The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters which derived from rosin and or hydrogenated rosin reacted with an epihalohydrin. The above glycidyl esters compositions can be used for example, as monomer in binder compositions for paints or adhesives, as reactive diluent or as acid scavenger. This invention is also about the uses of rosin and or hydrogenated rosin glycidyl ester in combinations with polyester polyols, or acrylic polyols, or polyether polyols.

The present invention relates to an acrylic resin powder containing a multistage polymer (G) having an alkyl (meth)acrylate ester (ma) monomer unit and an alkyl (meth)acrylate ester (mb) monomer unit, in which an alkyl group in the alkyl (meth)acrylate esters (ma) and (mb) has 4 to 8 carbon atoms, a glass transition temperature of the multistage polymer (G) is 50° C. or higher, a mass average molecular weight is 10,000 or more and 300,000 or less, a softening temperature that is measured by a flow tester temperature-rising method is 150° C. to 200° C., and the acrylic resin powder is soluble in acetone.

A bio-paint composition and a method of preparing the same can improve the physical properties of a paint by adding acrylic resins having a new composition when the paint composition containing a biomass polyurethane which is an eco-friendly material is prepared.

The present invention relates to polymerizable compositions which contain components that can be crosslinked both via isocyanurate bonds and by a radical reaction mechanism. The invention further relates to methods by way of which polymers can be produced from said compositions.

A pretreatment composition for adhesive bonds, including i) between 10 and 30 parts by weight of at least one polyurethane polymer PU containing isocyanate groups, obtained from the reaction of at least one poly(meth)acrylate polyol P and at least one polyisocyanate Il, with the proviso that the poly(meth)acrylate polyol P has an OH number of at least 35 and the polyurethane polymer PU has an NCO content of between 2.0% and 25.0% by weight, based on the polyurethane polymer PU; ii) 0.1 to 10 parts by weight of at least one organosilane OS; iii) 0 to 10 parts by weight of at least one further polyisocyanate I2; iv) 60 to 90 parts by weight of a solvent L; v) 0 to 15 parts by weight of an industrial carbon black; vi) 0 to 10 parts by weight of a fumed hydrophobic silica.

The present invention relates to a modified polyurethane prepolymer, a two-component polyurethane adhesive and the preparation method thereof. The modified polyurethane prepolymer is prepared from the raw materials comprising the following components: polyurethane prepolymer and graphene oxide; wherein, the polyurethane prepolymer is prepared from the raw materials comprising the following components: copolymer containing ureidopyrimidinone groups and aliphatic isocyanate; wherein, the copolymer containing ureidopyrimidinone groups is formed by copolymerization of the raw materials comprising the following components: alkyl acrylate ureidopyrimidinone, and hydroxyethyl alkyl acrylate; wherein, the alkyl acrylate ureidopyrimidinone has the structure shown in Formula (I); and the hydroxyethyl alkyl acrylate has the structure shown in Formula (II). The two-component polyurethane adhesive containing the modified polyurethane prepolymer has excellent mechanical properties and aging resistance simultaneously.

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A laminate containing: an adhesion layer-applied substrate containing a substrate and an adhesion layer disposed on the substrate, the adhesion layer containing an adhesive emulsion particle (F), an inorganic oxide (G) and a light-shielding agent (S1); and a hard coating layer (C) disposed on the adhesion layer-applied substrate and containing a matrix component (B) containing an inorganic oxide (D), wherein a haze value H1 of the adhesion layer-applied substrate is larger than a haze value H2 of the laminate.

This fluorine-containing curable composition comprises a curable component (A) that provides a cured product under the effect of heat or moisture, and a surface-modifying component (B) that contains a perfluoropolyether compound (b1) having a prescribed structure. The perfluoropolyether compound (b1) in the surface-modifying component (B) is present at 0.005-50 mass parts per 100 mass parts of the curable component (A) excluding volatile components. The fluorine-containing curable composition can be cured by heat or moisture, can be coated on the surface of an article even not containing a fluorine-containing solvent, and can provide the cured product surface with excellent surface characteristics.

The present invention relates to polyester polyols comprising units derived from a) at least one COOH group or derivative thereof carrying component or mixture of components (A) comprising at least one compound carrying two COOH groups or derivatives thereof (A1), b) at least one OH group carrying component or mixture of components (B) comprising (i) at least one compound carrying three OH groups selected from the group consisting of 1,3,5-tris(hydroxymethyl)isocyanurate, 1,3,5-tris(2-hydroxyethyl) isocyanurate, 1,3,5-tris(2-hydroxyisopropyl)isocyanurate, 1,3,5-tris(2-hydroxypropyl)isocyanurate and 1,3,5-tris(2-hydroxybutyl)isocyanurate (B1), (ii) at least one compound carrying two OH groups selected from the group consisting of 1,1-bis(hydroxymethyl)-cyclohexane, 1,2-bis(hydroxymethyl)-cyclohexane, 1,3-bis(hydroxymethyl)-cyclohexane, 1,4-bis(hydroxymethyl)-cyclohexane, 1,1-bis(hydroxyethyl)-cyclohexane, 1,2-bis(hydroxyethyl)-cyclohexane, 1,3-bis(hydroxyethyl)-cyclohexane and 1,4-bis(hydroxyethyl)cyclohexane (B2), (iii) optionally at least one compound or polymer carrying at least three OH groups, which is different from B1 (B3), and (iv) optionally at least one compound or polymer carrying two OH groups, which is different from B2 (B4), and c) optionally at least one compound carrying at least one OH group and at least one COOH group or a derivative thereof (C), and to organic-solvent based two-component coating compositions comprising a) a first component (K1) comprising (i) at least one polyester polyol of the present invention and (ii) optionally at least one polymer carrying more than one OH group, which is different from the polyester polyol of the present invention (D), and b) a second component (K2) comprising (i) at least one compound, oligomer or polymer carrying more than one N═C═O group or blocked N═C═O group (F).

A two-part curable urethane-based composition comprising a main agent (A); and a curing agent (B), wherein the main agent (A) contains a urethane prepolymer (a), an isocyanurate modified product of a polyisocyanate compound (b), and a silane coupling agent (c) in a specified ratio, the curing agent (B) contains a polyol (d) having a hydroxyl value of 50 to 500 mgKOH/g and an amine catalyst (e) in a specified amount, a mixing mass ratio of the main agent (A) to the curing agent (B) is 3:1 to 10:1, and an equivalent ratio of NCO group/OH group in the main agent (A) and the curing agent (B), respectively, is 1.0 to 5.0.