Patent classifications
C08F4/6548
SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION, AND METHOD FOR PRODUCING OLEFIN POLYMER
Provided is a solid catalyst component for olefin polymerization comprising an electron-donating compound other than a phthalate, the solid catalyst component being equal in the olefin-polymerizing activity and in the primary physical properties of the resulting polymer such as stereoregularity and molecular weight distribution to those with use of a phthalate as an electron-donating compound. A solid catalyst component for olefin polymerization comprises a magnesium atom, a titanium atom, a halogen atom, an ester compound (A) represented by a general formula (1) and a diester compound (B) represented by a general formula (2), wherein
a ratio represented by the following expression:
(content (mass %) of ester compound (A)/content (mass %) of diester compound (B))
is 0.05 to 50.
OLEFIN POLYMER AND METHOD FOR PRODUCING OLEFIN POLYMER
Provided is a novel olefin polymer which is excellent in lightness and moldability, has high rigidity and yields molded products excellent in flexural elasticity. The olefin polymer includes a propylene initial polymerization product formed in the presence of an olefin polymerization catalyst which is a contact reaction product of an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, at least one organoaluminum compound selected from the compounds of the general formula (I), and a first external electron donating compound; and a polypropylene part formed of a propylene polymerization product formed in the presence of the olefin polymerization catalyst and a second external electron donating compound higher in adsorption to the surface of the olefin polymerization solid catalyst component than the first external electron donating compound.
OLEFIN POLYMER AND METHOD FOR PRODUCING OLEFIN POLYMER
Provided is a novel olefin polymer which is excellent in lightness and moldability, has high rigidity and yields molded products excellent in flexural elasticity. The olefin polymer includes a propylene initial polymerization product formed in the presence of an olefin polymerization catalyst which is a contact reaction product of an olefin polymerization solid catalyst component containing a titanium atom, a magnesium atom, a halogen atom and an internal electron donating compound, at least one organoaluminum compound selected from the compounds of the general formula (I), and a first external electron donating compound; and a polypropylene part formed of a propylene polymerization product formed in the presence of the olefin polymerization catalyst and a second external electron donating compound higher in adsorption to the surface of the olefin polymerization solid catalyst component than the first external electron donating compound.
ZIEGLER-NATTA CATALYST SYSTEMS AND METHODS OF CONTROLLING PARTICLE SIZE
A colloidal suspension includes an organic phase and a complex of Formula I as precursor for Ziegler-Natta catalyst synthesis:
XTiCl.sub.p(OR.sup.1).sub.4p.Math.YMg(OR.sup.2).sub.q(OR.sup.3).sub.t(I).
In Formula I, a molar ratio of X to Y (X/Y) is from 0.2 to 5.0, p is 0 or 1, 0<q<2, 0<t<2, the sum of q and t is 2, R.sup.1, R.sup.2, and R.sup.3 are each independently a linear or branched alkyl, a linear or branched heteroalkyl, a cycloalkyl, a substituted cycloalkyl, a substituted heterocycloalkyl, a substituted aryl, or a (heteroaryl)alkyl; and R.sup.2 is not the same as R.sup.3.
ZIEGLER-NATTA CATALYST SYSTEMS AND METHODS OF CONTROLLING PARTICLE SIZE
A colloidal suspension includes an organic phase and a complex of Formula I as precursor for Ziegler-Natta catalyst synthesis:
XTiCl.sub.p(OR.sup.1).sub.4p.Math.YMg(OR.sup.2).sub.q(OR.sup.3).sub.t(I).
In Formula I, a molar ratio of X to Y (X/Y) is from 0.2 to 5.0, p is 0 or 1, 0<q<2, 0<t<2, the sum of q and t is 2, R.sup.1, R.sup.2, and R.sup.3 are each independently a linear or branched alkyl, a linear or branched heteroalkyl, a cycloalkyl, a substituted cycloalkyl, a substituted heterocycloalkyl, a substituted aryl, or a (heteroaryl)alkyl; and R.sup.2 is not the same as R.sup.3.
METHODS OF CONTROLLING ZIEGLER-NATTA PRE-CATALYST PARTICLES FORMATION AND USE FOR OLEFIN POLYMERIZATION
A colloidal suspension includes an organic phase and a complex of Formula I as precursor for Ziegler-Natta catalyst synthesis:
XTiCl.sub.p(OR.sup.1).sub.4-p.YMg(OR.sup.2).sub.q(OR.sup.3).sub.t (I).
In Formula I, a molar ratio of X to Y (X/Y) is from 0.2 to 5.0, p is 0 or 1, 0<q<2, 0<t<2, the sum of q and t is 2, R.sup.1, R.sup.2, and R.sup.3 are each independently a linear or branched alkyl, a linear or branched heteroalkyl, a cycloalkyl, a substituted cycloalkyl, a substituted heterocycloalkyl, a substituted aryl, or a (heteroaryl)alkyl; and R.sup.2 is not the same as R.sup.3.
METHODS OF CONTROLLING ZIEGLER-NATTA PRE-CATALYST PARTICLES FORMATION AND USE FOR OLEFIN POLYMERIZATION
A colloidal suspension includes an organic phase and a complex of Formula I as precursor for Ziegler-Natta catalyst synthesis:
XTiCl.sub.p(OR.sup.1).sub.4-p.YMg(OR.sup.2).sub.q(OR.sup.3).sub.t (I).
In Formula I, a molar ratio of X to Y (X/Y) is from 0.2 to 5.0, p is 0 or 1, 0<q<2, 0<t<2, the sum of q and t is 2, R.sup.1, R.sup.2, and R.sup.3 are each independently a linear or branched alkyl, a linear or branched heteroalkyl, a cycloalkyl, a substituted cycloalkyl, a substituted heterocycloalkyl, a substituted aryl, or a (heteroaryl)alkyl; and R.sup.2 is not the same as R.sup.3.
CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, PREPARATION METHOD THEREOF, AND CATALYST INCLUDING SAME
A catalyst component for olefin polymerization includes magnesium, titanium, a halogen, an internal electron donor compound, and a precipitation aid. The precipitation aid includes a precipitation aid represented by general formula (I). The precipitation aid represented by general formula (I) includes isomers represented by general formula (I-a) and/or (I-b).
##STR00001##
CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, PREPARATION METHOD THEREOF, AND CATALYST INCLUDING SAME
A catalyst component for olefin polymerization includes magnesium, titanium, a halogen, an internal electron donor compound, and a precipitation aid. The precipitation aid includes a precipitation aid represented by general formula (I). The precipitation aid represented by general formula (I) includes isomers represented by general formula (I-a) and/or (I-b).
##STR00001##
MAGNESIUM COMPOUND, METHOD FOR PRODUCING THE SAME AND USE THEREOF
The present invention relates to a method of producing a magnesium compound represented by the following formula: Mg(OR.sup.1).sub.2-n(Modifier).sub.n wherein R.sup.1 is C.sub.mH.sub.2m+1, where in m is an integer from 2 to 10, and n is 0-2 wherein the method comprises the steps a) providing a mixture comprising magnesium, an initiator and a first alcohol wherein the molar ratio of initiator to magnesium is from 0.0001 to 1; and b) adding a modifier to the mixture obtained in step a) wherein the modifier is selected from the group consisting of alkoxy alcohol, carboxylic acid ester, aliphatic hydrocarbon, aromatic hydrocarbon, ketone, a second alcohol or a mixture thereof, wherein the second alcohol is different from the first alcohol, respective magnesium compound and the use thereof.