There is provided a two-part urethane adhesive composition including: a main agent containing a polyisocyanate component (A); and a curing agent containing water and an active hydrogen-containing compound (B). The (B) contains a compound represented by Formula (4); the (A) contains a urethane prepolymer (A-3); an average active hydrogen concentration of the (B) is 0.50 to 3.50 mol/kg; an average active hydrogen concentration of the (B) and the water is 2.00 to 8.00 mol/kg. The main agent and the curing agent are mixed in such amounts as to satisfy conditions that: a ratio of the number of isocyanate groups of the (A) to the number of active hydrogens of the (B) is 1 to 5; and a ratio of the number of isocyanate groups of the (A) to the total number of active hydrogens of the (B) and the water is 0.5 to 2.5.

A polyurea composition containing monomeric diisocyanates in an amount of max. 0.5 wt.% and consisting of a first component containing a primary, aromatic diamine and a second component containing an isocyante-group-containing polyether urethane polymer containing monomeric diisocyantes in an amount of max. 0.5 wt.% and an aliphatic polyisocyanate with an NCO content of 8 to 25 wt.%.

In a self-repairing polyurethane resin material produced by reaction of pentamethylenediisocyanate with an active hydrogen group-containing compound, the active hydrogen group-containing compound contains a polyol compound having a number average molecular weight of 100 to 2000 and an average functionality of 2 to 3.

A self-repairing polyurethane resin material is produced by reaction of a polyisocyanate compound consisting of aliphatic polyisocyanate and/or araliphatic polyisocyanate with an active hydrogen group-containing compound, used for producing polyurethane resin having self-repairing properties, has an isocyanate group at its molecular terminal, contains an allophanate group and an isocyanate trimer, and the mole ratio of the allophanate group relative to the isocyanate trimer is 0.1 to 20.

A waterborne alternative polyurethane composition is provided which comprises a reaction product of: an azidated polyol; and a waterborne poly(alkynyl carbamate) prepolymer comprising a reaction product of a polyisocyanate and from 1 wt. % to 20 wt. % of an alkynol-polyether having a formula (I),
R.sub.1—R.sub.2—O—R.sub.3—OH  (I),
wherein, R.sub.1=a monovalent group selected from either HC≡C— or HC≡C—CO—, R.sub.2=a divalent alkylene group from 1 to 8 carbon atoms, and may be straight chain or branched and may contain cyclic moieties, and R.sub.3=a polyethylene glycol with number average molecular weight from 300-1,200 g/mol, wherein the wt. % is based on the weight of the prepolymer, wherein reaction of the azidated polyol and the waterborne poly(alkynyl carbamate) occurs at a temperature of from 20° C. to 200° C. and optionally in the presence of a catalyst. The inclusion of an alkynol-polyether does not materially alter the performance properties and reactivity of the waterborne polyurethane composition relative to a solventborne polyurethane control composition. Inclusion of the alkynol-polyether reduces the need for organic solvents by allowing for the use of water as a carrier. The inventive waterborne alternative polyurethane compositions may find use in or as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

The present invention relates to a polyurethane (PP2) comprising at least two, preferably two or three, end functional groups T of following formula (I):

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The present invention also relates to the uses of the polyurethanes (PP2) for the preparation of multicomponent systems.

A urethane (meth)acrylate not comprising caprolactone is the product of reaction of A) a monoalcohol bearing from 1 to 5 (meth)acrylates, B) an allophanate-modified polyisocyanate, C) optionally, in the presence of a saturated polyol of functionality 2 to 3, D) optionally, in the presence of an unsaturated polyol with a hydroxyl functionality of 2 to 4, said polyol being C.sub.3 to C.sub.18, E) optionally, in the presence of a reactive diluent. A process for preparing the urethane (meth)acrylate includes reacting the monoalcohol A) and the polyisocyanate B) in the optional presence of C), D), and/or E). The urethane (meth)acrylate may be used in curable compositions for coatings, in particular for varnishes and inks, adhesives, adhesion primers, coatings for wood, metal or plastic and application by spray gun and provide a good compromise between reactivity, flexibility, adherence, hardness, and ease of use.

A simulated sclera 2 is obtained by including a plurality of fiber layers (a) and a resin (b) in contact with the fiber layer (a), having a. fiber diameter of a fiber constituting the fiber layer (a) of 0.6 μm or more and 170.0 μm or less, laminating the plurality of fiber layers (a), and impregnating the laminated fiber layers (a) with the resin (b).

This invention relates to a method of preparing a microcellular polyurethane elastomer by reacting naphthalene diisocyanate with a polyol to prepare a prepolymer containing an isocyanate (NCO) group, followed by mixing the prepared polyurethane prepolymer with a plasticizer, water, an emulsifier and the like, and then foaming the prepolymer blend to prepare a polyurethane elastomer, wherein the emulsifier is a mixture of (a) a compound selected from the group consisting of 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,4-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, hexamethylene diisocyanate, 1,4′-cyclohexane diisocyanate and mixtures thereof, and (b) a C.sub.2-10 hydrocarbon having a molecular weight of 500 or less with two to four hydroxyl groups, or mixtures thereof. The method of the invention can optimize the viscosity and properties of the prepolymer resulting from the reaction of naphthalene diisocyanate with a polyol, thus improving processability.

The present invention provides a laminate obtained by arranging a composition to be in contact with a rubber, wherein the composition is prepared by blending a polythiol compound (A), an isocyanate group-containing compound (B) and a radical generator (C), and wherein the ratio of the total molar number of the isocyanate group contained in the isocyanate-containing compound (B) to the total molar number of the thiol group contained in the polythiol compound (A) (isocyanate group/thiol group) is from 0.2 to 0.78, and provides a method for producing the laminate. The present invention thus provides a laminate, in which the rubber layer is adhered using at least one of an adhesive or an adhesive sheet capable of strongly adhering a rubber member, especially a vulcanized rubber member, and provides a laminate adhering to a rubber article using at least one of a coating agent and a coating sheet.