Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula ##STR00001##
wherein each R.sup.1 is a Z.sup.1OZ.sup.2Z.sup.3SiZ.sup.4 group, wherein each Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z.sup.2 and Z.sup.3 independently represent a hydroxyl group, a C.sub.1-C.sub.4 alkyl group, a C.sub.1-C.sub.4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z.sup.4 represents a C.sub.1-C.sub.8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula ##STR00001##
wherein each R.sup.1 is a Z.sup.1OZ.sup.2Z.sup.3SiZ.sup.4 group, wherein each Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z.sup.2 and Z.sup.3 independently represent a hydroxyl group, a C.sub.1-C.sub.4 alkyl group, a C.sub.1-C.sub.4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z.sup.4 represents a C.sub.1-C.sub.8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

Methods for coating a substrate with a coating including an adsorbent material and a binder comprising an organosilica material which is a polymer comprising independent units of Formula [Z.sup.3Z.sup.4SiCH.sub.2].sub.3 (I), wherein each Z.sup.3 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group or an oxygen atom bonded to a silicon atom of another unit or an active site on the substrate and each Z.sup.4 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.4 alkyl group, an oxygen atom bonded to a silicon atom of another unit or an active site on the substrate are provided. Methods of gas separation are also provided.

Methods for coating a substrate with a coating including an adsorbent material and a binder comprising an organosilica material which is a polymer comprising independent units of Formula [Z.sup.3Z.sup.4SiCH.sub.2].sub.3 (I), wherein each Z.sup.3 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group or an oxygen atom bonded to a silicon atom of another unit or an active site on the substrate and each Z.sup.4 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.4 alkyl group, an oxygen atom bonded to a silicon atom of another unit or an active site on the substrate are provided. Methods of gas separation are also provided.

This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a bisphenolate compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a bisphenolate compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

This invention relates to a process to polymerize olefins comprising: i) contacting one or more olefins with a catalyst system comprising: 1) a support comprising an organoaluminum treated layered silicate and an inorganic oxide; and 2) a bisphenolate compound; and ii) obtaining olefin polymer having high molecular weight and layered silicate dispersed therein. Preferably the support is in the form of spheroidal particles.

A catalyst system including the reaction product of a fluorided support, an activator, and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems, and polymers made therefrom.

A catalyst system including the reaction product of a fluorided support, an activator, and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems, and polymers made therefrom.

This invention relates to propylene polymers having multimodal molecular weight distribution and propylene polymerization processes using single site catalyst systems with supports having multimodal particle size distribution comprising one mode peaked at particle size of 3-70 m, and another mode peaked at particle size of 70-200 m, the support also having an average particle size of more than 30 m up to 200 m and a specific surface area of 400-800 m.sup.2/g.