The present disclosure provides pyridyl hydroxyl amine catalyst compounds and systems containing the compounds. The present disclosure is also directed to polymerization processes to produce polyolefin polymers from catalyst systems including one or more olefin polymerization catalysts, at least one activator, and an optional support. The compounds are represented by Formula I(a), I(b) or I(c):

##STR00001##

A catalyst for olefin polymerization containing at least one metal complex comprising at least one —SF.sub.5 group attached to a ligand bound to the metal. The invention further relates to catalyst, a process for making polyolefins and dispersions of UHMWPE.

A catalyst for olefin polymerization containing at least one metal complex comprising at least one —SF.sub.5 group attached to a ligand bound to the metal. The invention further relates to catalyst, a process for making polyolefins and dispersions of UHMWPE.

A preparation method of bimetallic catalysts based on anthracene frameworks and use thereof in olefin polymerization is reported. Anthrecene frameworks were introduced, heat resistance of the catalysts is improved, and by changing central metals and configurations of the frameworks, steric and electronic effects of the metal catalysts of this model can be adjusted and controlled conveniently, and polyolefin polymer materials of different structures and different properties can be prepared, the bimetallic catalyst can be used in ethylene homopolymerization for preparation of high density polyethylene, ethylene/1-octene copolymerization for preparation of polyolefin elastomers and ethylene/norbornene copolymerization for preparation of cycloolefin copolymers. The bimetallic catalyst based on anthracene frameworks can be used in olefin high temperature solution polymerization for preparing polyolefin elastomers and cycloolefin copolymers, the polyolefin elastomers obtained have molecular weights as high as M.sub.W=890 kg.Math.mol.sup.−1, and the cycloolefin copolymers have copolymerization monomer insertion rates as high as 45 mol %.

This disclosure is generally directed to polymerization catalysts derived from 1,5-diazabicyclooctanes, catalyst systems utilizing such catalysts, and processes to polymerize alpha olefins therewith.

This disclosure is generally directed to polymerization catalysts derived from 1,5-diazabicyclooctanes, catalyst systems utilizing such catalysts, and processes to polymerize alpha olefins therewith.

An ultra-high molecular weight polyethylene polymer has: a powder bulk density of at least 200 kg/m.sup.3; an intrinsic viscosity (I.V.) of at least 8 dl/g, as measured in accordance with ASTM D4020; and wherein, a specimen prepared from the ultra-high molecular weight polyethylene can be drawn in the absence of a solvent, at a total draw ratio of at least 50, when drawing at a drawing temperature of ≥T.sub.m−30° C., wherein T.sub.m is the melting temperature of the ultra-high molecular weight polyethylene polymer. A supported catalyst system for producing such UHMWPE polymers includes a transition metal complex and a particulate catalyst support including particles having a volume based median particle diameter of at least 0.3 micrometer. Articles derived from such polymers having excellent strength and modulus.

An ultra-high molecular weight polyethylene polymer has: a powder bulk density of at least 200 kg/m.sup.3; an intrinsic viscosity (I.V.) of at least 8 dl/g, as measured in accordance with ASTM D4020; and wherein, a specimen prepared from the ultra-high molecular weight polyethylene can be drawn in the absence of a solvent, at a total draw ratio of at least 50, when drawing at a drawing temperature of ≥T.sub.m−30° C., wherein T.sub.m is the melting temperature of the ultra-high molecular weight polyethylene polymer. A supported catalyst system for producing such UHMWPE polymers includes a transition metal complex and a particulate catalyst support including particles having a volume based median particle diameter of at least 0.3 micrometer. Articles derived from such polymers having excellent strength and modulus.

The present disclosure provides pyridyl hydroxyl amine catalyst compounds and systems containing the compounds. The present disclosure is also directed to polymerization processes to produce polyolefin polymers from catalyst systems including one or more olefin polymerization catalysts, at least one activator, and an optional support. The compounds are represented by Formula I(a), I(b) or I(c): ##STR00001##

The present disclosure provides pyridyl hydroxyl amine catalyst compounds and systems containing the compounds. The present disclosure is also directed to polymerization processes to produce polyolefin polymers from catalyst systems including one or more olefin polymerization catalysts, at least one activator, and an optional support. The compounds are represented by Formula I(a), I(b) or I(c): ##STR00001##