Patent classifications
C08F4/6565
Olefin polymerization Ziegler-Natta catalyst components and process for the production of olefin polymers therewith
The present invention relates to a solid Ziegler-Natta catalyst component for olefin polymerization containing an organosilicon element in combination with one or more internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides a phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
Olefin polymerization Ziegler-Natta catalyst components and process for the production of olefin polymers therewith
The present invention relates to a solid Ziegler-Natta catalyst component for olefin polymerization containing an organosilicon element in combination with one or more internal electron donors. The catalyst components, according to the present invention, are able to produce polypropylene polymers with higher stereo-regularity. The present invention also provides a phthalate-free catalyst system capable of producing polypropylene with an isotacticity that is equal to or higher than catalyst systems containing phthalate derivatives.
METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING CATALYST FOR OLEFIN POLYMERIZATION, AND METHOD FOR PRODUCING OLEFIN POLYMER
Disclosed herein is a method for producing a solid catalyst component for olefin polymerization that is capable of reducing the amount of fine powder contained in the solid catalyst component for olefin polymerization. The method includes the step of reacting a magnesium compound and a titanium halide compound with each other so that a maximum heat release rate per mole of the magnesium compound is 18 W or less. Also disclosed herein is a method for producing a solid catalyst component for olefin polymerization that is capable of preventing a reduction in polymerization activity caused by application of heat to the solid catalyst component for olefin polymerization. The method includes the step of reacting a magnesium compound and a titanium halide compound with each other so that a total heat release value per mole of the titanium compound is 6 kJ to 90 kJ.
METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING CATALYST FOR OLEFIN POLYMERIZATION, AND METHOD FOR PRODUCING OLEFIN POLYMER
Disclosed herein is a method for producing a solid catalyst component for olefin polymerization that is capable of reducing the amount of fine powder contained in the solid catalyst component for olefin polymerization. The method includes the step of reacting a magnesium compound and a titanium halide compound with each other so that a maximum heat release rate per mole of the magnesium compound is 18 W or less. Also disclosed herein is a method for producing a solid catalyst component for olefin polymerization that is capable of preventing a reduction in polymerization activity caused by application of heat to the solid catalyst component for olefin polymerization. The method includes the step of reacting a magnesium compound and a titanium halide compound with each other so that a total heat release value per mole of the titanium compound is 6 kJ to 90 kJ.
Pellet comprising thermoplastic polymer sheath surrounding glass filaments having reduced emissions
The invention relates to a pellet comprising a thermoplastic polymer sheath intimately surrounding glass filaments, which glass filaments are covered at least in part with an impregnating agent and extend in a longitudinal direction of said pellets, wherein the thermoplastic polymer sheath is prepared from a thermoplastic polymer composition comprising A) a heterophasic propylene copolymer consisting of a propylene-based matrix and a dispersed ethylene-α-olefin copolymer, wherein the heterophasic propylene copolymer has a melt flow rate of at least 40 g/10 min as determined in accordance with ISO 1133 (230° C., 2.16 kg) and a FOG value of at most 350 μg/g as determined by VDA 278, wherein the glass filaments are present in an amount of 10-70 wt % based on the pellet.
Pellet comprising thermoplastic polymer sheath surrounding glass filaments having reduced emissions
The invention relates to a pellet comprising a thermoplastic polymer sheath intimately surrounding glass filaments, which glass filaments are covered at least in part with an impregnating agent and extend in a longitudinal direction of said pellets, wherein the thermoplastic polymer sheath is prepared from a thermoplastic polymer composition comprising A) a heterophasic propylene copolymer consisting of a propylene-based matrix and a dispersed ethylene-α-olefin copolymer, wherein the heterophasic propylene copolymer has a melt flow rate of at least 40 g/10 min as determined in accordance with ISO 1133 (230° C., 2.16 kg) and a FOG value of at most 350 μg/g as determined by VDA 278, wherein the glass filaments are present in an amount of 10-70 wt % based on the pellet.
Ziegler-Natta catalysts prepared from solid alkoxymagnesium halide supports
Catalyst systems containing a titanium alkoxymagnesium halide supported catalyst component can be used for the polymerization of olefins. The catalyst can be prepared from a microcrystalline solid alkoxymagnesium halide support having a lattice spacing in the 5 nm to 15 nm range.
Ziegler-Natta catalysts prepared from solid alkoxymagnesium halide supports
Catalyst systems containing a titanium alkoxymagnesium halide supported catalyst component can be used for the polymerization of olefins. The catalyst can be prepared from a microcrystalline solid alkoxymagnesium halide support having a lattice spacing in the 5 nm to 15 nm range.
Catalyst components for propylene polymerization
A process of preparing a solid catalyst component for the production of polypropylene includes a) dissolving a halide-containing magnesium compound in a mixture, the mixture including an epoxy compound, an organic phosphorus compound, and a hydrocarbon solvent to form a homogenous solution; b) treating the homogenous solution with an organosilicon compound during or after the dissolving step; c) treating the homogenous solution with a first titanium compound in the presence of a first non-phthalate electron donor, and an organosilicon compound, to form a solid precipitate; and d) treating the solid precipitate with a second titanium compound in the presence of a second non-phthalate electron donor to form the solid catalyst component, where the process is free of carboxylic acids and anhydrides.
Catalyst components for propylene polymerization
A process of preparing a solid catalyst component for the production of polypropylene includes a) dissolving a halide-containing magnesium compound in a mixture, the mixture including an epoxy compound, an organic phosphorus compound, and a hydrocarbon solvent to form a homogenous solution; b) treating the homogenous solution with an organosilicon compound during or after the dissolving step; c) treating the homogenous solution with a first titanium compound in the presence of a first non-phthalate electron donor, and an organosilicon compound, to form a solid precipitate; and d) treating the solid precipitate with a second titanium compound in the presence of a second non-phthalate electron donor to form the solid catalyst component, where the process is free of carboxylic acids and anhydrides.