaction product of a polyester polyol and a polyisocyanate. The polyester polyol comprises recurring units of at least one C.sub.2-C.sub.6 aliphatic diol, at least one aliphatic or cycloaliphatic C.sub.4-C.sub.10 dicarboxylic acid, and an aromatic diacid source, which can be recycled PET. The dispersion is formulated using 1 to 3 moles of an acid-functional diol per mole of polyester polyol. Dispersions for the adhesives are produced at NCO/OH molar ratios within the range of 0.90 to 0.98. The adhesives successfully bond a wide range of plastic and metal materials, often demonstrating substrate failure, even with steel. This contrasts with commercial adhesives such as EVA that exhibit only adhesive failure with the same substrates.

A two-component solventless polyurethane adhesive composition including (A) at least one isocyanate component and (B) at least one polyol component. The isocyanate component (A) comprises an isocyanate prepolymer that is the reaction product of (Ai) a polyisocyanate and (Aii) an isocyanate-reactive component; wherein the isocyanate-reactive component comprises (Aiia) at least one polyol having a functionality greater than two, (Aiib) at least one aromatic polyester polyol having a functionality of greater than two, and (Aiic) at least one hydrophobic polyol. The polyol component (B) comprises (Bi) at least one polyether polyol having a functionality greater than two, (Bii) at least one aromatic polyester polyol transesterified with a natural oil, and (Biii) at least one phosphate ester polyol. A method for forming a laminate is also disclosed, the method comprising the steps of: (I) mixing the above reactants (components (A) and (B)) to form a solventless adhesive composition, (II) applying a layer of the solventless adhesive composition to a surface of a first substrate, (III) bringing the layer of the solventless adhesive composition on the first substrate into contact with a surface of a second substrate to form a laminate, and (IV) curing the solventless adhesive composition. A laminate comprising the above solventless adhesive composition is also disclosed.

Resin particles are provided. The resin particles include one or more binder resins, a release agent, and a colorant. The one or more binder resins include an amorphous resin. The amorphous resin contains an alcohol component as one of the constituents thereof. The alcohol component includes a plant-derived alcohol component. The resin particles contain a tetrahydrofuran (THF)-insoluble component by an amount of from 5% by mass through 40% by mass.

A system for applying a coating composition to a substrate utilizing a high transfer efficiency applicator is provided herein. The system includes a high transfer efficiency applicator defining a nozzle orifice. The coating composition comprises a carrier and a binder. The coating composition has a viscosity of from about 0.002 Pa*s to about 0.2 Pa*s, a density of from about 838 kg/m3 to about 1557 kg/m3, a surface tension of from about 0.015 N/m to about 0.05 N/m, and a relaxation time of from about 0.0005 s to about 0.02 s. The high transfer efficiency applicator is configured to expel the coating composition through the nozzle orifice to the substrate to form a coating layer. At least 80% of the droplets of the coating composition expelled from the high transfer efficiency applicator contact the substrate.

A system for applying a first, a second, and a third coating composition. The system includes a first high transfer efficiency applicator defining a first nozzle orifice. The system further includes a second high transfer efficiency applicator defining a second nozzle orifice. The system further includes a third high transfer efficiency applicator defining a third nozzle orifice. The system further includes a substrate defining a target area. The first, the second, and the third high transfer efficiency applicators are configured to expel the first coating composition through the first nozzle orifice to the target area of the substrate, through the second nozzle orifice to the target area of the substrate, and through the third nozzle orifice to the target area of the substrate.