Patent classifications
C08F4/65927
RESIN COMPOSITION AND MOLDED ARTICLE
An object of the present invention is to provide a resin composition and a molded article each having suppressed surface stickiness while having high stress-relaxing ability and vibration-absorbing ability at room temperature. A resin composition (X) containing 10 to 50 parts by mass of a thermoplastic resin (A) and 50 to 90 parts by mass of an inorganic substance (B), wherein a tan δ peak temperature and tan δ peak value, obtained by performing dynamic viscoelastic measurement at a frequency of 10 rad/s (1.6 Hz) in the temperature range of −40 to 150° C., are 0° C. or higher and 60° C. or lower, and 0.8 or more and 5.0 or less, respectively.
ETHYLENE/1-HEXENE COPOLYMER HAVING IMPROVED FLEXIBILITY AND PROCESSIBILITY
The present disclosure relates to an ethylene/1-hexene copolymer having excellent flexibility and processability and useful for manufacturing high-pressure heating pipes, PE-RT pipes or large-diameter pipes.
ETHYLENE/1-HEXENE COPOLYMER HAVING IMPROVED FLEXIBILITY AND PROCESSIBILITY
The present disclosure relates to an ethylene/1-hexene copolymer having excellent flexibility and processability and useful for manufacturing high-pressure heating pipes, PE-RT pipes or large-diameter pipes.
METALLOCENE SUPPORTED CATALYST AND METHOD FOR PREPARING OLEFINE POLYMER USING THE SAME
Provided are a metallocene supported catalyst capable of greatly reducing generation of fine powder during preparation of olefin polymers while exhibiting excellent catalyst activity, and a method of preparing olefin polymers using the same.
METALLOCENE SUPPORTED CATALYST AND METHOD FOR PREPARING OLEFINE POLYMER USING THE SAME
Provided are a metallocene supported catalyst capable of greatly reducing generation of fine powder during preparation of olefin polymers while exhibiting excellent catalyst activity, and a method of preparing olefin polymers using the same.
HETEROPHASIC PROPYLENE ETHYLENE COPOLYMER COMPOSITION WITH DESIRABLE BALANCE OF MECHANICAL PROPERTIES
A heterophasic propylene ethylene copolymer composition having an MFR.sub.2 in the range from 1.0 to 55.0 g/10 min and a melting temperature in the range from 155 to 162° C., comprising: i) from 60 to 88 wt.-% of a xylene cold insoluble fraction (XCI) having an intrinsic viscosity iV(XCI) in the range from 1.40 to 2.50 dl/g, an isotactic pentad concentration [mmmm] of more than 97.0% and a content of 2,1-regiodefects in the range from 0.1 to 0.4 mol %, ii) from 12 to 40 wt.-% of a xylene cold soluble fraction (XCS) having an intrinsic viscosity iV(XCS) in the range from 1.80 to 3.20 dl/g and an ethylene content C2(XCS) in the range from 25 to 80 wt.-%, wherein the ratio of the intrinsic viscosities of the two fractions, iV(XCS)/iV(XCI), is in the range from 1.0 to 2.0.
HETEROPHASIC PROPYLENE ETHYLENE COPOLYMER COMPOSITION WITH DESIRABLE BALANCE OF MECHANICAL PROPERTIES
A heterophasic propylene ethylene copolymer composition having an MFR.sub.2 in the range from 1.0 to 55.0 g/10 min and a melting temperature in the range from 155 to 162° C., comprising: i) from 60 to 88 wt.-% of a xylene cold insoluble fraction (XCI) having an intrinsic viscosity iV(XCI) in the range from 1.40 to 2.50 dl/g, an isotactic pentad concentration [mmmm] of more than 97.0% and a content of 2,1-regiodefects in the range from 0.1 to 0.4 mol %, ii) from 12 to 40 wt.-% of a xylene cold soluble fraction (XCS) having an intrinsic viscosity iV(XCS) in the range from 1.80 to 3.20 dl/g and an ethylene content C2(XCS) in the range from 25 to 80 wt.-%, wherein the ratio of the intrinsic viscosities of the two fractions, iV(XCS)/iV(XCI), is in the range from 1.0 to 2.0.
CONTINUOUS SOLUTION POLYMERIZATION PROCESS
A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH.sub.2═CHR.sup.1, wherein R.sup.1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH.sub.2═CHR.sup.2, wherein R.sup.2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship:
Tp≥Tm+20° C.
wherein Tm is the melting temperature of the obtained polymer.
CONTINUOUS SOLUTION POLYMERIZATION PROCESS
A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH.sub.2═CHR.sup.1, wherein R.sup.1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH.sub.2═CHR.sup.2, wherein R.sup.2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship:
Tp≥Tm+20° C.
wherein Tm is the melting temperature of the obtained polymer.
POLYMERIZATION PROCESS AND REACTOR FOR CONTROLLING MOLECULAR WEIGHT DISTRIBUTION AND COMONOMER COMPOSITION DISTRIBUTION
A reactor for the polymerization of olefins comprising a first inlet for introducing a first stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof, at least one outlet for withdrawing a product stream, characterized in that the reactor further comprises at least one second inlet for introducing a second stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof; and a process for polymerizing olefins in a reactor according to the present invention, comprising the steps of introducing monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof as the first stream via the first inlet into the reactor forming a reaction mixture; polymerizing a polymer from the reaction mixture; withdrawing the product stream via the at least one outlet from the reactor; characterized in that the process comprises a further step of introducing a second stream comprising monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof into the reactor via the at least one second inlet into the reactor.