An embodiment relates to an isocyanate composition with improved stability and reactivity and a plastic optical lens using the same. The isocyanate composition has improved stability since the content of chlorine in the composition is adjusted to 22-500 ppm, and thus the isocyanate composition can prevent the deterioration in reactivity even in the long-term storage. Therefore, the isocyanate composition according to an example, even when used after long-term storage after preparation, can be prepared, through polymerization with a thiol-based compound, as a polythiourethane-based optical material with excellent physical properties, such as refractive index, Abbe number, transparency, glass transition temperature, and yellowness, and thus the isocyanate composition is useful in fields of glass lenses, a camera lens, and the like.

Silicone polyurea block copolymers are prepared by copolymerizing: (a) a diamine composition that includes a polyethylene glycol diamine, and optionally, a dipiperidyl alkane; (b) a monofunctional silicone isocyanate; and (c) a diisocyanate. Compositions useful as passivating coatings comprising the block copolymer are also provided, and substrates coated with the compositions. Methods of preparing and using the compositions are also described.

A polyisocyanate composition is produced by reaction of bis(isocyanatomethyl) cyclohexane with trimethylolpropane, and contains a trimethylolpropane-monomolecular-body obtained by reaction of three molecules of bis(isocyanatomethyl) cyclohexane with one molecule of trimethylolpropane, and a trimethylolpropane-bimolecular-body obtained by reaction of five molecules of bis(isocyanatomethyl) cyclohexane with two molecules of trimethylolpropane; and the molar ratio of trimethylolpropane-monomolecular-body relative to trimethylolpropane-bimolecular-body (trimethylolpropane-monomolecular-body/trimethylolpropane-bimolecular-body) contained in the polyisocyanate composition is 1.5 or more and 4.5 or less.

The present invention relates to polymers having dynamic urea bonds and more specifically to polymers having hindered urea bonds (HUBs). The present invention also relates to: (a) malleable, repairable, and reprogrammable shape memory polymers having HUBs, (b) reversible or degradable (e.g., via hydrolysis or aminolysis) linear, branched or network polymers having HUBs, and (c) to precursors for incorporation of HUBs into these polymers. The HUB technology can be applied to and integrated into a variety of polymers, such as polyureas, polyurethanes, polyesters, polyamides, polycarbonates, polyamines, and polysaccharides to make linear, branched, and cross-linked polymers. Polymers incorporating the HUBs can be used in a wide variety of applications including plastics, coatings, adhesives, biomedical applications, such as drug delivery systems and tissue engineering, environmentally compatible packaging materials, and 4D printing applications.

An organosilicon-modified polyurethane resin and a method for producing the same are provided. The organosilicon-modified polyurethane resin includes organosilicon ingredients obtained by chemically bonding a first organosilicon chain extender having a chemical structure of formula (I) and a second organosilicon chain extender having a chemical structure of formula (II) into a molecular structure of a polyurethane resin during a polymerization reaction:

##STR00001##

in which R.sub.11 is a substituent of —CH.sub.2CH.sub.2— or —CH.sub.2CH(CH.sub.3)—, n.sub.1 is a positive integer between 0 and 50, m.sub.1 is a positive integer between 0 and 50, and x.sub.1 is a positive integer between 4 and 100;

##STR00002##

in which R.sub.21 is a substituent of —CH.sub.3 or —CH.sub.2CH.sub.3, R.sub.22 is a substituent of —CH.sub.2CH.sub.2CH.sub.2—, and R.sub.23 is a substituent of —CH.sub.2CH.sub.2— or —CH.sub.2CH(CH.sub.3)—, n.sub.2 is a positive integer between 6 and 130, and m.sub.2 is a positive integer between 4 and 50.

In a polyurethane gel 1 including a gel layer 2 and a coat layer 3 covering the gel layer 2, the gel layer 2 is produced by allowing at least aliphatic polyisocyanate having an average functionality of more than 2.0 to react with polyol having an average functionality of 3.0 or less, and the coat layer 3 is produced by allowing at least aliphatic diisocyanate and/or alicyclic diisocyanate to react with bifunctional active hydrogen compound.

A coating composition includes a coating resin, a triazine ultraviolet light absorber of Formula (I), and a hindered light amine stabilizer, where Formula (I) has the structure: ##STR00001##

Polymer dispersions in aqueous media form binders for pretreatments, coatings and images on substrates. The polymer includes polyamide segments and may have a high percentage of tertiary amide linkages, which facilitates film formation at temperature convenient to textiles and nonwovens. The polyamides are linked with reactions with polyisocyanates (which forms urea linkages if the other reactant is an amine or a urethane linkage if the other reactant is a hydroxyl group).

The thermoplastic polyurethane (TPU) compositions described herein have a very good snap back properties (also called rebound resilience) while still maintaining a good combination of other properties, including hardness, low-temperature flexibility, abrasion resistance, weather-ability, low density, or any combination thereof. This combination of properties make the TPU compositions described herein useful materials for applications where polyamide copolymers (COPA) and/or polyether block amide (PEBA) materials have traditionally been used over TPU.

The eyewear material is an eyewear material containing thermoplastic polyurethane. The eyewear material has a tan δ peak at both less than 0° C. and 0° C. or more and 70° C. or less observed in dynamic viscoelasticity measurement in tensile mode under the measurement conditions of a temperature increase speed of 5° C./min and a measurement frequency of 10 Hz.